Research Progress on Stereocomplex Crystallization of Polymers

Qing Xie; Jian-na Bao; Cheng-tao Yu; Guo-rong Shan; Yong-zhong Bao; Peng-ju Pan

doi:10.11777/j.issn1000-3304.2017.16326

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Research Progress on Stereocomplex Crystallization of Polymers

Reviews | 更新时间：2021-03-19

- Research Progress on Stereocomplex Crystallization of Polymers
- Acta Polymerica Sinica Issue 6, Pages: 893-905(2017)
- 作者机构：
  
  浙江大学化学工程与生物工程学院化学工程联合国家重点实验室杭州 310027
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.16326
  CLC：
- Published：2017-6，
  
  Received：1 November 2016，
  
  Revised：2 December 2016，
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Qing Xie, Jian-na Bao, Cheng-tao Yu, Guo-rong Shan, Yong-zhong Bao, Peng-ju Pan. Research Progress on Stereocomplex Crystallization of Polymers. [J]. Acta Polymerica Sinica (6):893-905(2017)
DOI：

Qing Xie, Jian-na Bao, Cheng-tao Yu, Guo-rong Shan, Yong-zhong Bao, Peng-ju Pan. Research Progress on Stereocomplex Crystallization of Polymers. [J]. Acta Polymerica Sinica (6):893-905(2017) DOI： 10.11777/j.issn1000-3304.2017.16326.

摘要

立构复合结晶是高分子结晶中的一种普遍现象，也是不同高分子之间共结晶的特殊形式.互为立体异构高分子在共混物和立体嵌段共聚物中可形成立构复合结晶.由于这种独特的链凝聚结构，立构复合结晶材料与相应的同质结晶材料的性能显著不同，立构复合结晶通常可提高高分子材料的熔点、耐热性、结晶能力、结晶度、机械力学性能、耐溶剂性能等.通过立构复合结晶，可使一些非晶或难结晶的高分子转变为可结晶或高结晶度的状态，从而实现材料性能的转变.因此，互为立体异构高分子之间的立构复合结晶为聚合物材料的性能优化和调控提供了有效的途径.文献已报道了多类可立构复合结晶的聚合物体系，包括脂肪族聚酯、脂肪族聚碳酸酯、聚甲基丙烯酸酯、聚酰胺和聚酮等.本文根据聚合物化学结构的不同，针对文献已报道的可立构复合结晶的高分子体系，综述了其立构复合结晶的形成条件、结构特征与物理性质.

Abstract

Stereocomplex crystallization is a generalbehaviour in polymer crystallizationand it is also a special cocrystallization process between different polymers. The polymers with complementary configurations and chiralities can form stereocomplex crystallites in their blends and stereoblock copolymers. Stereocomplex crystallization includes homo and hetero types; the former and latter represent the stereocomplex formation between the enantiomeric polymers having the identical and different structures

respectively. Stereocomplex crystallites of the polymers usually have denser chainpacking in the crystalline lattice than that in the common homocrystallites

because of the presence of additional intermolecular interactions (

e.g.

hydrogen bonding interactions). Due to their unique structural feature

the stereocomplexed polymers generally have distinct physical performances from the corresponding homocrystalline polymers. Stereocomplex crystallization can change melting temperature of the original polymers

and improve their thermal resistance

crystallizability

degree of crystallinity

processability

mechanical properties

and solvent-resistance. Some polymers

that are non-crystallizable or difficult to crystallize

can become crystallizable through stereocomplex crystallization; this can significantly change the physical performances of the resulted materials.Stereocomplex crystallization offers therefore a feasible andefficient avenue to manipulate and optimize the physical properties of the involved polymers. Stereocomplexed polymers havea variety of potential applications as biomedical materials and thermal-resistant engineeringplastics. A large number of polymer systems have been reported to fit for stereocomplex crystallization

including aliphatic polyesters

aliphatic polycarbonates

polymethacrylate

polyimide

polyketone

etc

. Among them

the aliphatic polyesters and polycarbonates are two majorclasses of the stereocomplexable polymers; these polymers are biodegradable and can be partially derived from the biomass. Stereocomplex crystallization of enantiomeric polymers is affected by a variety of factors such as the chemical structure of the polymer components

blending ratio

crystallization and processing conditions. This paper gives a review on the stereocomplex formation conditions

structural characteristics

and physicalproperties for all reported stereocomplexable polymer systems according to the chemical structures of the polymers. We hope that this review can provide a theoretical guideline for the development of the stereocomplexable polymers.

关键词

立构复合结晶聚酯聚碳酸酯结晶结构热性能

Keywords

Stereocomplex crystallizationPolyesterPolycarbonateCrystalline structureThermal property

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