Near-infrared-responsive Copper Sulfide Nanoparticle/Liquid Crystal Elastomer Composites

Ge Si-jia; Shan Zhou-nan; Deng Lin-lin; Lin Bao-ping; Yang Hong

doi:10.11777/j.issn1000-3304.2017.17105

您当前的位置：

首页 >

文章列表页 >

Near-infrared-responsive Copper Sulfide Nanoparticle/Liquid Crystal Elastomer Composites

Research Article | 更新时间：2021-01-26

- Near-infrared-responsive Copper Sulfide Nanoparticle/Liquid Crystal Elastomer Composites
- Acta Polymerica Sinica Issue 10, Pages: 1633-1640(2017)
- 作者机构：
  
  东南大学化学化工学院南京 211189
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2017.17105
  CLC：
- Published：20 October 2017，
  
  Received：26 April 2017，
  
  Revised：11 May 2017，
扫描看全文
Ge Si-jia, Shan Zhou-nan, Deng Lin-lin, Lin Bao-ping, Yang Hong. Near-infrared-responsive Copper Sulfide Nanoparticle/Liquid Crystal Elastomer Composites. [J]. Acta Polymerica Sinica (10):1633-1640(2017)
DOI：

Ge Si-jia, Shan Zhou-nan, Deng Lin-lin, Lin Bao-ping, Yang Hong. Near-infrared-responsive Copper Sulfide Nanoparticle/Liquid Crystal Elastomer Composites. [J]. Acta Polymerica Sinica (10):1633-1640(2017) DOI： 10.11777/j.issn1000-3304.2017.17105.

摘要

报道了一种新型近红外响应光热转换试剂/液晶弹性体复合材料.目前绝大多数近红外吸收的无机金属纳米粒子，由于自身或其稳定剂（如长链硫醇或季铵盐）的化学性质，会致使经典的Finkelmann两步硅氢化加成反应中所使用的催化剂中毒失活，从而极大地限制了无机金属纳米粒子/液晶弹性体复合材料的拓展与应用.为了解决这一科学问题，我们采用了两步硫醇-烯点击化学快速制备单畴取向液晶弹性体薄膜的技术，将对近红外光有强吸收的油溶性硫化铜纳米粒子，成功地掺杂入聚硅氧烷液晶弹性体体系中，制备了近红外响应的硫化铜纳米粒子/液晶弹性体复合薄膜.通过使用紫外可见光谱、透射电子显微镜、扫描电子显微镜、偏光显微镜、示差扫描量热法、变温广角X射线散射对该复合材料进行了深入的研究，结果表明：该薄膜材料在980 nm近红外光源的照射下，可以实现高效的光热转换，从而实现快速、可逆的二维伸缩运动.

Abstract

We report a novel near-infrared-responsive photothermal conversion reagent/liquid crystal elastomer composite material. Nowadays

most of the near-infrared absorbing inorganic metal nanoparticles can poison platinum and other precious metal catalysts

due to the chemical properties of these metal nanoparticles or their stabilizers (such as long chain thiols

quaternary ammonium salts

etc

which cause the failure to prepare inorganic metal nanoparticle/liquid crystal elastomer composites through classical Finkelmann two-step hydrosilylation reaction. In order to solve this problem

we apply a fast two-step thiol-ene photoaddition technique

by embedding near-infrared-responsive copper sulfide nanoparticles into liquid crystal elastomer matrix

and a composite film

based on copper sulfide nanoparticle/liquid crystal elastomer with near-infrared-responsiveness

is successfully fabricated for the first time. Water-soluble CuS nanoparticles are first synthesized

and oil-soluble CuS nanoparticles are prepared by exchanging the sodium citrate stabilizer with poly(3-mercaptopropyl methylsiloxanes) (PMMS). The latter is mixed with PMMS

mesogenic monomers

crosslinkers and photoinitiators. The mixture is cast into a polytetrafluoroethylene mould and UV-illuminated at room temperature for 3 min to provide a pre-crosslinked liquid crystal elastomer composite film

which is further hung up and uniaxially stretched. The suspended pre-crosslinked liquid crystal elastomer film is UV-irradiated again at room temperature for another 15 min. to accomplish the second thiol-ene photo-crosslinking to obtain the composite film consisting of monodomain copper sulfide nanoparticle/liquid crystal elastomer. This composite material is thoroughly investigated using ultra-violet spectroscopy

transmission electron microscopy

polarized optical microscope

differential scanning calorimetry

and one-dimensional X-ray scattering. The experimental results demonstrate that this composite has a room-temperature nematic liquid crystal phase with a high-quality monodomain alignment. Most importantly

this composite film can perform a fast and reversible two-dimensional shrinking motion under irradiation of near infrared light with a wavelength of 980 nm .

关键词

光热转换液晶弹性体硫化铜纳米粒子近红外光硫醇-烯点击化学

Keywords

Photothermal conversionLiquid crystal elastomerCopper sulfide nanoparticlesNear infrared lightThiol-ene click chemistry

references

C Ohm , M Brehmer , R Zentel . Adv Mater , 2010 . 22 3366 - 3387 . DOI:10.1002/adma.200904059http://doi.org/10.1002/adma.200904059.

H Yu , T Ikeda . Adv Mater , 2011 . 23 2149 - 2180 . DOI:10.1002/adma.v23.19http://doi.org/10.1002/adma.v23.19.

T J White , D J Broer . Nat Mater , 2015 . 14 1087 - 1098 . DOI:10.1038/nmat4433http://doi.org/10.1038/nmat4433.

H Yang , G Ye , X Wang , P Keller . Soft Matter , 2011 . 7 815 - 823 . DOI:10.1039/C0SM00734Jhttp://doi.org/10.1039/C0SM00734J.

J Küpfer , H Finkelmann . Makromol. Chem Rapid Commun , 1991 . 12 717 - 726 . DOI:10.1002/marc.1991.030121211http://doi.org/10.1002/marc.1991.030121211.

J A Lv , Y Liu , J Wei , E Chen , L Qin , Y Yu . Nature , 2016 . 537 179 - 182 . DOI:10.1038/nature19344http://doi.org/10.1038/nature19344.

Y Yu , M Nakano , T Ikeda . Nature , 2003 . 425 145 - 145 . DOI:10.1038/425145ahttp://doi.org/10.1038/425145a.

M H Li , P Keller , B Li , X Wang , M Brunet . Adv Mater , 2003 . 15 569 - 572 . DOI:10.1002/adma.200304552http://doi.org/10.1002/adma.200304552.

T Ikeda , M Nakano , Y Yu , O Kanazawa , A Tsutsumi . Adv Mater , 2003 . 15 201 - 205 . DOI:10.1002/adma.200390045http://doi.org/10.1002/adma.200390045.

W Wu , L Yao , T Yang , R Yin , F Li , Y Yu . J Am Chem Soc , 2011 . 133 15810 - 15813 . DOI:10.1021/ja2043276http://doi.org/10.1021/ja2043276.

Z Jiang , M Xu , F Li , Y Yu . J Am Chem Soc , 2013 . 135 16446 - 16453 . DOI:10.1021/ja406020rhttp://doi.org/10.1021/ja406020r.

F Cheng , Y Zhang , R Yin , Y Yu . J Mater Chem , 2010 . 20 4888 - 4896 . DOI:10.1039/b926903ghttp://doi.org/10.1039/b926903g.

N Torras , K E Zinoviev , C J Camargo , E M Campo , H Campanella , J Esteve , P Teplicky . Sens Actuators A Phys , 2014 . 208 104 - 112 . DOI:10.1016/j.sna.2014.01.012http://doi.org/10.1016/j.sna.2014.01.012.

C J Camargo , H Campanella , J E Marshall , N Torras , K Zinoviev , E M Terentjev , J Esteve . Macromol Rapid Commun , 2011 . 32 1953 - 1959 . DOI:10.1002/marc.201100578http://doi.org/10.1002/marc.201100578.

J E Marshall , Y Ji , N Torras , K Zinoviev , E M Terentjev . Soft Matter , 2012 . 8 1570 - 1574 . DOI:10.1039/C1SM06656Khttp://doi.org/10.1039/C1SM06656K.

L Yang , K Setyowati , A Li , S Gong , J Chen . Adv Mater , 2008 . 20 2271 - 2275 . DOI:10.1002/adma.v20:12http://doi.org/10.1002/adma.v20:12.

R R Kohlmeyer , J Chen . Angew Chem Int Ed , 2013 . 52 9234 - 9237 . DOI:10.1002/anie.201210232http://doi.org/10.1002/anie.201210232.

C Li , Y Liu , X Huang , H Jiang . Adv Funct Mater , 2012 . 22 5166 - 5174 . DOI:10.1002/adfm.v22.24http://doi.org/10.1002/adfm.v22.24.

Y Ji , Y Y Huang , R Rungsawang , E M Terentjev . Adv Mater , 2010 . 22 3436 - 3440 . DOI:10.1002/adma.200904103http://doi.org/10.1002/adma.200904103.

C Li , Y Liu , C Lo , H Jiang . Soft Matter , 2011 . 7 7511 - 7516 . DOI:10.1039/c1sm05776fhttp://doi.org/10.1039/c1sm05776f.

M Wang , S Mir Sayed , L Guo , B Lin , X Zhang , Y Sun , H Yang . Macromolecules , 2016 . 49 663 - 671 . DOI:10.1021/acs.macromol.5b02388http://doi.org/10.1021/acs.macromol.5b02388.

Y Yang , W Zhan , R Peng , C He , X Pang , D Shi , T Jiang , Z Lin . Adv Mater , 2015 . 27 ( 41 ): 6376 - 6381 . DOI:10.1002/adma.201503680http://doi.org/10.1002/adma.201503680.

Y Sun , J S Evans , T Lee , B Senyuk , P Keller , S He , I I Smalyukh . Appl Phys Lett , 2012 . 100 241901 DOI:10.1063/1.4729143http://doi.org/10.1063/1.4729143.

H Yang , J Liu , Z Wang , L Guo , P Keller , B Lin , Y Sun , X Zhang . Chem Commun , 2015 . 51 12126 - 12129 . DOI:10.1039/C5CC02599Khttp://doi.org/10.1039/C5CC02599K.

J S Evans , Y Sun , B Senyuk , P Keller , Pergamenshchik , M V , T Lee , I I Smalyukh . Phys Rev Lett , 2013 . 110 ( 18 ): 187802 DOI:10.1103/PhysRevLett.110.187802http://doi.org/10.1103/PhysRevLett.110.187802.

X Liu , R Wei , P T Hoang , X Wang , T Liu , P Keller . Adv Funct Mater , 2015 . 25 ( 20 ): 3022 - 3032 . DOI:10.1002/adfm.201500443http://doi.org/10.1002/adfm.201500443.

X Liu , X Wang , T Liu , P Keller . Macromolecules , 2016 . 49 ( 21 ): 8322 - 8331 . DOI:10.1021/acs.macromol.6b01930http://doi.org/10.1021/acs.macromol.6b01930.

L Guo , M Liu , S Mir Sayed , B Lin , P Keller , X Zhang , Y Sun , H Yang . Chem Sci , 2016 . 7 4400 - 4406 . DOI:10.1039/C6SC00758Ahttp://doi.org/10.1039/C6SC00758A.

M Wang , B P Lin , H Yang . Nat Commun , 2016 . 7 13981 DOI:10.1038/ncomms13981http://doi.org/10.1038/ncomms13981.

W Liu , L Guo , B Lin , X Zhang , Y Sun , H Yang . Macromolecules , 2016 . 49 4023 - 4030 . DOI:10.1021/acs.macromol.6b00640http://doi.org/10.1021/acs.macromol.6b00640.

L Wang , W Liu , L Guo , B Lin , X Zhang , Y Sun , H Yang . Polym Chem , 2017 . 8 1364 - 1370 . DOI:10.1039/C6PY02096Hhttp://doi.org/10.1039/C6PY02096H.

M Zhou , M Tian , C Li . Bioconjug Chem , 2016 . 27 ( 5 ): 1188 - 1199 . DOI:10.1021/acs.bioconjchem.6b00156http://doi.org/10.1021/acs.bioconjchem.6b00156.

M Zhou , R Zhang , M Huang , W Lu , S Song , M P Melancon , C Li . J Am Chem Soc , 2010 . 132 15351 DOI:10.1021/ja106855mhttp://doi.org/10.1021/ja106855m.

S Zhang , Z Zha , X Yue , X Liang , Z Dai . Chem Commun , 2013 . 49 ( 60 ): 6776 - 6778 . DOI:10.1039/c3cc43440khttp://doi.org/10.1039/c3cc43440k.

X Liu , B Li , F Fu , K Xu , R Zou , Q Wang , B Zhang , Z Chen , J Hu . Dalton Trans , 2014 . 43 ( 30 ): 11709 - 11715 . DOI:10.1039/C4DT00424Hhttp://doi.org/10.1039/C4DT00424H.

H Bi , Y Dai , R Lv , C Zhong , F He , S Gai , A Gulzar , X Yang , P Yang . Dalton Trans , 2016 . 45 ( 12 ): 5101 - 5110 . DOI:10.1039/C5DT04842Ghttp://doi.org/10.1039/C5DT04842G.

Y Geng , Z Wang , B Lin , H Yang . Chem Eur J , 2016 . 22 18197 - 18207 . DOI:10.1002/chem.201603905http://doi.org/10.1002/chem.201603905.

L M Campos , I Meinel , R G Guino , M Schierhorn , N Gupta , G D Stucky , C J Hawker . Adv Mater , 2008 . 20 3728 - 3733 . DOI:10.1002/adma.v20:19http://doi.org/10.1002/adma.v20:19.

H Yang , M Liu , Y Yao , P Tao , B Lin , P Keller , X Zhang , Y Sun , L Guo . Macromolecules , 2013 . 46 3406 - 3416 . DOI:10.1021/ma400462ehttp://doi.org/10.1021/ma400462e.

M Wang , L Guo , B Lin , X Zhang , Y Sun , H Yang . Liq Cryst , 2016 . 43 1626 - 1635 . DOI:10.1080/02678292.2016.1191686http://doi.org/10.1080/02678292.2016.1191686.

X Wang , Z Fang , X Lin . J Nanopart Res , 2009 . 11 ( 3 ): 731 - 736 . DOI:10.1007/s11051-008-9480-2http://doi.org/10.1007/s11051-008-9480-2.

Dobson , D K. , I Visoly-Fisher , G Hodes , Cahen , D . Adv Mater , 2001 . 13 ( 19 ): 1495 - 1499 . DOI:10.1002/1521-4095(200110)13:19<>1.0.CO;2-Shttp://doi.org/10.1002/1521-4095(200110)13:19<>1.0.CO;2-S.

X L Yu , C B Cao , H S Zhu , Q S Li , C L Liu , Q H Gong . Adv Funct Mater , 2007 . 17 ( 8 ): 1397 - 1401 . DOI:10.1002/(ISSN)1616-3028http://doi.org/10.1002/(ISSN)1616-3028.

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Liquid Crystalline Vitrimer with Better Actuation Repeatability

Related Author

No data

Related Institution

The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University

CAS Key Laboratory of Bio-Inspired Materials and Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰