<italic style="font-style: italic">In situ</italic> Polymerization of PEDOT: <italic style="font-style: italic">π</italic>-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells

Xiao Yu-juan; He Qian-nan; Zhou Huan-yu; Xu Hai-tao; Tan Li-cheng; Chen Yi-wang

doi:10.11777/j.issn1000-3304.2018.17215

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In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells

Research Article | 更新时间：2021-01-26

- In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells
- Acta Polymerica Sinica Issue 2, Pages: 257-265(2018)
- 作者机构：
  
  1.南昌大学化学学院南昌 330031
  2.江西省新能源化学重点实验室/高分子研究所南昌 330031
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.17215
  CLC：
- Published：20 February 2018，
  
  Received：4 August 2017，
  
  Revised：26 August 2017，
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Xiao Yu-juan, He Qian-nan, Zhou Huan-yu, Xu Hai-tao, Tan Li-cheng, Chen Yi-wang. In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells. [J]. Acta Polymerica Sinica (2):257-265(2018)
DOI：

Xiao Yu-juan, He Qian-nan, Zhou Huan-yu, Xu Hai-tao, Tan Li-cheng, Chen Yi-wang. In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells. [J]. Acta Polymerica Sinica (2):257-265(2018) DOI： 10.11777/j.issn1000-3304.2018.17215.

摘要

以带磺酸基团的

共轭聚电解质为模板，采用化学氧化还原方法制备了在水相中稳定分散的聚（3，4-乙烯二氧噻吩）（PEDOT）与聚电解质的复合物，并用作聚合物太阳能电池的空穴传输层.通过傅里叶变换红外光谱（FTIR）、紫外可见光谱（UV-Vis）、紫外光电子能谱（UPS）、原子力显微镜（AFM）、透射电子显微镜（TEM）和接触角等对聚（3，4-乙烯二氧噻吩）：聚苯乙烯磺酸（PEDOT：PSS）和复合物薄膜的形貌和光电性能进行测试与表征.结果表明，相比于PEDOT：PSS，PEDOT：聚电解质复合物作为空穴传输层，具有合适的能级结构、高达95%的透光率（30 nm）、更疏水的表面形貌以及更高的空穴迁移率，有利于与活性层形成欧姆接触并提高空穴的注入和收集效率，进而提高器件的光伏性能.

Abstract

Poly(3

4-ethylenedioxythiophene) (PEDOT) is usually dispersed in water by incorporating polystyrene sulfonate (PSS) as a charge compensator and a template for polymerization. The polymerization behavior of 3

4-ethylenedioxythiophene (EDOT) without assistance of insulating PSS was explored. Due to their semiconducting and hydrophilic characteristics

-conjugated polyelectrolytes with sulfonic acid groups

namely PCPDT-T and PCPDT-2T

were used as template for

in situ

oxidative polymerization of PEDOT. The obtained PEDOT:polyelectrolyte composites showed good dispersibility in aqueous solution

which was used as hole transport layer (HTL) in polymer solar cells (PSCs). The morphologies and photoelectric properties of PEDOT:PSS and PEDOT:polyelectrolyte composites were characterized by Fourier transform infrared spectroscopy

ultraviolet-visible spectroscopy

ultraviolet photoelectron spectroscopy

atomic force microscopy

transmission electron microscopy and contact angle test

respectively. PEDOT:polyelectrolyte composites displayed suitable energy level

transmittance up to 95% (30 nm)

hydrophobic surface morphology

as well as superior hole mobility

which were in favour of forming Ω contact with the active layer and increasing the injection and collection efficiency of the holes. Thus

improving the device photovoltaic performance. The current density-voltage (J-V) characteristics of the PSCs with the structure of Glass/ITO/HTL/PTB7-Th:PC

BM/PFN/Al were measured under one standard sun by solar simulator with an Air Mass 1.5 global (AM 1.5G) and an irradiation intensity of 100 mW/cm

. Compared to the photovoltaic characteristics for PEDOT:PSS based device

PSCs with PEDOT:T (1:2) as HTL yielded the highest power conversion efficiency (PCE) of 8.6% with a short current density (

) of 18.07 mA/cm

open circuit voltage (

) of 0.77 and fill factor (FF) of 61.31%

respectively. Compared to that of PEDOT:PSS

the obvious increased

for PEDOT:polyelectrolyte composites based PSCs was ascribed to the high hole mobility and transmittance

which were consistent with the results from the space-charge limited current (SCLC) method and the external quantum efficiency (EQE) measurement.

关键词

聚(3 4-乙烯二氧噻吩)聚电解质原位聚合聚合物太阳能电池复合材料

Keywords

Poly (3 4-ethylenedioxythiophene)PolyelectrolyteIn situ polymerizationPolymer solar cellsComposite

references

C K Chiang , C R J Fincher , Y W Park , A J Heeger , H Shirakawa , E J Louis , S C Gau , A G MacDiarmid . Phys Rev Lett , 1977 . 39 1098 - 1101 . DOI:10.1103/PhysRevLett.39.1098http://doi.org/10.1103/PhysRevLett.39.1098.

V N Sheemol , B TyagvI , R V Jasra . J Mol Catal A Chem , 2006 . 252 194 - 201 . DOI:10.1016/j.molcata.2006.01.068http://doi.org/10.1016/j.molcata.2006.01.068.

L Groenendaal , F Jonas , D Freitag , H Pielartzik , J R Reynolds . Adv Mater , 2000 . 12 481 - 494 . DOI:10.1002/(ISSN)1521-4095http://doi.org/10.1002/(ISSN)1521-4095.

S Kirchmeyer , K Reuter . J Mater Chem , 2005 . 15 2077 - 2088 . DOI:10.1039/b417803nhttp://doi.org/10.1039/b417803n.

J Ouyang , C W Chu , F C Chen , Q Xu , Y Yang . Adv Funct Mater , 2005 . 15 203 - 208 . DOI:10.1002/(ISSN)1616-3028http://doi.org/10.1002/(ISSN)1616-3028.

A I Hofmann , W T T Smaal , M Mumtaz , D D Katsigiannopoulos , D C Brochon , F Brochon , D O R Hild , H D E Cloutet , P D G Hadziioannou . Angew Chem Int Ed , 2015 . 127 8626 - 8630 . DOI:10.1002/ange.201503024http://doi.org/10.1002/ange.201503024.

Y Tao , K Yuan , T Chen , P Xu , H Li , R Chen , C Zheng , L Zhang , W Huang . Adv Mater , 2014 . 26 7931 - 7958 . DOI:10.1002/adma.v26.47http://doi.org/10.1002/adma.v26.47.

T Heumueller , W R Mateker , A Distler , U F Fritze , R Cheacharoen , W H Nguyen , M Biele , M Salvador , M von Delius , H J Egelhaaf , M D McGehee , C J Brabec . Energy Environ Sci , 2016 . 9 247 - 256 . DOI:10.1039/C5EE02912Khttp://doi.org/10.1039/C5EE02912K.

C Zuo , H J Bolink , H Han , J Huang , D Cahen , L Ding . Adv Sci , 2016 . 3 1500324 DOI:10.1002/advs.201500324http://doi.org/10.1002/advs.201500324.

D Alemu , H Y Wei , K C Ho , C W Chu . Energy Environ Sci , 2012 . 5 9662 - 9671 . DOI:10.1039/c2ee22595fhttp://doi.org/10.1039/c2ee22595f.

K Nara , K Seyoung , H L Seoung , H L Byoung , H K Yung , R J Yong , J K Bong , L Kwanghee . Adv Mater , 2014 . 26 2268 - 2272 . DOI:10.1002/adma.v26.14http://doi.org/10.1002/adma.v26.14.

W Meng , R Ge , Z F Li , J H Tong , T F Liu , Q Zhao , S X Xiong , F Y Jiang , L Mao , Y H Zhou . ACS Appl Mater Interfaces , 2015 . 7 14089 - 14094 . DOI:10.1021/acsami.5b03309http://doi.org/10.1021/acsami.5b03309.

F J Lim , K Ananthanarayanan , J Luther , G W Ho . J Mater Chem , 2012 . 22 25057 - 25064 . DOI:10.1039/c2jm35646ehttp://doi.org/10.1039/c2jm35646e.

G Fang , S Wu , Z Xie , Y Geng , L Wang . Macromol Chem Phys , 2011 . 212 1846 - 1851.

B Kadem , W Cranton , A Hassan . Org Electron , 2015 . 24 73 - 79 . DOI:10.1016/j.orgel.2015.05.019http://doi.org/10.1016/j.orgel.2015.05.019.

M G Han , S H Foulger . Chem Commun , 2005 . 1 3092 - 3094.

X Zhang , J-S Lee , G S Lee , D-K Cha , M J Kim , D J Yang , S K Manohar . Macromolecules , 2006 . 39 470 - 472 . DOI:10.1021/ma051975chttp://doi.org/10.1021/ma051975c.

D Hohnholz , A G MacDiarmid , D M Sarno , W E J Jr . Chem Commun , 2001 . 23 2444 - 2445.

X Du , Z Wang . Electrochim Acta , 2003 . 48 1713 - 1717 . DOI:10.1016/S0013-4686(03)00143-9http://doi.org/10.1016/S0013-4686(03)00143-9.

Y D Li , M Y Liu , Y Li , K Yun , L J Xu , W Wu , R F Chen , X Q Qin , H L Yip . Adv Energy Mater , 2016 . 6 1601499 .

Yonghong Deng , Zhuoxi Li , Xueqing Qiu , Dacheng Zhao . Acta Polymerica Sinica , 2015 . ( 5 ): 589 - 595 . http://www.gfzxb.org/CN/abstract/abstract14336.shtml.

邓永红 , 黎卓熹 , 邱学青 , 赵大成 . 高分子学报 , 2015 . ( 5 ): 589 - 595 . http://www.gfzxb.org/CN/abstract/abstract14336.shtml.

H T Xu , X Fu , X F Cheng , L Q Huang , D Zhou , L Chen , Y W Chen . J Mater Chem A , 2017 . 5 14689 - 14696 . DOI:10.1039/C7TA02590Dhttp://doi.org/10.1039/C7TA02590D.

H Dan , G Yang , J Song , L Niu , A Ivaska . J Electroanal Chem , 2007 . 602 24 - 28 . DOI:10.1016/j.jelechem.2006.11.027http://doi.org/10.1016/j.jelechem.2006.11.027.

S Braun , W R Salaneck , M Fahlman . Adv Mater , 2009 . 21 1450 - 1472 . DOI:10.1002/adma.v21:14/15http://doi.org/10.1002/adma.v21:14/15.

Y J Cheng , C H Hsieh , P J Li , C S Hsu . Adv Funct Mater , 2011 . 21 1723 - 1732 . DOI:10.1002/adfm.201002502http://doi.org/10.1002/adfm.201002502.

H Zhou , Y Zhang , C K Mai , S D Collins , T Q Nguyen , G C Bazan , A J Heeger . Adv. Mater , 2014 . 26 780 - 785 . DOI:10.1002/adma.201302845http://doi.org/10.1002/adma.201302845.

S A Chen , M Y Hua . Macromolecules , 1993 . 26 7108 - 7110 . DOI:10.1021/ma00077a066http://doi.org/10.1021/ma00077a066.

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Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University

Department of Ophthalmology, Zhongda Hospital, Southeast University

Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University

State Key Laboratory of Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications

University of Chinese Academy of Sciences

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In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells

DOI：10.11777/j.issn1000-3304.2018.17215

摘要

Abstract

关键词

Keywords

references