Facile Preparation and Diverse Applications of Polymer Brush

Zhi-qin Wang; Chun Feng; Chen Ma; Xiao-yu Huang

doi:10.11777/j.issn1000-3304.2018.18199

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Facile Preparation and Diverse Applications of Polymer Brush

Feature Articles | 更新时间：2021-01-26

- Facile Preparation and Diverse Applications of Polymer Brush
- Acta Polymerica Sinica Vol. 0, Issue 12, Pages: 1467-1481(2018)
- 作者机构：
  
  中国科学院上海有机化学研究所　上海 200032
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18199
  CLC：
- Published：2018-12，
  
  Received：13 September 2018，
  
  Revised：10 October 2018，
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Zhi-qin Wang, Chun Feng, Chen Ma, Xiao-yu Huang. Facile Preparation and Diverse Applications of Polymer Brush. [J]. Acta Polymerica Sinica 0(12):1467-1481(2018)
DOI：

Zhi-qin Wang, Chun Feng, Chen Ma, Xiao-yu Huang. Facile Preparation and Diverse Applications of Polymer Brush. [J]. Acta Polymerica Sinica 0(12):1467-1481(2018) DOI： 10.11777/j.issn1000-3304.2018.18199.

摘要

当聚合物链通过稳定的共价或非共价键高密度地接枝到另一聚合物链、二维平面结构或球形或柱形的三维结构上时，这类聚合物体系分别称为一维、二维和三维聚合物分子刷. 与具有相似化学组成的线性聚合物相比，一维聚合物分子刷具有一些独特的性质，其中包括蠕虫状构象、紧凑的分子尺寸和链端效应. 将聚合物链引入平面、球形或圆柱形基体的表面不仅能显著地改变基体的表面性质，还可赋予所得杂化聚合物分子刷新的功能. 因此，聚合物分子刷在催化、纳米光刻、生物矿化、药物递送、医学诊断和光电子材料等领域具有十分广泛的应用. 虽然活性/可控聚合的出现为各种一维、二维和三维聚合物分子刷的制备提供了更高效的合成手段，但是具有精确组成、结构和功能的聚合物分子刷的高效可控制备仍然是该领域的关键挑战之一. 本文总结和评述了课题组近些年在发展一维、二维和三维聚合物分子刷的高效可控制备策略中取得的成果，并且通过相关实例展现了聚合物分子刷基材料在药物输送、防污涂料、催化和锂离子电池等领域的广阔应用前景.

Abstract

Polymer brush generally refers to a kind of special macromolecular structures

of which polymer chains are densely tethered to another polymer chain (one-dimension

1-D)

the surface of a planar (two-dimension

2-D)

a spherical or a cylindrical (three-dimension

3-D) solid matrice

via

stable covalent or non-covalent bond linkages

and can be divided into 1-D

2-D

and 3-D polymer brushes

respectively

depending on the substrates. Different from the corresponding linear counterpart with similar molecular composition

1-D polymer brush has some attractive properties including wormlike conformation

compact molecular dimension

and notable chain end effects due to its compact and densely grafted structure. The introduction of polymer chains onto the surface of a 2-D or 3-D matrix can not only improve surface-related properties of the matrix significantly

but also endow new functionalities with the obtained hybrid polymer brushes. Thus

polymer brush is of great interest in the fields of polymer and material science due to its potential applications in catalysis

nanolithography

biomineralization

drug delivery

medical diagnosis

optoelectronics

and so on. With the advent of living/controlled polymerization

organic

and supramolecular chemistry

a large number of 1-D

2-D and 3-D polymer brushes have been prepared. However

the development of highly efficient synthetic protocols for the preparation of polymer brush with precisely controlled composition

structure

and functionality remains a key challenge. Herein

we summarize our recent efforts on the development of efficient methods to prepare 1-D

2-D

and 3-D polymer brushes and the exploration of their potential applications in drug delivery

anti-fouling coating

catalysis

and lithium-ion battery.

关键词

聚合物分子刷活性聚合单体设计结晶驱动自组装聚合物复合体系

Keywords

Polymer brushLiving/controlled polymerizationMonomer designCrystallization-driven self-assemblyPolymer composite

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