Polymers with Aggregation-induced Emission Characteristics

Rong Hu; De-hua Xin; An-jun Qin; Ben Zhong Tang

doi:10.11777/j.issn1000-3304.2018.17280

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Polymers with Aggregation-induced Emission Characteristics

Feature Articles | 更新时间：2021-01-26

- Polymers with Aggregation-induced Emission Characteristics
- Acta Polymerica Sinica Issue 2, Pages: 132-144(2018)
- 作者机构：
  
  1.华南理工大学发光材料与器件国家重点实验室广州 510640
  2.香港科技大学化学系国家人体组织功能重建工程技术研究中心-香港分中心香港
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.17280
  CLC：
- Published：20 February 2018，
  
  Received：6 October 2017，
  
  Revised：11 November 2017，
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Rong Hu, De-hua Xin, An-jun Qin, Ben Zhong Tang. Polymers with Aggregation-induced Emission Characteristics. [J]. Acta Polymerica Sinica (2):132-144(2018)
DOI：

Rong Hu, De-hua Xin, An-jun Qin, Ben Zhong Tang. Polymers with Aggregation-induced Emission Characteristics. [J]. Acta Polymerica Sinica (2):132-144(2018) DOI： 10.11777/j.issn1000-3304.2018.17280.

摘要

聚集诱导发光（AIE）的研究已经成为化学和材料等领域的一个前沿.目前，AIE领域的研究重点主要集中于小分子方面，而具有良好成膜性和协同放大效应的AIE聚合物的研究仍有待进一步发展.其制备方法，构效关系以及相对于小分子的性能和应用独特性还有待进一步体现.该专论较系统性地总结了AIE聚合物的制备方法，介绍了AIE聚合物的构效关系及在传感和生物医药等领域的应用，并对AIE聚合物的未来发展进行了展望.

Abstract

Organic luminescent materials have played important roles in optoelectronic device

chemo-/biosensing

and biomedical applications. However

traditional luminescent materials always suffer from the aggregation-caused quenching (ACQ) effect:they are highly emissive in dilute solutions but their emission becomes weaker or totally quenched in the practical application forms

i.e. the aggregate

film and solid states. The ACQ effect has greatly limited the applications of these luminescent materials in many fields. Exactly opposite to the ACQ

the aggregation-induced emission (AIE) can actively utilize the natural aggregation process of a molecule to provide intense emission in the aggregate and solid states. In the AIE area

the research is focusing on the low mass molecules

and the polymers have been paid less attention although they possess the unique properties such as good film-forming ability

amplification effect of the signals

and multiple functionalization

which facilitates their practical applications. In this review

we first accounted the used polymerizations for the construction of AIE polymers

such as polycouplings

radical polymerization

and click polymerizations. Next

we discussed the structure-property relationship of the AIE polymers based on the systematically investigation of the effect of substituent groups

the link of TPE and fluorene groups on the triazole rings

the attachment of TPE-diethynyl groups on phenyl rings with

and

-positions

and the side-chains on their photo-physical properties. Moreover

the interesting non-conjugated AIE polymers without aromatic rings were also discussed and cluster oluminescence was proposed as the cause for this unique emission. Finally

the applications of the AIE polymers in chemo-and biosensors

and tracing were reviewed and the advantages of AIE polymers over AIE low-mass molecules were also emphasized. It is expected that this review could serve as a trigger for future innovation in the AIE research area.

关键词

聚集诱导发光聚合物聚合方法学构效关系高技术应用

Keywords

Aggregation-induced emissionPolymerPolymerization methodologyStructure-property relationshipHigh-tech application

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