Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly

Qi-quan Ye; Ming-xin Zheng; Xi Chen; Dan Li; Wei-guo Tian; Jun Zhang; Jin-ying Yuan

doi:10.11777/j.issn1000-3304.2018.18256

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Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly

Research Article | 更新时间：2021-01-26

- Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly
- Acta Polymerica Sinica Vol. 50, Issue 4, Pages: 344-351(2019)
- 作者机构：
  
  1.有机光电子与分子工程教育部重点实验室清华大学化学系　北京 100084
  2.中国科学院化学研究所中国科学院工程塑料重点实验室北京分子科学国家实验室　北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2018.18256
  CLC：
- Published：2019-4，
  
  Published Online：25 February 2019，
  
  Received：27 November 2018，
  
  Revised：16 January 2019，
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Qi-quan Ye, Ming-xin Zheng, Xi Chen, Dan Li, Wei-guo Tian, Jun Zhang, Jin-ying Yuan. Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly. [J]. Acta Polymerica Sinica 50(4):344-351(2019)
DOI：

Qi-quan Ye, Ming-xin Zheng, Xi Chen, Dan Li, Wei-guo Tian, Jun Zhang, Jin-ying Yuan. Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly. [J]. Acta Polymerica Sinica 50(4):344-351(2019) DOI： 10.11777/j.issn1000-3304.2018.18256.

摘要

具有光响应性的采用乙醇相分散共聚的方法将螺吡喃基团引入聚合原位自组装体系，合成了具有光响应性的聚甲基丙烯酸

-二甲基氨基乙酯-

-聚(甲基丙烯酸苄酯-

-甲基丙烯酸螺吡喃酯)(PDMA-

-P(BzMA-

-SPMA))共聚物组装体. 通过调节BzMA、SPMA和PDMA的投料比，制备了球形胶束、蠕虫状胶束、“章鱼”状组装体、囊泡、实心粒子等不同形貌的组装体. 所得组装体分散液具备良好的紫外响应显色性：在交替的UV(紫外)/可见光照射下，组装体分散液发生无色-蓝色的可逆转变. 使用光响应组装体墨水绘制的文字和图案可以实现在UV/可见光照射(或升温)下的可逆显示与隐藏. 这种方法可拓展应用于文字和图案的打印，实现精细图案的大批量快速制备. 二维光响应图案具备良好的稳定性，且光响应过程具备良好的可循环性.

Abstract

A series of spiropyrane-containing copolymer assemblies— poly(

-dimethylaminoethyl methacrylate)-

-poly{(benzyl methacrylate)-

-[1'-(2-methacryloxyethyl)-3'

3'-dimethyl-6-nitro-spiro(2

-1-benzo-pyran-2

2'-indoline)]} (PDMA-

-P(BzMA-

-SPMA)) were prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization-induced self-assembly (PISA)

where SPMA units act as the photo-responsive moieties

P(BzMA-

-SPMA) chains as the core-forming blocks

and PDMA chains as shell-forming blocks. First

PDMA was prepared by RAFT polymerization in ethanol at 80 °C. With PDMA as macro chain transfer agent

the RAFT PISA of BzMA and SPMA in ethanol at 70 °C were completed. By changing the feed ratios of BzMA

SPMA

and PDMA

diverse morphologies

such as spheres

worms

" octopus”-like structures

vesicles

and solid particles

were readily prepared. During UV irradiation

the absorbance maximum at 585 nm increased successively

suggesting the spiropyrane structure gradually isomerized into merocyanine structure. As a result

copolymer assembly dispersion underwent a colorless-to-colorful transformation. Subsequently

the colorful copolymer assembly dispersion was exposed to visible light. The results suggested that the absorbance maximum at 585 nm gradually decreased and the colorful copolymer assembly dispersion transformed into colorless. Using the copolymer assembly dispersion as ink

the characters and patterns were drawn on papers. Since the copolymer assembly dispersion was colorless

the characters and patterns were invisible. Upon UV irradiation

with spiropyrane isomerized into merocyanine

the characters and patterns changed to blue and visible

while upon visible light irradiation or heating

merocyanine structure isomerized into spiropyrane

which induced the characters and patterns to become colorless and invisible. Taking advantage of ink-jet printing

fine-patterned patterns and two-dimensional materials could be rapidly and massively produced

which also underwent reversible invisible-to-visible transformation

upon alternative UV irradiation and visible light irradiation/heating.

关键词

聚合诱导自组装螺吡喃光响应显色喷墨打印刺激响应

Keywords

Polymerization-induced self-assemblySpiropyranePhoto-responsive colorationInk-jet printingStimuli-response

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