Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials

Min Chen; Chang-le Chen

doi:10.11777/j.issn1000-3304.2018.18155

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Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials

Feature Articles | 更新时间：2021-01-26

- Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials
- Acta Polymerica Sinica Vol. 0, Issue 11, Pages: 1372-1384(2018)
- 作者机构：
  
  中国科学技术大学高分子科学与工程系　合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18155
  CLC：
- Published：2018-11，
  
  Received：3 July 2018，
  
  Revised：6 August 2018，
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Min Chen, Chang-le Chen. Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials. [J]. Acta Polymerica Sinica 0(11):1372-1384(2018)
DOI：

Min Chen, Chang-le Chen. Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials. [J]. Acta Polymerica Sinica 0(11):1372-1384(2018) DOI： 10.11777/j.issn1000-3304.2018.18155.

摘要

近50年来，烯烃聚合的研究在学术界以及工业界都取得了巨大的成功. 聚烯烃年产量巨大、用途广泛，但是其最大的缺点之一是其非极性的特点. 在聚烯烃中引入少量的极性官能团可以极大地改善其性质、拓宽其用途、提高其商业价值. 通过过渡金属催化剂来实现烯烃与极性单体的共聚反应是合成官能团化聚烯烃材料最直接的途径，但是也具有非常大的挑战性. 针对极性单体这一科学问题，本专论主要围绕我们课题组的工作，从以下几个方面进行了论述：已知催化剂体系的改进、全新催化剂体系的发展、新型聚合调控手段的设计、特种聚烯烃以及官能团化聚烯烃材料的制备与性质研究.

Abstract

In the past 50 years

the studies of olefin polymerization have achieved great successes in both academia and industry. Polyolefins have huge annual production and wide applications. However

one of their biggest limitations is their nonpolar nature. The introduction of a small amount of polar and functionalized groups can greatly improve many properties

broaden their applications

and increase their business values. Transition metal catalyzed copolymerization of olefin with polar monomers is the most direct route to access polar and functionalized polyolefins

which is also highly challenging. With the " polar monomer problem” as the central theme

this account mainly focuses on the works from our own research group and describes the following topics: modification of existing catalyst systems

development of new catalyst systems

design of new polymerization modulation strategies

and the synthesis and property studies of special polyolefins and polar functionalized polyolefins materials.

关键词

官能团化聚烯烃极性单体烯烃共聚催化剂调控手段

Keywords

Polar functionalized polyolefinsPolar monomerOlefin copolymerizationCatalystsModulation strategies

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State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

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