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Thermadapt Shape Memory Polymer
- Acta Polymerica Sinica Issue 11, Pages: 1715-1724(2017)
- 作者机构：
浙江大学化学工程与生物工程学院 化学工程联合国家重点实验室 杭州 310027
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2017.17161
CLC：Published：20 November 2017，
Received：19 June 2017，
Revised：20 July 2017，
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Zheng Ning, Xie Tao. Thermadapt Shape Memory Polymer. [J]. Acta Polymerica Sinica (11):1715-1724(2017)
Zheng Ning, Xie Tao. Thermadapt Shape Memory Polymer. [J]. Acta Polymerica Sinica (11):1715-1724(2017) DOI： 10.11777/j.issn1000-3304.2017.17161.
摘要
动态共价交联聚合物的研究具有悠久的历史，其早期的工作着眼于如何解决应力松弛带来的聚合物材料力学性能降低的问题.20世纪90年代以来，利用动态共价键来主动设计聚合物网络的特殊可适性逐渐成为研究主流，其中包括自修复和重加工性.然而，受到动态共价键的种类、通用性及所实现功能的特异性等限制，对于动态共价交联聚合物网络的研究尚停留在基础阶段.本文以本课题组近期在动态共价交联形状记忆聚合物的研究为基础，结合其他相关工作，展示了通用共价键（酯键及氨酯键）的动态可逆性，并利用其设计了具有特殊性能和潜在商业化价值的形状记忆聚合物.在此基础上，我们提出分子结构设计及宏观性能均不同于传统热塑性和热固性形状记忆聚合物的第3类形状记忆聚合物，即热适性形状记忆聚合物.
Abstract
As a class of smart materials
shape memory polymers have gained considerable interest in recent years due to their unique shape changing behaviors. Recent advances in shape memory polymer field have led to the emergence of various exciting applications
including deployable biomedical devices and aerospace structures. Beyond the traditional shape memory effect (one way dual-shape memory effect)
the recently emerged properties (triple-
multi-and two way shape memory effects) have drastically expanded their potential application. However
these properties focus mainly on the temporary shape manipulation
and the attention on the permanent shapes has been largely ignored. Unlike the classical thermoplastic and thermoset shape memory polymers
the recently emerged shape memory polymers with dynamic covalent bonds in the network have opened up new opportunities in manipulating its permanent shape. Dynamic covalent polymer networks have long been recognized. Early work focused mainly on minimizing stress relaxation in commercial network polymers to improve their mechanical properties. Since 1990's
the attention has been shifted towards purposeful design of dynamic covalent polymer networks with unique adaptive properties
including self-healing and thermoset reprocessing properties. Several new terms (dynamer
CAN
and vitrimer) have been proposed to emphasize the uniqueness of these polymer networks with dynamic covalent bonds. However
these past efforts have been mostly limited to basic research due to the inherently niche chemistry involved. In this article
we briefly overview recent progresses in dynamic covalent polymer networks and shape memory polymers
which sets the stage for further discussion on recently emerged dynamic covalent shape memory polymer networks. On account of the general applicability of the dynamic covalent bonds (
e.g.
esters and urethanes) involved as well as unique macroscopic properties (solid state plasticity)
we propose that dynamic covalent shape memory polymers can form a third class of shape memory polymers
thermadapt shape memory polymers
alongside the widely known thermoplastic and thermoset shape memory polymers.
关键词
形状记忆聚合物动态可逆交联应力松弛
Keywords
Dynamic covalent bondShape memory polymerStress relaxation
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