浏览全部资源
扫码关注微信
Molecular Relaxation and Rheological Behaviors of Fumed Silica/Low-molecular Weight Polyethylene Glycol Suspensions
- Acta Polymerica Sinica Issue 11, Pages: 1832-1840(2017)
- 作者机构：
高分子合成与功能构造教育部重点实验室 浙江大学高分子科学与工程学系 杭州 310027
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2017.17008
CLC：Published：20 November 2017，
Received：9 January 2017，
Revised：5 March 2017，
扫 描 看 全 文
Bei Xu, Yi-hu Song, Qiang Zheng. Molecular Relaxation and Rheological Behaviors of Fumed Silica/Low-molecular Weight Polyethylene Glycol Suspensions. [J]. Acta Polymerica Sinica (11):1832-1840(2017)
Bei Xu, Yi-hu Song, Qiang Zheng. Molecular Relaxation and Rheological Behaviors of Fumed Silica/Low-molecular Weight Polyethylene Glycol Suspensions. [J]. Acta Polymerica Sinica (11):1832-1840(2017) DOI： 10.11777/j.issn1000-3304.2017.17008.
摘要
采用亲水气相二氧化硅（FS）、非缠结聚乙二醇（PEG，重均分子量400）制备悬浮体系，考察FS体积分数（
φ
）对PEG本体相
α
-松弛、结晶行为及悬浮体系流变行为的影响.结果表明，FS可延缓PEG本体相
α
-松弛，提高玻璃化转变温度，并显著增加浮体系黏度，降低本体PEG相结晶与熔融焓.低填充时，FS起成核作用；高填充时，FS延迟PEG分子扩散，并降低结晶温度.FS对PEG结晶的不同作用发生在悬浮体系溶胶-凝胶转变附近，此时悬浮液非线性动态流变行为呈现显著的硬化软化特性，线性动态流变行为呈现最为显著的频率依赖性.通过建立线性动态流变行为叠加曲线，揭示了FS对PEG分子链扩散行为的显著推迟作用.
Abstract
Suspensions were prepared by mixing hydrophilic fumed silica (FS) with low-molecular polyethylene glycol (PEG
weight-averaged molecular weight 400). By differential scanning calorimeter and broadband dielectric spectrometer
influences of FS volume fraction (
φ
) on
α
-relaxation and crystallization behaviors of bulk PEG phase were investigated. Furthermore
influences of
φ
on the linear and nonlinear rheology behaviors of the suspensions were also investigated using stress-controlled rheometer. For the bulk PEG phase
α
-relaxation is retarded and glass transition temperature (
T
g
) is increased due to the addition of FS. On the other hand
FS significantly retard the diffusion of global PEG molecules
which leads to a great increase in viscosity of the suspensions along with significant reductions in crystallization and fusion enthalpy of the bulk PEG phase. The suspensions demonstrate different rheology and crystallization behaviors with varying
φ
. The low-filled suspensions exhibit an apparent sol-like rheological response
in which FS plays a nucleating role to promote PEG crystallization. However
the high-filled suspensions apparently behave like gels
in which FS restrains the chain diffusion and crystallization. The role of FS changes in the vicinity of
φ
=0.16
where the system undergoes an apparent sol-to-gel transition. In the close vicinity of this transition
the nonlinear dynamic rheology shows the most obvious strain hardening
while the linear dynamic rheology demonstrates the most significant frequency-dependence. Due to the extremely complicated nonlinear rheological response of the suspensions
it is hard to observe the pure hydrodynamics region experimentally
and in the frequency range achieved
complex viscosity (
η
*
) as a function of
φ
at given frequencies does not fit classical hydrodynamics equations that do not consider the effect of nanoparticles on the polymer chains diffusion. To account for the effect of nanoparticles on the diffusion of PEG chains
data of liner dynamic rheology of the suspensions are shifted horizontally and vertically to create master curves with pure PEG as the reference. The creation of master curves reveals that FS greatly retards the diffusion of global PEG chains in the constrained bulk phase
which plays a major role in the reinforcement and dissipation of the suspensions. In addition to the dynamically retarded bulk PEG chains
both the inter-particle friction in the low-filled sols and the in-cage rattling motion of nanoparticles in the high-filled gels additionally contribute to the dissipation behavior of the suspensions
resulting in the complicated dynamic rheological behavior.
关键词
气相二氧化硅聚乙二醇界面层剪切增稠分子松弛
Keywords
Fumed silicaPolyethylene glycolInterfacial layerShear thickeningMolecular relaxation
references
G B Appetecchi , F Croce , J Hassoun , B Scrosati , Mark Salomon , Frank Cassel . J Power Sour , 2003 . 114 105 - 112 . DOI:10.1016/S0378-7753(02)00543-8http://doi.org/10.1016/S0378-7753(02)00543-8.
J E Weston , B C H Steele . Solid State Ionics , 1982 . 7 75 - 79 . DOI:10.1016/0167-2738(82)90072-8http://doi.org/10.1016/0167-2738(82)90072-8.
S R Raghavan , H J Walls , S A Khan . Langmuir , 2000 . 16 7920 - 74 . DOI:10.1021/la991548qhttp://doi.org/10.1021/la991548q.
M Wetjen , M A Navarra , S Panero , S Passerini , S Bruno , H Jusef . ChemSusChem , 2013 . 6 1037 - 43 . DOI:10.1002/cssc.v6.6http://doi.org/10.1002/cssc.v6.6.
D P G Gennes . Adv Collid Interf Sci , 1987 . 27 189 - 190 . DOI:10.1016/0001-8686(87)85003-0http://doi.org/10.1016/0001-8686(87)85003-0.
A Papon , K Saalwachter , K Schaler , L Guy , F Lequeux , H Montes . Macromolecules , 2011 . 44 913 - 922 . DOI:10.1021/ma102486xhttp://doi.org/10.1021/ma102486x.
Y Song , Q Zheng . Polymer , 2010 . 51 3262 - 3268 . DOI:10.1016/j.polymer.2010.05.018http://doi.org/10.1016/j.polymer.2010.05.018.
A Sanz , M Ruppel , J F Douglas . J Phys:Conden Matter , 2008 . 20 104209 DOI:10.1088/0953-8984/20/10/104209http://doi.org/10.1088/0953-8984/20/10/104209.
J M Kropka , K W Putz , V Pryamitsyn , V Ganesan , P F Green . Macromolecules , 2007 . 40 5424 - 5432 . DOI:10.1021/ma070407phttp://doi.org/10.1021/ma070407p.
A Bansal , H Yang , C Li , K Cho , B C Benicewicz , S K Kumar , L S Schadler . Nat Mater , 2005 . 4 1 - 6 . DOI:10.1038/nmat1305http://doi.org/10.1038/nmat1305.
A Ghanbari , T V M Ndoro , F Leroy , M Rahimi , M C Bohm , F Muller-Plathe . Macromolecules , 2012 . 45 ( 1 ): 572 - 584 . DOI:10.1021/ma202044ehttp://doi.org/10.1021/ma202044e.
Zhong Zheng , Yihu Song , Qiang Zheng . Acta Polymerica Sinica , 2017 . ( 3 ): 429 - 453 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
郑 重 , 宋 义虎 , 郑 强 . 高分子学报 , 2017 . ( 3 ): 429 - 453 . http://www.gfzxb.org/CN/abstract/abstract14657.shtml.
Qiumei Wu , Jianming Ruan , Baiyun Huang , Zhongcheng Zhou , Jianpeng Zou . J Central South Univ , 2006 . 13 ( 1 ): 1 - 5 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
伍 秋美 , 阮 建明 , 黄 伯云 , 周 忠诚 , 邹 俭鹏 . 中南大学学报 , 2006 . 13 (1 ): 1 - 5 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
S R Raghavan , M W Riley , P S Fedkiw , S A Khan . Chem Mater , 1998 . 10 244 - 251 . DOI:10.1021/cm970406jhttp://doi.org/10.1021/cm970406j.
J H Park , H G Kim , D H Han , J C Lim , D H Oh , K E Min . J Appl Polym Sci , 2007 . 103 2481 - 2486 . DOI:10.1002/(ISSN)1097-4628http://doi.org/10.1002/(ISSN)1097-4628.
X Q Liu , R Y Bao , X J Wu , W Yang , B H Xie , M B Yang . RSC Adv , 2015 . 5 18367 - 18374 . DOI:10.1039/C4RA16261Ghttp://doi.org/10.1039/C4RA16261G.
S Y Kim , H W Meyer , K Saalwachter , C F Zukoski . Macromolecules , 2012 . 45 4225 - 4237 . DOI:10.1021/ma300439khttp://doi.org/10.1021/ma300439k.
R P Wool . Polymer Interfaces:Structure and Strength , : Munich Hunser Publisher , 1995 . 12 .
Z Bogdan , K V Sunil , L Igor . Langmuir , 2004 . 20 6727 - 6735 . DOI:10.1021/la049359hhttp://doi.org/10.1021/la049359h.
R E Mozine , G Smith , E Polygalov , P M Suherman , J Broadhead . J Phys D:Appl Phys , 2003 . 36 330 - 335 . DOI:10.1088/0022-3727/36/4/302http://doi.org/10.1088/0022-3727/36/4/302.
R B Bogoslovov , C M Roland , A R Ellis , A M Randall , S G Robertson . Macromolecules , 2008 . 41 1289 - 1296 . DOI:10.1021/ma702372ahttp://doi.org/10.1021/ma702372a.
A Schiinhals , E Schlosser . Macromolecules , 1992 . 25 4915 - 4919 . DOI:10.1021/ma00045a015http://doi.org/10.1021/ma00045a015.
M M Feldstein , G A Shandryuk , S A Kuptsov , N A Plate . Polymer , 2000 . 41 5327 - 5338 . DOI:10.1016/S0032-3861(99)00802-2http://doi.org/10.1016/S0032-3861(99)00802-2.
J Dudowicz , K F Freed , J F Douglas . J Chem Phys , 2006 . 124 64901 DOI:10.1063/1.2166391http://doi.org/10.1063/1.2166391.
J Dudowicz , K F Freed , J F Douglas . J Chem Phys , 2005 . 109 21285 - 21292 . DOI:10.1021/jp0523266http://doi.org/10.1021/jp0523266.
Q Qin , G B Mckenna . J Non-Crystal Solids , 2006 . 352 2977 - 2985 . DOI:10.1016/j.jnoncrysol.2006.04.014http://doi.org/10.1016/j.jnoncrysol.2006.04.014.
F W Starr , J F Douglas . Phys Rev Lett , 2011 . 106 115702 DOI:10.1103/PhysRevLett.106.115702http://doi.org/10.1103/PhysRevLett.106.115702.
I Janigova , I Chodak , I Chorvath . Eur Polym J , 1992 . 28 1547 - 1552 . DOI:10.1016/0014-3057(92)90149-Vhttp://doi.org/10.1016/0014-3057(92)90149-V.
He Manjun, Chen Weixiao, Dong Xixia. Polymer Physics. Shanghai :Fudan University Press, 2000. 86-88
何曼君, 陈维孝, 董西侠.高分子物理, 修订版.上海:复旦大学出版社, 2000. 86-88
A P Holt , J R Sangoro , Y Wang , A L Agapov , A P Sokolov . Macromolecules , 2013 . 46 4168 - 4173 . DOI:10.1021/ma400418bhttp://doi.org/10.1021/ma400418b.
J Wang , M Yang , Y Lu , Z Jin , L Tan , H Gao , S Fan , W Dong , G Wang . Nano Energy , 2016 . 19 78 - 87 . DOI:10.1016/j.nanoen.2015.11.001http://doi.org/10.1016/j.nanoen.2015.11.001.
V R Geiser , Y Leterrier , J A E Manson . Macromolecules , 2010 . 43 7705 - 7712 . DOI:10.1021/ma100569chttp://doi.org/10.1021/ma100569c.
R Ruggerone , V R Geiser , Vacche S Dalle , Y Leterrier , J A E Mansonet . Macromolecules , 2010 . 43 10490 - 10497 . DOI:10.1021/ma102074xhttp://doi.org/10.1021/ma102074x.
A Tewari , A M Gokhale . Mater Sci Eng:A , 2004 . 385 332 - 341 . DOI:10.1016/S0921-5093(04)00875-5http://doi.org/10.1016/S0921-5093(04)00875-5.
E Brown , H M Jaeger . Science , 2011 . 333 1230 - 1231 . DOI:10.1126/science.1211155http://doi.org/10.1126/science.1211155.
H Watanabe , ML Yao , T Inoue , K Osaki . Rheological Acta , 1998 . 37 1 - 6 . DOI:10.1007/s003970050085http://doi.org/10.1007/s003970050085.
S R Raghavan , J Hou , G L Baker , S A Khan . Langmuir , 2000 . 16 1066 - 1077 . DOI:10.1021/la9815953http://doi.org/10.1021/la9815953.
K Hyun , M Wilhelm , C O Klein , K S Cho , J G Nam , K H Ahn , S J Lee , R H Ewoldt , G H McKinley . Prog Polym Sci , 2011 . 36 1697 - 1753 . DOI:10.1016/j.progpolymsci.2011.02.002http://doi.org/10.1016/j.progpolymsci.2011.02.002.
K Hyun , S H Kim , K H Ahn , S J Lee . J Non-Newton Fluid Mech , 2002 . 107 51 - 65 . DOI:10.1016/S0377-0257(02)00141-6http://doi.org/10.1016/S0377-0257(02)00141-6.
Z Zheng , Y Song , R Yang , Q Zheng . Langmuir , 2015 . 31 13478 - 87 . DOI:10.1021/acs.langmuir.5b03899http://doi.org/10.1021/acs.langmuir.5b03899.
E Guth , O Gold . Phys Rev , 1938 . 53 ( 322 ): 2 - 15 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
M Klüppel , G Heinric . Rubber Chem Technol , 1995 . 68 ( 4 ): 623 - 651 . DOI:10.5254/1.3538763http://doi.org/10.5254/1.3538763.
Ruiquan Yang , Yihu Song , Qiang Zheng . Acta Polymerica Sinica , 2016 . ( 10 ): 1425 - 1430 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
杨 瑞权 , 宋 义虎 , 郑 强 . 高分子学报 , 2016 . ( 10 ): 1425 - 1430 . http://www.gfzxb.org/CN/abstract/abstract14552.shtml.
W Shih , W Y Shih , S Kim , Liu J , I A Aksay . Phys Rev A , 1990 . 42 4772 - 4779 . DOI:10.1103/PhysRevA.42.4772http://doi.org/10.1103/PhysRevA.42.4772.
G Huber , T A Vilgis . Kautsch Gummi Kunstst , 1999 . 52 102 - 107 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
G Heinrich , M Kluppel , T A Vilgis . Curr Opin Solid State Mater Sci , 2002 . 6 195 - 203 . DOI:10.1016/S1359-0286(02)00030-Xhttp://doi.org/10.1016/S1359-0286(02)00030-X.
M Kluppel . Adv Polym Sci , 2003 . 164 1 - 86 . DOI:10.1007/b10953http://doi.org/10.1007/b10953.
P Meakin . Phys Rev Lett , 1983 . 51 1119 - 1122 . DOI:10.1103/PhysRevLett.51.1119http://doi.org/10.1103/PhysRevLett.51.1119.
A A Potanin , W W Russel . Phys Rev E , 1996 . 53 3702 - 3709 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
A A Potanin , R Derooij , D Vandenende , J Mellema . J Chem Phys , 1995 . 102 5845 - 5853 . DOI:10.1063/1.469317http://doi.org/10.1063/1.469317.
R Buscall , P D A Mills , J W Goodwin , D W Lawson . J Chem Soc Faraday Trans Ⅰ , 1988 . 84 4249 - 4260 . DOI:10.1039/f19888404249http://doi.org/10.1039/f19888404249.
R Kotsilkova . Thermoset Nanocomposites for Engineering Applications , : Shrewsbury Smithers Rapra Technology Limited , 2007 . 258 - 263.
Y Song , Q Zheng . J Rheol , 2015 . 59 155 - 191 . DOI:10.1122/1.4903312http://doi.org/10.1122/1.4903312.
Y Song , Q Zheng . Crit Rev Solid State Mater Sci , 2016 . 41 318 - 346 . DOI:10.1080/10408436.2015.1135415http://doi.org/10.1080/10408436.2015.1135415.
Y Song , Q Zheng . Prog Mater Sci , 2016 . 84 1 - 58 . DOI:10.1016/j.pmatsci.2016.09.002http://doi.org/10.1016/j.pmatsci.2016.09.002.
Yihu Song , Miao Du , Hongmei Yang , Qiang Zheng . Acta Polymerica Sinica , 2013 . ( 9 ): 1115 - 1130 . http://d.wanfangdata.com.cn/Periodical/jsjxb201411015.
宋 义虎 , 杜 淼 , 杨 红梅 , 郑 强 . 高分子学报 , 2013 . ( 9 ): 1115 - 1130 . http://www.gfzxb.org/CN/abstract/abstract14008.shtml.
Ferry J D. Viscoelastic Properties of Polymers. New York:John Wiley & Sons, Inc, 1980. 136-139
S E Harton , S K Kumar , H C Yang , T Koga , K Hicks , H K Lee , J Mijovic , M Liu , R S Vallery , D W Gidley . Macromolecules , 2010 . 43 3415 - 3421 . DOI:10.1021/ma902484dhttp://doi.org/10.1021/ma902484d.
C Schick , A Sargsyan , A Tonoyan , S Davtyan , A Tonoyan . Eur Polym J , 2007 . 43 3113 - 3127 . DOI:10.1016/j.eurpolymj.2007.05.011http://doi.org/10.1016/j.eurpolymj.2007.05.011.
D Fragiadakis , P Pissis . J Non-Crystal Solids , 2007 . 353 4344 - 4352 . DOI:10.1016/j.jnoncrysol.2007.05.183http://doi.org/10.1016/j.jnoncrysol.2007.05.183.
D Fragiadakis , P Pissis , L Bokobza . Polymer , 2005 . 46 6001 - 6008 . DOI:10.1016/j.polymer.2005.05.080http://doi.org/10.1016/j.polymer.2005.05.080.
S Gam , J S Meth , S G Zane , C Chi , B A Wood , M E Seiz , K I Winey , N Clarke , R J Composto . Macromolecules , 2011 . 44 3494 - 3501 . DOI:10.1021/ma102463qhttp://doi.org/10.1021/ma102463q.
G J Schneider , K Nusser , L Willner , D Richter . Macromolecules , 2011 . 44 5857 - 5860 . DOI:10.1021/ma200899yhttp://doi.org/10.1021/ma200899y.
U Yamamoto , K S Schweizer . J Chem Phys , 2011 . 135 224902 DOI:10.1063/1.3664863http://doi.org/10.1063/1.3664863.
C C Lin , S Gam , J S Meth , N Clarke , K I Winey , R J Composto . Macromolecules , 2013 . 46 4502 - 4509 . DOI:10.1021/ma4000557http://doi.org/10.1021/ma4000557.
J S Meth , S Gam , J Choi , C C Lin , R J Composto , K I Winey . J Phys Chem B , 2013 . 117 15675 - 15683 . DOI:10.1021/jp406411thttp://doi.org/10.1021/jp406411t.
C C Lin , K Ohno , N Clarke , K I Winey , R J Composto . Macromolecules , 2014 . 47 5357 - 5364 . DOI:10.1021/ma501113chttp://doi.org/10.1021/ma501113c.
S S Sternstein , A J Zhu . Macromolecules , 2002 . 35 7262 - 7273 . DOI:10.1021/ma020482uhttp://doi.org/10.1021/ma020482u.
J Yang , C R Han . J Phys Chem C , 2013 . 117 20236 - 20243 . DOI:10.1021/jp404616shttp://doi.org/10.1021/jp404616s.
Y H Wen , Y Lu , K M Dobosz , L A Archer . Macromolecules , 2014 . 47 4479 - 4492 . DOI:10.1021/ma5004002http://doi.org/10.1021/ma5004002.
Y H Wen , J L Schaefer , L A Archer . ACS Macro Lett , 2015 . 4 119 - 123 . DOI:10.1021/mz5006662http://doi.org/10.1021/mz5006662.
0
Views
20
下载量
0
CSCD
- L-PDFDownload
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Publicity Resources
Related Articles
Related Author
Related Institution
- Postal code：100190
- Tel：010-62588927 Email：gfzxb@iccas.ac.cn
- Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8
京公网安备11010802024621 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.