Green Fabrication of Flexible, Thermally Conductive Graphene-carbonized Chinese Art Paper Composite Film

Dan Xie; Chao Teng; Lei Jiang

doi:10.11777/j.issn1000-3304.2018.18087

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Green Fabrication of Flexible, Thermally Conductive Graphene-carbonized Chinese Art Paper Composite Film

Research Article | 更新时间：2021-01-26

- Green Fabrication of Flexible, Thermally Conductive Graphene-carbonized Chinese Art Paper Composite Film
- Acta Polymerica Sinica Vol. 0, Issue 11, Pages: 1460-1466(2018)
- 作者机构：
  
  1.北京航空航天大学化学学院仿生智能界面科学与技术教育部重点实验室　北京 100191
  2.青岛科技大学材料科学与工程学院　青岛 266042
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18087
  CLC：
- Published：2018-11，
  
  Received：21 March 2018，
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Dan Xie, Chao Teng, Lei Jiang. Green Fabrication of Flexible, Thermally Conductive Graphene-carbonized Chinese Art Paper Composite Film. [J]. Acta Polymerica Sinica 0(11):1460-1466(2018)
DOI：

Dan Xie, Chao Teng, Lei Jiang. Green Fabrication of Flexible, Thermally Conductive Graphene-carbonized Chinese Art Paper Composite Film. [J]. Acta Polymerica Sinica 0(11):1460-1466(2018) DOI： 10.11777/j.issn1000-3304.2018.18087.

摘要

基于柔韧吸水的天然宣纸和大球-小球复合球磨法剥离宏量高分散的水性石墨烯分散液，通过浸泡吸附-机械压缩-热处理路线，绿色制备了柔性导热石墨烯-碳化宣纸复合膜. 该石墨烯-碳化宣纸复合膜的电导率和热导率分别高达568 S/cm和258 W/mK，其红外热成像图片展现了好的热传输性能. 另外，该石墨烯-碳化宣纸复合膜具有良好的柔韧性，反复弯曲100次之后，其电阻基本不变.

Abstract

Highly thermal conductive and flexible materials are urgently required in the heat management of high-power electronic devices. In this work

a composite film with these required properties

based on graphene and carbonized Chinese art paper

is prepared through a green route. Graphite is directly exfoliated in water in the presence of polyvinylpyrrolidone surfactant into high-quality graphene through a combination of large and small ball milling. The exfoliated graphene is filled into the porous network of the flexible superhydrophilic Chinese art paper through immersion absorption. After drying

the immersed Chinese art paper is mechanically compressed and carbonized at high temperature

leading to a composite film of graphene and carbonized Chinese art paper. TEM shows that the exfoliated graphene nanoplatelets is of layered structure and has a diameter in the range of several hundreds of nanometers to several micrometers. Raman spectroscopy proves that the exfoliated graphene nanoplatelet has a few defects with a low intensity ratio of D peak to G peak (0.25). SEM image shows that the graphene nanoplatelets filled in Chinese art paper are interconnected

which provides continuous channels for phonon transport. Mechanical compression increases the mass density of the composite film and improves the contact between the graphene nanoplatelets. Raman spectroscopy proves that annealing at high temperature decreases the amount of SP

hybrid carbon. As a result

the resultant composite film of graphene and carbonized Chinese art paper shows excellent thermal conductivity of 258 W/mK

superior to previously reported RGO-polymer composites (0.8 – 19.5 W/mK). The interconnected three-dimensional microfiber network of the carbonized Chinese art paper imparts the composite film with good flexibility

superior to that of the pure graphene film. After 100 bending cycles

the electrical resistance of the composite film remains practically unchanged. Compared with the conventional chemical oxidation-thermal reduction

the present route is environment-friendly

which avoids the use of strong oxidizing acids and does not generate acidic waste water.

关键词

石墨烯宣纸球磨电导率热导率

Keywords

GrapheneChinese art paperBall millingElectrical conductivityThermal conductivity

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Anhui Province Key Laboratory of Environment-friendly Polymer Materials, School of Chemistry & Chemical Engineering, Anhui University

State Key Laboratory of Separation Membranes and Membrane Processes, School of Textile Science and Engineering, Tianjin Polytechnic University

College of Materials and Mechanical Engineering, Beijing Technology and Business University

College of Materials Science & Engineering, Beijing University of Chemical Technology

Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science & Technology

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