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功能有机分子化学国家重点实验室 兰州大学化学化工学院 兰州 730000
Published:20 March 2018,
Received:7 June 2017,
Revised:28 June 2017,
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Tao Li, Shao-yu Lv, Jiao Chen, Chun-mei Gao, Shao-fei Zhang, Ming-zhu Liu. Progress in Polymer-based Environment-responsive Fertilizers. [J]. Acta Polymerica Sinica 2018(3):336-348(2018)
Tao Li, Shao-yu Lv, Jiao Chen, Chun-mei Gao, Shao-fei Zhang, Ming-zhu Liu. Progress in Polymer-based Environment-responsive Fertilizers. [J]. Acta Polymerica Sinica 2018(3):336-348(2018) DOI: 10.11777/j.issn1000-3304.2017.17152.
随着农业现代化进程的不断推进和高分子材料的不断发展,环境响应性肥料作为一种新型的功能化肥料正受到越来越多研究者的关注.环境响应性肥料是指能够根据温度和土壤环境中特定的刺激响应信号来改变吸水、保水和养分释放等行为,从而达到智能调控土壤中水分和养分的新型多功能肥料.本文首先简要介绍了肥料的发展阶段,然后根据外界刺激信号的不同和肥料实际的应用效果,将环境响应性肥料分为温度响应性肥料、pH响应性肥料和盐敏感性肥料,并对其制备方法、刺激响应行为和应用领域进行了综述.可以预期,天然高分子基环境响应性肥料、多重响应性智能肥料和生物响应性肥料的制备及其应用研究将会成为今后肥料科学的发展趋势.
Mineral nutrients from environment are required for plants growing
but the natural nutrients from soil can not completely meet the need. Therefore
use of fertilizers is the simple
effective and fast method to increase the yield and to improve the quality of the grains. However
only a small amount of the fertilizers used can be effectively absorbed by crops
and most of them are lost by volatilizing into the atmosphere or leaching into the ground
which leads to a serious waste of the fertilizers with severe environmental pollution (
e.g.
acidic rain
soil salinization and greenhouse gas release
etc
.). To solve these problems
polymer-based slow-release fertilizers were developed by functional modification to control the release of the nutrients and to prolong the effective use of the fertilizer. However
the release behavior of these slow-release fertilizers is always influenced by some factors such as temperature
humidity
pH and salinization of soil in practical applications. To address this issue
intelligent fertilizer
i.e
. fertilizer with functional controlled-release
has been developed to regulate the release of various nutrients in accordance with the change of soil environment and the different stages of plant growth. Especially
polymer-based environment-responsive fertilizer
as an intelligent fertilizer
can change water absorbency
water-holding capacity and nutrient release behavior
by intelligently regulating water and nutrients in soil according to specific stimulus response signals of soil environment
such as temperature
humidity
pH value and ion concentration. This review briefly introduces the development stages of the fertilizer and their classification. On the basis of different stimulation signals from the environment and actual application
these environment-responsive fertilizers are classified as temperature-responsive
pH-responsive and salt-sensitive fertilizers. Their preparations
properties
stimulus-responsive behaviors and application are introduced in detail. Intelligentialization of the fertilizer is an important tendency in agriculture and horticulture field
and the polymer-based environment-responsive fertilizer has great potential in fertilizer development and application. With the development of agricultural modernization and polymer science
it can be expected that the preparation and application of the natural polymer-based responsive fertilizer
the multiple-responsive fertilizer and the biologically responsive fertilizer will be research trends in the fertilizer fields.
高分子基肥料功能化材料智能肥料环境响应智能调控
Polymer-based fertilizerFunctional materialsIntelligent fertilizerEnvironment-responsiveIntelligent regulation
Z Majeed , N K Ramli , N Mansor , Z Man . Rev Chem Eng , 2015 . 31 ( 1 ): 69 - 95 . https://www.journals.elsevier.com/chemical-engineering-science/.
W Liu , R Qiu . J Chem Technol Biot , 2007 . 82 ( 9 ): 781 - 786 . DOI:10.1002/(ISSN)1097-4660http://doi.org/10.1002/(ISSN)1097-4660.
D J Conley , H W Paerl , R W Hwarth , D F Boesch , S P Seitzinger , K E Havens , C Lancelot , G E Likens . Science , 2009 . 323 ( 5917 ): 1014 - 1015 . DOI:10.1126/science.1167755http://doi.org/10.1126/science.1167755.
P A Matson , R Naylor , I I Ortiz-Monasterio . Science , 1998 . 280 ( 5360 ): 112 - 115 . DOI:10.1126/science.280.5360.112http://doi.org/10.1126/science.280.5360.112.
S H Chien , L I Prochnow , S Tu , C Snyder . Nutr Cycl Agroecosyst , 2011 . 89 ( 2 ): 229 - 255 . DOI:10.1007/s10705-010-9390-4http://doi.org/10.1007/s10705-010-9390-4.
U Shavit , A Shaviv , G Shalit , D Zaslavsky . J Control Release , 1997 . 43 ( 2 ): 131 - 138 . https://link.springer.com/article/10.1007/s00343-017-6074-9.
Shengxiu Li . J Plant Nutr Fertilizer , 1999 . ( 3 ): 193 - 205 . DOI:10.11674/zwyf.1999.0301http://doi.org/10.11674/zwyf.1999.0301.
李 生秀 . 植物营养与肥料学报 , 1999 . ( 3 ): 193 - 205 . DOI:10.11674/zwyf.1999.0301http://doi.org/10.11674/zwyf.1999.0301.
R Liang , M Z Liu . J Agr Food Chem , 2006 . 54 ( 4 ): 1392 - 1398 . DOI:10.1021/jf052582fhttp://doi.org/10.1021/jf052582f.
L Wu , M Z Liu , R Liang . Bioresource Technol , 2008 . 99 ( 3 ): 547 - 554 . DOI:10.1016/j.biortech.2006.12.027http://doi.org/10.1016/j.biortech.2006.12.027.
L Wu , M Z Liu . Carbohyd Polym , 2008 . 72 ( 2 ): 240 - 247 . DOI:10.1016/j.carbpol.2007.08.020http://doi.org/10.1016/j.carbpol.2007.08.020.
R Liang , M Z Liu . Ind Eng Chem Res , 2006 . 45 ( 25 ): 8610 - 8616 . DOI:10.1021/ie060705vhttp://doi.org/10.1021/ie060705v.
M Y Guo , M Z Liu , F L Zhan , L Wu . Ind Eng Chem Res , 2005 . 44 ( 12 ): 4206 - 4211 . DOI:10.1021/ie0489406http://doi.org/10.1021/ie0489406.
B L Ni , M Z Liu , Y LüS . Chem Eng J , 2009 . 155 ( 3 ): 892 - 898 . DOI:10.1016/j.cej.2009.08.025http://doi.org/10.1016/j.cej.2009.08.025.
B L Ni , M Z Liu , Y LüS , L H Xie , X Zhang , Y F Wang . Ind Eng Chem Res , 2010 . 49 ( 10 ): 4546 - 4552 . DOI:10.1021/ie9019769http://doi.org/10.1021/ie9019769.
B L Ni , M Z Liu , Y LüS , L H Xie , Y F Wang . J Agr Food Chem , 2010 . 58 ( 23 ): 12373 - 12378 . DOI:10.1021/jf1029306http://doi.org/10.1021/jf1029306.
B Azeem , K Z KuShaari , Z B Man , A Basit , T H Thanh . J Control Release , 2014 . 181 11 - 21 . DOI:10.1016/j.jconrel.2014.02.020http://doi.org/10.1016/j.jconrel.2014.02.020.
C E Husby , A X Niemiera , J R Harris , R D Wright . Hortscience , 2003 . 38 ( 3 ): 387 - 389 . http://www.hort.vt.edu/rharris/pubs.html.
P Tlustos , A M Blackmer . Soil Sci Soc Am J , 1992 . 56 ( 6 ): 1807 - 1810 . DOI:10.2136/sssaj1992.03615995005600060026xhttp://doi.org/10.2136/sssaj1992.03615995005600060026x.
H Ewen , T Jahns . Recent Res Dev Microbiol , 2000 . 4 ( 2 ): 537 - 546.
Bao Xianyang(鲍先扬), Amjad A, Qiao Dongling(乔冬玲), Liu Hongsheng(刘宏生), Chen Ling(陈玲), Yu Long(余龙). Acta Polymerica Sinica(高分子学报), 2015, (9): 1010 − 1019
X Yin , A S Hoffman , P S Stayton . Biomacromolecules , 2006 . 7 ( 5 ): 1381 - 1385 . DOI:10.1021/bm0507812http://doi.org/10.1021/bm0507812.
Haixuan Zhang , Xun Meng , Ping Li . Progress in Chemistry , 2008 . 20 ( 5 ): 657 - 672 . http://manu56.magtech.com.cn/progchem/CN/abstract/abstract10514.shtml.
张 海璇 , 孟 旬 , 李 平 . 化学进展 , 2008 . 20 ( 5 ): 657 - 672 . http://manu56.magtech.com.cn/progchem/CN/abstract/abstract10514.shtml.
D Roy , J N Cambre , B S Sumerlin . Prog Polym Sci , 2010 . 35 ( 1 ): 278 - 301 . http://www.oalib.com/references/9025312.
X G Wang , Y LüS , C M Gao , X B Xu , Y Wei , X Bai , C Feng , N N Gao , M Z Liu , L Wu . RSC Adv , 2014 . 4 ( 35 ): 18382 - 18390 . DOI:10.1039/c4ra00207ehttp://doi.org/10.1039/c4ra00207e.
X G Wang , S Y Lü , C M Gao , X B Xu , X J Zhang , X Bai , M Z Liu , L Wu . Chem Eng J , 2014 . 252 404 - 414 . DOI:10.1016/j.cej.2014.04.097http://doi.org/10.1016/j.cej.2014.04.097.
S Y Lü , C M Gao , X G Wang , X B Xu , X Bai , N N Gao , C Feng , Y Wei , L Wu , M Z Liu . RSC Adv , 2014 . 4 ( 93 ): 51208 - 51214 . DOI:10.1039/C4RA06006Ghttp://doi.org/10.1039/C4RA06006G.
S Y Lü , C Feng , C M Gao , X G Wang , X B Xu , X Bai , N N Gao , M Z Liu . J Agr Food Chem , 2016 . 64 ( 24 ): 4965 - 4974 . DOI:10.1021/acs.jafc.6b01133http://doi.org/10.1021/acs.jafc.6b01133.
Y F Wang , M Z Liu , B L Ni , L H Xie , X Zhang . J Macromol Sci A , 2011 . 48 ( 10 ): 806 - 815 . DOI:10.1080/10601325.2011.603629http://doi.org/10.1080/10601325.2011.603629.
L H Xie , Y LüS , M Z Liu , C M Gao , X G Wang , L Wu . J Agr food Chem , 2013 . 61 ( 14 ): 3382 - 3388 . DOI:10.1021/jf4004016http://doi.org/10.1021/jf4004016.
L H Xie , M Z Liu , .L Ni , Y F Wang . J Agr Food Chem , 2012 . 60 ( 28 ): 6921 - 6928 . DOI:10.1021/jf3001235http://doi.org/10.1021/jf3001235.
E Daly , B R Saunders . Langmuir , 2000 . 16 ( 13 ): 5546 - 5552 . DOI:10.1021/la991292ohttp://doi.org/10.1021/la991292o.
Gaoxiang Pan , Ze Feng , Jia Wei , Yanlei Yu . Acta Chimica Sinica , 2013 . 71 ( 5 ): 733 - 738 . http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract331412.shtml.
潘 高翔 , 冯 泽 , 韦 嘉 , 俞 燕蕾 . 化学学报 , 2013 . 71 ( 5 ): 733 - 738 . http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract331412.shtml.
M Bradley , B Vincent , N Warren , J Eastoe , A Vesperinas . Langmuir , 2006 . 22 ( 1 ): 101 - 105 . DOI:10.1021/la0523053http://doi.org/10.1021/la0523053.
H Dalmont , O Pinprayoon , B R Saunders . Langmuir , 2008 . 24 ( 6 ): 2834 - 2840 . DOI:10.1021/la703597ahttp://doi.org/10.1021/la703597a.
Shouxin Liu , Yu Fang , Mingzhu Liu , Mingzhen Wang , Zhuanrong Wang . Acta Chimica Sinica , 2006 . 64 ( 15 ): 1575 - 1580 . DOI:10.3321/j.issn:0567-7351.2006.15.011http://doi.org/10.3321/j.issn:0567-7351.2006.15.011.
刘 守信 , 房 喻 , 柳 明珠 , 王 明珍 , 王 转绒 . 化学学报 , 2006 . 64 ( 15 ): 1575 - 1580 . DOI:10.3321/j.issn:0567-7351.2006.15.011http://doi.org/10.3321/j.issn:0567-7351.2006.15.011.
Zhen Wang , Dongsheng Guo , Jie Zhang , Yu Liu . Acta Chimica Sinica , 2012 . 70 ( 16 ): 1709 - 1715 . http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract325735.shtml.
王 振 , 郭 东升 , 张 捷 , 刘 育 . 化学学报 , 2012 . 70 ( 16 ): 1709 - 1715 . http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract325735.shtml.
Z Y Ma , X Jia , J M Hu , Z Y Liu , H Y Wang , F Zhou . J Agric Food Chem , 2013 . 61 12232 - 12237 . DOI:10.1021/jf4038826http://doi.org/10.1021/jf4038826.
Y Zhang , X Y Liang , X G Yang , H Y Liu , J M Yao . ACS Sustain Chem Eng , 2014 . 2 ( 7 ): 1871 - 1878 . DOI:10.1021/sc500204zhttp://doi.org/10.1021/sc500204z.
Dongdong Cheng , Guizhe Zhao , Yaqing Liu , Shuaiqun Hao . J Soil Water Conservation , 2013 . 27 ( 6 ): 216 - 220 . http://www.plantnutrifert.org/CN/abstract/abstract4179.shtml.
程 冬冬 , 赵 贵哲 , 刘 亚青 , 郝 率群 . 水土保持学报 , 2013 . 27 ( 6 ): 216 - 220 . http://www.plantnutrifert.org/CN/abstract/abstract4179.shtml.
Hongtao Zou , Yanyu Han , Yuling Zhang , Yi Huang , Minjian Cao , Yulong Zhang . Chinese J Soil Sci , 2009 . ( 2 ): 321 - 324.
邹 洪涛 , 韩 艳玉 , 张 玉玲 , 黄 毅 , 曹 敏建 , 张 玉龙 . 土壤通报 , 2009 . ( 2 ): 321 - 324.
A Jarosiewicz , M Tomaszewska . J Agr Food Chem , 2003 . 51 ( 2 ): 413 - 417 . DOI:10.1021/jf020800ohttp://doi.org/10.1021/jf020800o.
B L Ni , M Z Liu , Y LüS , L H Xie , Y F Wang . J Agr Food Chem , 2011 . 59 ( 18 ): 10169 - 10175 . DOI:10.1021/jf202131zhttp://doi.org/10.1021/jf202131z.
C W Du , J M Zhou , A Shaviv . J Polym the Environ , 2006 . 14 ( 3 ): 223 - 230 . DOI:10.1007/s10924-006-0025-4http://doi.org/10.1007/s10924-006-0025-4.
C Adams , J Frantz , B Bugbee . J Plant Nutr Soil Sci , 2013 . 176 ( 1 ): 76 - 88 . DOI:10.1002/jpln.201200156http://doi.org/10.1002/jpln.201200156.
J H Guo , X J Liu , Y Zhang , J L Shen , W X Han , W F Zhang . Science , 2010 . 327 ( 5968 ): 1008 - 1010 . DOI:10.1126/science.1182570http://doi.org/10.1126/science.1182570.
R Lal . Soil Till Res , 1997 . 42 145 DOI:10.1016/S0167-1987(97)00006-8http://doi.org/10.1016/S0167-1987(97)00006-8.
M Wang , G L Zhang , L L Zhou , D F Wang , N Q Zhong , D Q Cai , Z Y Wu . ACS Sustain Chem Eng , 2016 . 4 ( 12 ): 6800 - 6808 . DOI:10.1021/acssuschemeng.6b01761http://doi.org/10.1021/acssuschemeng.6b01761.
M R Hill , E J MacKrell , C P Forsthoefel , S P Jensen , M S Chen , G A Moore , Z L He , B S Sumerlin . Biomacromolecules , 2015 . 16 1276 - 1280 . DOI:10.1021/acs.biomac.5b00069http://doi.org/10.1021/acs.biomac.5b00069.
Z Y Ma , X Jia , G X Zhang , J M Hu , X L Zhang , Z Y Liu , H Y Wang , F Zhou . J Agric Food Chem , 2013 . 61 5474 - 5482 . DOI:10.1021/jf401102ahttp://doi.org/10.1021/jf401102a.
C Feng , Y LüS , C M Gao , X G Wang , X B Xu , X Bai , N N Gao , M Z Liu , L Wu . ACS Sustain Chem Eng , 2015 . 3 ( 12 ): 3157 - 3166 . DOI:10.1021/acssuschemeng.5b01384http://doi.org/10.1021/acssuschemeng.5b01384.
D D Cheng , G Z Zhao , T Bai , Y Q Liu . J Chem Soc Pakistan , 2014 . 36 ( 4 ): 647 - 653.
Dongdong Cheng , Wuhong Dou , Guizhe Zhao , Yaqing Liu . J Basic Sci Eng , 2015 . ( 3 ): 484 - 492 . http://www.chinaagrisci.com/article/2016/0578-1752-49-20-3958.html.
程 冬冬 , 窦 午红 , 赵 贵哲 , 刘 亚青 . 应用基础与工程科学学报 , 2015 . ( 3 ): 484 - 492 . http://www.chinaagrisci.com/article/2016/0578-1752-49-20-3958.html.
P Wen , Z S Wu , Y H He , B C Ye , Y J Han , J Wang , X Y Guan . ACS Sustain Chem Eng , 2016 . 4 6572 - 6579 . DOI:10.1021/acssuschemeng.6b01466http://doi.org/10.1021/acssuschemeng.6b01466.
X G Wang , Y LüS , C M Gao , C Feng , X B Xu , X Bai , N N Gao , J L Yang , M Z Liu , L Wu . ACS Sustain Chem Eng , 2016 . 4 2068 - 2079 . DOI:10.1021/acssuschemeng.5b01494http://doi.org/10.1021/acssuschemeng.5b01494.
H J Dai , H H Huang . J Agr Food Chem , 2017 . 65 565 - 574 . DOI:10.1021/acs.jafc.6b04899http://doi.org/10.1021/acs.jafc.6b04899.
W Wang , A Wang . Carbohydr Polym , 2010 . 80 1028 - 1036 . DOI:10.1016/j.carbpol.2010.01.020http://doi.org/10.1016/j.carbpol.2010.01.020.
G R Mahdavinia , M J Zohuriaan-Mehr , A Pourjavadi . Polym Adv Technol , 2004 . 15 173 - 180 . DOI:10.1002/(ISSN)1099-1581http://doi.org/10.1002/(ISSN)1099-1581.
X D Li , Q Li , Y Su , Q Y Yue , B Y Gao , Y J Su . Taiwan Inst Chem Eng , 2015 . 55 170 - 179 . DOI:10.1016/j.jtice.2015.04.022http://doi.org/10.1016/j.jtice.2015.04.022.
F Ghassemi , A J Jakeman , H A Nix . Salinisation of Land and Water Rresources:Human Causes, Extent, Management and Case Studies , : Australia Univ New South Wales Press , 1995 . 1 - 3.
Yibing Qian , Huarong Zhou . J Soil Water Conservation , 2004 . 18 ( 2 ): 186 - 188 . http://www.geog.com.cn/CN/10.11821/xb200506011.
钱 亦兵 , 周 华荣 . 水土保持学报 , 2004 . 18 ( 2 ): 186 - 188 . http://www.geog.com.cn/CN/10.11821/xb200506011.
X H Xu , X Y Su , B Bai , H L Wang , Y R Suo . RSC Adv , 2016 . 6 103199 - 103209 . DOI:10.1039/C6RA22668Jhttp://doi.org/10.1039/C6RA22668J.
T K Giri , M Pradhan , D K Tripathi . Turk J Chem , 2016 . 40 ( 2 ): 283 - 295 . https://pubs.acs.org/doi/abs/10.1021/cm950549a.
K M El Salmawi , S M Ibrahim . Macromol Res , 2011 . 19 ( 10 ): 1029 - 1034 . DOI:10.1007/s13233-011-1006-6http://doi.org/10.1007/s13233-011-1006-6.
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