Enzyme Catalysis for RAFT Polymerization and Functionalization: a Sustainable Strategy for Synthesis of Precision Polymers

Hua-zhang Guo; Ze-sheng An

doi:10.11777/j.issn1000-3304.2018.18120

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Enzyme Catalysis for RAFT Polymerization and Functionalization: a Sustainable Strategy for Synthesis of Precision Polymers

Feature Articles | 更新时间：2021-01-26

- Enzyme Catalysis for RAFT Polymerization and Functionalization: a Sustainable Strategy for Synthesis of Precision Polymers
- Acta Polymerica Sinica Vol. 0, Issue 10, Pages: 1253-1261(2018)
- 作者机构：
  
  上海大学纳米化学与生物学研究所　上海 200444
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18120
  CLC：
- Published：2018-10，
  
  Received：14 May 2018，
  
  Revised：28 May 2018，
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Hua-zhang Guo, Ze-sheng An. Enzyme Catalysis for RAFT Polymerization and Functionalization: a Sustainable Strategy for Synthesis of Precision Polymers. [J]. Acta Polymerica Sinica 0(10):1253-1261(2018)
DOI：

Hua-zhang Guo, Ze-sheng An. Enzyme Catalysis for RAFT Polymerization and Functionalization: a Sustainable Strategy for Synthesis of Precision Polymers. [J]. Acta Polymerica Sinica 0(10):1253-1261(2018) DOI： 10.11777/j.issn1000-3304.2018.18120.

摘要

酶催化与可逆加成-断裂链转移(RAFT)聚合的结合是一种合成精密聚合物的可持续发展策略，近年来在高分子聚合领域引起了广泛的关注. 我们课题组在该领域开展了一系列工作. 酶催化引发的RAFT聚合可以在温和条件下高效合成分子量与构型可控且分散度低的聚合物. 酶催化除氧与酶催化引发的联用实现了在空气存在的条件下合成多嵌段及超高分子量聚合物. 此外，利用酶的催化多功能性实现了一酶三催化，用于规整聚合物的高效合成与生物点击化学修饰. 本文从以上3个方面介绍了酶催化用于RAFT聚合的研究现状，并对该方向的发展提出了前瞻性的预期.

Abstract

Enzymes are well-known biological catalysts able to catalyze chemical processes in a mild

efficient and selective manner. Controlled radical polymerization (CRP) techniques have revolutionized the field of polymer chemistry

enabling unprecedented access to various polymer architectures with controlled molar mass

topology

sequence

composition and functionality. The combination of enzyme catalysis and reversible addition-fragmentation chain transfer (RAFT) polymerization is a sustainable strategy for synthesis and functionalization of precision polymers

which has attracted extensive attention in the field of polymer syntheses in recent years. Our group has carried out the following series of work in this field. (i) Enzyme catalysis has been used to initiate RAFT polymerization for synthesis of well-defined polymers with controlled molar mass and low dispersity in benign solvents under mild conditions. (ii) Enzyme cascade catalysis has enabled the synthesis of multiblock and ultrahigh-molecular-weight (UHMW) polymers with oxygen tolerance. (iii) Interestingly

the promiscuity of enzyme can be employed for synthesis and functionalization of well-defined polymers

via

three different catalytic reactions mediated by one single enzyme. In this feature article

we highlight the recent development on enzyme catalysis for RAFT polymerization and functionalization. At last

perspectives in this field and some future research directions along this exciting theme are proposed.

关键词

酶催化RAFT聚合可控自由基聚合氧气耐受性功能化

Keywords

Enzyme catalysisRAFT polymerizationControlled radical polymerizationOxygen toleranceFunctionalization

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