浏览全部资源
扫码关注微信
Advance in Ion Exchange and Adsorption Resins in China
增强出版- Acta Polymerica Sinica Vol. 0, Issue 7, Pages: 814-828(2018)
- 作者机构：
1.南京大学环境学院 有机毒物污染控制与资源化国家工程技术研究中心 南京 210023
2.南开大学高分子化学研究所 吸附分离功能高分子材料教育部重点实验室 天津 300071
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2018.17317
CLC：Published：2018-7，
Received：22 November 2017，
Revised：30 November 2017，
扫 描 看 全 文
Quan-xing Zhang, Zheng-pu Zhang, Ai-min Li, Bing-cai Pan, Xiao-lin Zhang. Advance in Ion Exchange and Adsorption Resins in China. [J]. Acta Polymerica Sinica 0(7):814-828(2018)
Quan-xing Zhang, Zheng-pu Zhang, Ai-min Li, Bing-cai Pan, Xiao-lin Zhang. Advance in Ion Exchange and Adsorption Resins in China. [J]. Acta Polymerica Sinica 0(7):814-828(2018) DOI： 10.11777/j.issn1000-3304.2018.17317.
摘要
1949年以来，我国离子交换与吸附树脂领域在一代代科研工作者的不懈努力下取得了飞速发展，先后发展了凝胶树脂、大孔树脂、超高交联树脂、复合功能树脂及树脂基复合吸附剂等五代树脂，广泛应用于国防工业、医药卫生、精细化工、湿法冶金以及环境保护等领域，在我国不同发展时期均做出了突出贡献. 本文总结了半个多世纪以来我国离子交换与吸附树脂领域发展的主要历程，重点回顾了以“中国离子交换树脂之父”何炳林先生为代表的离子交换与吸附事业先驱的历史贡献，并对离子交换与吸附树脂近年来的最新发展动向与成果进行简要介绍.
Abstract
Since 1949
China has been witnessing a rapid development in ion exchange and adsorption technology. Up to date
at least five generations of polymeric resins have been developed
including gel-type resin
macroporous resin
hyper-cross-linked resin
bifunctional resin and resin-based composite adsorbent. These resin-based materials have been widely utilized in various industries
including military defense
medical and health
fine chemicals
hydrometallurgy
environmental protection
making considerable contributions to the modernization of China. In brief
gel-type resin
characterized by non-porous nature
was first developed for uranium extraction and later expanded to other fields such as water softening. Due to abundant porous structure
macroporous resin exhibited faster ion exchange rate and higher mechanical strength over the gel-type one. A variety of macroporous adsorption resins were developed and widely utilized in separation and/or purification in the industries of food
chemicals
rare elements
drugs
toxins
and environmental remediation. Hyper-cross-linked resin was mainly prepared
via
Friedel-Crafts reaction
possessing ultra-high specific surface area (usually high than 800 m
2
/g) and abundant microporous structure. Hyper-cross-linked resins have been successfully applied for hemoperfusion purpose
representing one of the most promising adsorbents for organic pollutants in chemical industry effluents. Bifunctional resins were designed for adsorptive removal of highly water-soluble organic pollutants from industrial effluents
because they could offer multiple interactions with target pollutants such as
π
-
π
interaction
electrostatic attraction
hydrophobic interaction and hydrogen bonds. In the past decade
resin-based composite adsorbents
including resin-supported nanocomposite and magnetic resin
were obtained by integrating resin hosts with inorganic (nano) particles for advanced (waste) water treatment. The present review summarizes the development of ion exchange and adsorption resins in China since its foundation
particularly focusing on the historic contributions of Prof. Binglin He
the father of China’s ion exchange resins
to the progress of ion exchange and adsorption technology in China. Also
it provides an outlook of the perspective of ion exchange and adsorption resins in emerging applications.
关键词
离子交换与吸附树脂凝胶树脂大孔树脂超高交联树脂复合功能树脂树脂基复合吸附剂
Keywords
Ion exchange and adsorption resinGel-type resinMacroporous resinHyper-cross-linked resinBifunctional resinResin-based composite adsorbent
references
Zhang Quanxing(张全兴). Modern Ion Exchange and Adsorption Technology Preface(现代离子交换与吸附技术序). Beijing(北京): Tsinghua University Press(清华大学). 2015
Xu Jiami(徐家鼏). Chemical World(化学世界), 1954, 9(8):339 – 341
Xu Jiami(徐家鼏).Chin Pharm Bull(药学通报), 1954, 2(10): 420-422
Xu Jiami(徐家鼏). Chemical World(化学世界), 1955, 10(4): 158-161
He Binglin(何炳林), Qian Tingbao(钱庭宝). Polymer Communications(高分子通讯), 1957, 1(4): 195-209
He Binglin(何炳林). Chemistry(化学通报), 1957, (5): 4-12
Ion Exchange Resin Research Center Liaison Station(离子交换树脂研究中心联络站). Polymer Communications(高分子通讯), 1958, 2(3): 197-200
Kunin R, Myers R J. Ion Exchange Resins. New York: John Wiley & Sons, 1951
Kunin R, Myers R J. Ion Exchange Resins. Translated by Zhu Xiuchang(朱秀昌). Beijing(北京): Science Press(科学出版社), 1960
Rao Guoxuan(饶国宣). Chemical World(化学世界), 1981, (5): 133-135
Chen Yiyong(陈义镛), Xu Chengwei(许承威). Polymer Communications(高分子通讯), 1980, 4: 254
He Binglin(何炳林). Polymer Communications(高分子通讯), 1959, 3(5): 219 – 224
He Binglin(何炳林), Qian Tingbao(钱庭宝). Journal of Chemistry(化学学报), 1959, 25(6): 360 – 365
He Binglin(何炳林), Qian Tingbao(钱庭宝), Zhang Quanxing(张全兴), Lin Xiaoyuan(林孝元). Journal of Nankai University (Natural Science)(南开大学学报(自然科学)), 1964, 5(2): 103-118
He Binglin(何炳林), Qian Tingbao(钱庭宝), Chen Weizhu(陈伟朱). Atomic Energy Science and Technology(原子能科学技术), 1964, 5: 515-522
He Binglin(何炳林), Zhang Zhenpu(张政朴), Qian Tingbao(钱庭宝), Chen Hongbin(陈洪彬), Guo Xianquan(郭贤权), Shi Zuoqing(史作清), Pei Guangwen(裴广文). Polymer Communications(高分子通讯), 1982, 4: 278-283
He Binglin(何炳林), Zhang Zhengpu(张政朴), Qian Tingbao(钱庭宝), Shi Zuoqing(史作清), Guo Xianquan(郭贤权), Chen Hongbin(陈洪彬). Polymer Communications(高分子通讯), 1983, (5): 351-355
Zhang Quanxing(张全兴), Li Aimin(李爱民), Pan Bingcai(潘丙才). Polymer Bulletin(高分子通报), 2015, (9): 21 – 43
Yan Husheng(阎虎生), Cheng Xiaohui(程晓辉), Ni Aiguo(倪爱国), He Binglin(何炳林). Weakly Acidic Cation Exchange Resin(弱酸性阳离子交换树脂). China patent, CN93105858.9. 1993-05-27
Yan Husheng(阎虎生), Cheng Xiaohui(程晓辉), Ni Aiguo(倪爱国), He Binglin(何炳林). Production Technology of Weak Acidic Cation Exchange Resin(弱酸性阳离子交换树脂生产工艺). China patent, CN92114550.0. 1992-12-19
Nankai University(南开大学). Synthetic Materials(合成材料), 1976, (4): 13
Shenyang Institute of Chemical Engineering and Technical Information(沈阳市化工研究所技术情报窒). Shenyang Chemical Industry(沈阳化工), 1976, (6): 42-50
North China Pharmaceutical Factory(华北制药厂). Pharmaceutical Industry(医药工业), 1976, (3): 28
Yuan Zhi(袁直), Yang Defu(杨德富), Shen Lihua(申丽华), He Binglin(何炳林). Science Bulletin(科学通报), 1996, 41(21): 1957-195
Yuan Zhi(袁直), Yang Defu(杨德富), Shen Lihua(申丽华), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1996, 12(1): 56-60
Shi Zuoqing(史作清). Journal of Henan University (Medical Edition)(河南大学学报(医学版)), 2007, 26(1): 1-5
Merrifield R B. J Am Chem Soc, 1963, 85: 2149 – 2154
Chen Zhenbo(陈振波). Amino Acid Communication(氨基酸通讯), 1977, (8): 34-83
Merrifield M R . Federation Proc , . 1962 . 21 412 .
Miertus S, Fassina G. Combinatorial Chemistry and Technology. New York: Marcel Dekker, Inc., 1999
He Binglin(何炳林), Chen Weizhu(陈伟朱), Liu Keliang(刘克良), Zong Jianchao(宗建超), Li Naihong(李乃宏). Chinese Science B Series(中国科学B辑), 1985, (12): 1071-1080
Jiang Ying(蒋英), Liang Xun(梁逊), Chen Weizhu(陈伟朱), He Binglin(何炳林). Journal of Chemistry(化学学报), 1987, (11): 1112-1118
Ren Qisheng(任启生), Huang Wenqiang(黄文强), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1989, (3): 203-205
Liu Keliang(刘克良), He Binglin(何炳林), Xiao Shaobo(萧绍博), Xia Qiming(夏启明), Fang Xi(方溪), Wang Zhongyi(王忠义). Chinese Science B Series(中国科学B辑), 1990, (2): 163-169
He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Shi Rongfu(施荣富), Wang Jianying(王建英). Journal of Chemistry in Colleges and Universities(高等学校化学学报), 1981, 2(3): 397-399
He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Chen Changzhi(陈长治), Shi Rongfu(施荣富), Wang Jianying(王建英). Polymer Communications(高分子通讯), 1980, (6): 328-334
He Binglin(何炳林), Zhang Quanxing(张全兴), Li Xiaobai(李效白), Shi Rongfu(施荣富), Shi Zuoqing(史作清), Guo Xianquan(郭贤权), Zhu Xiaolun(朱孝伦), Wang Jianying(王建英). Polymer Communications(高分子通讯), 1986, (5): 353-359
He B L, Zhang Q X, Li X B, Shi R F, Shi Z Q, Guo X Q, Zhu X L, Wang J Y. Chinese J Polym Sci, 1986, (3): 220-228
Zhang Quanxing(张全兴), Shi Rongfu(施荣富), Zhu Xiaolun(朱孝伦), Cui Futong(崔福通), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1986, 2(1): 26-33
Zhang Quanxing(张全兴), Yan Husheng(阎虎生), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1986, 2(3): 8-17
Zhang Quanxing(张全兴), Yan Husheng(阎虎生), He Binglin(何炳林). Journal of Chemistry in Colleges and Universities(高等学校化学学报), 1987, 8(10): 946-951
Yan Husheng(阎虎生), Zhang Quanxing(张全兴), He Binglin(何炳林). Ion Exchange and Adsorption(离子交换与吸附), 1988, 4(3): 167-171
Zhang Quanxing(张全兴), Chen Jinlong(陈金龙), Xu Zhaoyi(许昭怡), Pan Bingcai(潘丙才), Li Aimin(李爱民), Zhang Weiming(张炜铭), Han Yongzhong(韩永忠). Polymer Bulletin(高分子通报), 2005, (4): 116-121
Fei Zhenghao(费正皓), Chen Jinlong(陈金龙), Li Aimin(李爱民), Liu Fuqiang(刘福强), Zhang Quanxing(张全兴). Applied Chemistry(应用化学), 2003, 20(11): 1062-1065
Zhang W M, Xu Z W, Pan B C, Lv L, Zhang Q J, Zhang Q R, Du W, Pan B J, Zhang Q X . J Colloid Interface Sci. , . 2007 . 311 ( 2 ): 382 - 390 . DOI:10.1016/j.jcis.2007.03.005http://doi.org/10.1016/j.jcis.2007.03.005 .
Pan B C, Du W, Zhang W M, Zhang X, Zhang Q R, Pan B J, Lv L, Zhang Q X, Chen J L . Environ Sci Technol , . 2007 . 41 ( 14 ): 5057 - 5062 . DOI:10.1021/es070134dhttp://doi.org/10.1021/es070134d .
Davankov V, Tsyurupa M . Pure Appl Chem , . 1989 . 11 ( 61 ): 1881 - 1888.
Technical information station of Shanghai Pharmaceutical Industry Research Institute(上海医药工业研究院技术情报站). Pharmaceutical Industry(医药工业), 1975, (6): 65-66
Chen C Z, Zhang Q X, Yu Y T, He B L, Qian S C, Chang H Z, Song J C. In: Proceedings of the fifth International Symposium on Hemoperfusion and Artificial Organs. China Academic Publishers.1985. 350
Qian Shaocheng(钱绍诚), Song Jichang(宋继昌), Chen Changzhi(陈长治), Yang Xiaoming(杨晓明), Yu Yaoting(俞耀庭). Chinese Journal of Internal Medicine(中华内科杂志), 1985, 24(5): 296 – 298
Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(3): 262-269
Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(4): 370-376
Yu Jie(于杰), Guo Xianquan(郭贤权). Ion Exchange and Adsorption(离子交换与吸附), 2013, 29(5): 468-472
Zhang Quanxing(张全兴), Xu Wei(徐伟), Jing Xiang(荆和祥), Zhou Xisheng(周希圣), Cai Jianguo(蔡建国), Liu Shiyou(刘世友), He Binglin(何炳林), Xu Hulong(徐虎龙), Fan Xiaolan(范晓兰). Journal of Jiangsu Institute of Chemical Technology(江苏化工学院学报), 1989, 1(3): 74-83
Zhang Quanxing(张全兴), Xu Wei(徐伟), Jing Hexiang(荆和祥), Zhou Xisheng(周希圣), Fan Zhengming(范正明), Xu Hulong(徐虎龙), Fan Xiaolan(范晓兰), Kuang Monan(匡墨南), Zhu Wei(朱伟), Li Ming(李明). Pollution Control Technology(污染防治技术), 1992, 5(3): 35-39
Zhang Quanxing(张全兴), Zhou Xisheng(周希圣), Yan Wenyao(严文瑶), Zhou Qingrong(周庆荣), Zhang Dianlan(张殿兰), Tu Yaoqing(屠尧卿), Hu Jiaxian(胡家先). Jiangsu Chemical Industry(江苏化工), 1989, (1): 41-43
Zhang Quanxing(张全兴), Qiu Zhaorong(裘兆蓉), Zhou Xisheng(周希圣), Yan Wenyao(严文瑶), Jing Hexiang(荆和祥), Tan Hong(谈红), Liu Jianping(刘建平), Song Changgen(宋长根), He Binglin(何炳林), Yang Hengfu(杨恒富), Xue Xinmei(薛新美). Ion Exchange and Adsorption(离子交换与吸附), 1989, 5(2): 95-101
Feng W G, Zhang Q X, Chen J L, Xu Z Y, Pan B C, Su X . Chinese Journal of Reactive Polymers , . 1999 . 8 ( 1-2 ): 68 - 75.
Cheng Ling(承玲), Xu Zhengwen(许正文), Han Qing(韩青), Shi Jing(史静), Lu Jiangang(陆建刚), Zhao Yunlong(赵云龙), Li Fengying(李凤英), Chen Mindong(陈敏东). Polymer Bulletin(高分子通报), 2014, (3): 23-29
Li Aimin(李爱民), Zhang Quanxing(张全兴), Liu Fuqiang(刘福强), Fei Zhenghao(费正皓), Wang Xuejiang(王学江), Chen Jinlong(陈金龙). Ion Exchange and Adsorption(离子交换与吸附), 2001, 17(6): 515-525
Fei Zhenghao(费正皓), Chen Jinlong(陈金龙), Cai Jianguo(蔡建国), Li Aimin(李爱民), Zhang Quanxing(张全兴). Technology and Equipment for Environmental Pollution Control(环境污染治理技术与设备), 2003, 4(12): 17-22
Li A M, Zhang Q X, Wu H S, Zhai Z C, Liu F Q, Fei Z H, Long C, Zhu Z L, Chen J L . Adsorpt Sci Technol , . 2004 . 22 ( 10 ): 807 - 819 . DOI:10.1260/0263617053499005http://doi.org/10.1260/0263617053499005 .
Sun Y, Li X T, Xu C, Chen J L, Li A M, Zhang Q X . J Environ Sci-China , . 2005 . 17 ( 4 ): 584 - 588.
Pan B C, Zhang Q X, Meng F W, Li X T, Zhang X, Zheng J Z, Zhang W M, Pan B J, Chen J L . Environ Sci Technol , . 2005 . 39 ( 9 ): 3308 - 3313 . DOI:10.1021/es048548jhttp://doi.org/10.1021/es048548j .
Xu C, Long C, Li A M, Liu F Q, Yang W B, Zhang Q X . Adsorpt Sci Technol , . 2006 . 24 ( 1 ): 65 - 77 . DOI:10.1260/026361706778062559http://doi.org/10.1260/026361706778062559 .
Zhang Quanxing(张全兴), Chen Jinlong(陈金龙) , Li Aimin(李爱民), Yang Weiben(杨维本). Acta Polymerica Sinica(高分子学报), 2008, (7): 651-655
Zhang Quanxing(张全兴), Li Aimin(李爱民), Liu Fuqiang(刘福强), Fei Zhenghao(费正皓), Pan Bingcai(潘丙才), Long Chao(龙超), Chen Jinlong(陈金龙). Synthesis of Super Crosslinked Weakly Basic Anion Exchange Resin With Double Functions(具有双重功能的超高交联弱碱阴离子交换树脂的合成方法). China patent, ZL 01134143.2. 2001-11-05
Zhang L D, Fang M . Nano Today , . 2010 . 5 ( 2 ): 128 - 142 . DOI:10.1016/j.nantod.2010.03.002http://doi.org/10.1016/j.nantod.2010.03.002 .
Masciangioli T M, Zhang W X . Abstr Pap Am Chem S , . 2003 . 225 U952 - U952.
Colvin V L . Nat Biotechnol , . 2003 . 21 ( 10 ): 1166 - 1170 . DOI:10.1038/nbt875http://doi.org/10.1038/nbt875 .
Zhao X, Lv L, Pan B C, Zhang W M, Zhang S J, Zhang Q X . Chem Eng J , . 2011 . 170 ( 2-3 ): 381 - 394 . DOI:10.1016/j.cej.2011.02.071http://doi.org/10.1016/j.cej.2011.02.071 .
Zhang Q J, Pan B C, Chen X Q, Zhang W M, Pan B J, Zhang Q X, Lü L, Zha X S. Sci China Ser B, 2008, 51(4): 379-385
Pan B C, Pan B J, Chen X Q, Zhang W M, Zhang X, Zhang Q J, Zhang Q X, Chen J L . Water Res , . 2006 . 40 ( 15 ): 2938 - 2946 . DOI:10.1016/j.watres.2006.05.028http://doi.org/10.1016/j.watres.2006.05.028 .
Pan B J, Wu J, Pan B C, Lv L, Zhang W M, Xiao L L, Wang X S, Tao X C, Zheng S R . Water Res , . 2009 . 43 ( 17 ): 4421 - 4429 . DOI:10.1016/j.watres.2009.06.055http://doi.org/10.1016/j.watres.2009.06.055 .
Hua M, Xiao L L, Pan B C, Zhang Q X . Front Environ Sci Eng , . 2013 . 7 ( 3 ): 435 - 441 . DOI:10.1007/s11783-013-0508-1http://doi.org/10.1007/s11783-013-0508-1 .
Jiang Z M, Lv L, Zhang W M, Du Q O, Pan B C, Yang L, Zhang Q X . Water Res , . 2011 . 45 ( 6 ): 2191 - 2198 . DOI:10.1016/j.watres.2011.01.005http://doi.org/10.1016/j.watres.2011.01.005 .
Pan B C, Xu J S, Wu B, Li Z G, Liu X T . Environ Sci Technol , . 2013 . 47 ( 16 ): 9347 - 9354 . DOI:10.1021/es401710qhttp://doi.org/10.1021/es401710q .
Pan B C, Li Z G, Zhang Y Y, Xu J S, Chen L, Dong H J, Zhang W M . Chem Eng J , . 2014 . 248 290 - 296 . DOI:10.1016/j.cej.2014.02.093http://doi.org/10.1016/j.cej.2014.02.093 .
Bolto B, Dixon D, Eldridge R, King S, Linge K . Water Res , . 2002 . 36 ( 20 ): 5057 - 5065 . DOI:10.1016/S0043-1354(02)00231-2http://doi.org/10.1016/S0043-1354(02)00231-2 .
Bolto B, Dixon D, Eldridge R . React Funct Polym , . 2004 . 60 171 - 182 . DOI:10.1016/j.reactfunctpolym.2004.02.021http://doi.org/10.1016/j.reactfunctpolym.2004.02.021 .
Drikas M, Dixon M, Morran J . Water Res , . 2011 . 45 ( 4 ): 1539 - 1548 . DOI:10.1016/j.watres.2010.11.024http://doi.org/10.1016/j.watres.2010.11.024 .
Gan X J, Karanfil T, Bekaroglu S S K, Shan J H . Water Res , . 2013 . 47 ( 3 ): 1344 - 1352 . DOI:10.1016/j.watres.2012.11.049http://doi.org/10.1016/j.watres.2012.11.049 .
Shuang C D, Pan F, Zhou Q, Li A M, Li P H, Yang W B . Ind Eng Chem Res , . 2012 . 51 ( 11 ): 4380 - 4387 . DOI:10.1021/ie201488ghttp://doi.org/10.1021/ie201488g .
Shuang C D, Li P H, Li A M, Zhou Q, Zhang M C, Thou Y . Water Res , . 2012 . 46 ( 14 ): 4417 - 4426 . DOI:10.1016/j.watres.2012.05.052http://doi.org/10.1016/j.watres.2012.05.052 .
Wang Q J, Li A M, Wang J N, Shuang C D . J Environ Sci China , . 2012 . 24 ( 11 ): 1891 - 1899 . DOI:10.1016/S1001-0742(11)61066-8http://doi.org/10.1016/S1001-0742(11)61066-8 .
Wang Q J, Shi P, Ma Y, Li A M, Wang J N, Ma R, Chen X . Chem Eng J , . 2014 . 254 230 - 236 . DOI:10.1016/j.cej.2014.03.103http://doi.org/10.1016/j.cej.2014.03.103 .
Shi P, Ma R, Zhou Q, Li A M, Wu B, Miao Y, Chen X, Zhang X X . J. Hazard Mater , . 2015 . 285 53 - 60 . DOI:10.1016/j.jhazmat.2014.09.047http://doi.org/10.1016/j.jhazmat.2014.09.047 .
Wang J, Li H B, Li A M, Shuang C D, Zhou Q . Chem Eng J , . 2014 . 253 237 - 242 . DOI:10.1016/j.cej.2014.05.060http://doi.org/10.1016/j.cej.2014.05.060 .
Zhang M C, Zhou Q, Zhou Y, Li A M, Shuang C D . Chin Chem Lett , . 2012 . 23 ( 11 ): 1267 - 1270 . DOI:10.1016/j.cclet.2012.09.007http://doi.org/10.1016/j.cclet.2012.09.007 .
Zhang X L, Cheng C, Qian J S, Lu Z D, Pan S Y, Pan B C . Environ Sci Technol , . 2017 . 51 ( 16 ): 9210 - 9218 . DOI:10.1021/acs.est.7b01608http://doi.org/10.1021/acs.est.7b01608 .
Chen Qun(陈群), He Mingyang(何明阳), Zhang Wenwen(张文雯), Zhang Weihong(张卫红). Bisphenol A Synthesis Catalyst and Its Preparation Method(双酚A合成催化剂及其制备方法). China patent, CN03113425.4. 2003-05-09
Chen Qun(陈群), He Mingyang(何明阳), Zhang Weihong(张卫红), Zhang Wenwen(张文雯). Storage Method of Catalyst for Bisphenol A Synthesis(双酚A合成催化剂贮存方法). China patent, CN03113424.6. 2003-05-09
He Mingyang(何明阳), He Hongyi(何洪一), Chen Qun(陈群), Qin Jinlai(秦金来). Macroporous Cation Exchange Resin and Preparation Method and Application in the Synthesis of Bisphenol A in Catalyst(大孔阳离子交换树脂及制备方法以及在合成双酚A催化剂中的用途). China patent, CN200410044962.3. 2004-06-07
Jiang W, Huang W, Chang N, Qi Y B, Zong X P, Li H, Zhang Q X . Polymer , . 2012 . 53 5476 - 5479 . DOI:10.1016/j.polymer.2012.09.044http://doi.org/10.1016/j.polymer.2012.09.044 .
Huang W, Cheng N, Qi Y B, Zhang T R, Jiang W, Li H, Zhang Q X . Polymer , . 2014 . 55 1491 - 1496 . DOI:10.1016/j.polymer.2014.01.054http://doi.org/10.1016/j.polymer.2014.01.054 .
0
Views
150
下载量
4
CSCD
- L-PDFDownload
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Publicity Resources
Related Articles
Related Author
Related Institution
- Postal code：100190
- Tel：010-62588927 Email：gfzxb@iccas.ac.cn
- Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8
京公网安备11010802024621 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.