Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells

Ya-zhi Liu; Liang Ding; Jiao Liu; Zheng-jin Yang; Tong-wen Xu

doi:10.11777/j.issn1000-3304.2018.18055

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Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells

Feature Articles | 更新时间：2021-01-26

- Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells
- Acta Polymerica Sinica Vol. 0, Issue 7, Pages: 797-813(2018)
- 作者机构：
  
  中国科学技术大学化学与材料科学学院　合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18055
  CLC：
- Published：2018-7，
  
  Received：10 February 2018，
  
  Revised：14 April 2018，
扫描看全文
Ya-zhi Liu, Liang Ding, Jiao Liu, Zheng-jin Yang, Tong-wen Xu. Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells. [J]. Acta Polymerica Sinica 0(7):797-813(2018)
DOI：

Ya-zhi Liu, Liang Ding, Jiao Liu, Zheng-jin Yang, Tong-wen Xu. Polyphenylene Oxide Based Ion Exchange Membranes for Fuel Cells. [J]. Acta Polymerica Sinica 0(7):797-813(2018) DOI： 10.11777/j.issn1000-3304.2018.18055.

摘要

离子交换膜凭借其对离子的选择透过性，可用于离子的分离、分级，在清洁生产、节能减排、能量转换等方面有着广泛的应用前景. 本文系统介绍了本课题组在以聚苯醚(PPO)为主链的离子交换膜的制备、结构和性能以及应用过程等方面的前沿性进展，并对亟待解决的问题和未来的发展方向做出展望. 基于PPO的阴、阳离子交换膜可通过引入侧链、交联、优化功能基团和掺杂等方法提高膜的电导率、溶胀率和机械强度等重要的性能，实现了离子膜功能的多样化及在燃料电池等方面的应用.

Abstract

Due to the unique ion transfer characteristics of ion exchange membranes (IEMs)

they can be used in the separation and classification of ionic systems. Hence

IEMs have a wide application prospect in clean production

energy conservation

emission reduction and energy conversion. Because of gradually depleted fossil fuel

the ever-increasing power demand of our modern lifestyle and the awareness of environment protection

the conversion and storage of energy from renewable sources (hydrogen

wind and solar energy

for instances) have attracted worldwide attention. For both fuel cells and aqueous organic redox flow batteries operated in neutral pH

ion exchange membranes are crucial in determining the internal resistance (conversion efficiency)

working life span of the former and the coulombic efficiency

cycle life of the latter. IEMs have great potential in diverse applications and play prominent roles in addressing energy and environment related issues. Over the past decade

the development of IEMs has attracted much research attention in terms of materials

preparation and applications

due to their academic and industrial values. In this review

we summarized the advanced research on polyphenylene oxide (PPO) polymer based ion exchange membranes. We introduced the membranes synthetic methods

polymer structures

key performances and application processes separately. Besides

we also discussed about the problems of the PPO based ion exchange membranes that should be solved and prospected the development direction in the future. As to the PPO based ion exchange membranes synthetic methods

we divided them into two parts

anion exchange membranes and cation exchange membranes

with a variety of methods enumerated

including introduction of side chains

polymers crosslinking

optimization of functional groups and doping to improve the performances

such as ion conductivity

swelling ratio

mechanical strength and other important performances of the PPO based exchange membranes. We also realized the diversification of the function of ion exchange membranes and application in fuel cells

etc

关键词

离子交换膜聚苯醚结构性能前景

Keywords

Ion exchange membranesPolyphenylene oxideStructurePropertiesProspect

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Liaoning Province Engineering Center of High Performance Resins

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