Synthesis and Properties of Creosol-derived Polyimides

Jie Miao; Zhen Wang; Xiao-dong Ji; Jing-ling Yan

doi:10.11777/j.issn1000-3304.2019.18201

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Synthesis and Properties of Creosol-derived Polyimides

Research Article | 更新时间：2021-01-26

- Synthesis and Properties of Creosol-derived Polyimides
- Acta Polymerica Sinica Vol. 50, Issue 3, Pages: 261-270(2019)
- 作者机构：
  
  1.中国科学院长春应用化学研究所　长春 130022
  2.中国科学技术大学应用化学与工程学院　合肥 230026
  3.中国科学院宁波材料技术与工程研究所　宁波 315201
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.18201
  CLC：
- Published：2019-3，
  
  Published Online：15 November 2018，
  
  Received：21 September 2018，
  
  Revised：14 October 2018，
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Jie Miao, Zhen Wang, Xiao-dong Ji, Jing-ling Yan. Synthesis and Properties of Creosol-derived Polyimides. [J]. Acta Polymerica Sinica 50(3):261-270(2019)
DOI：

Jie Miao, Zhen Wang, Xiao-dong Ji, Jing-ling Yan. Synthesis and Properties of Creosol-derived Polyimides. [J]. Acta Polymerica Sinica 50(3):261-270(2019) DOI： 10.11777/j.issn1000-3304.2019.18201.

摘要

以木质素衍生物4-甲基愈创木酚为主要原料制备了3种生物基芳香二酐，并与石油基和生物基二胺聚合制备了3个系列的生物基聚酰亚胺，这些聚合物的生物基含量为31.8% ~ 56.4%. 利用FTIR、

H-NMR、DSC、DMTA、TGA和拉伸实验对聚合物的结构、热性能和力学性能进行了系统分析表征. 双醚型生物基聚酰亚胺(PI-I和PI-II系列)的玻璃化转变温度(

)在213 ~ 235 °C之间，5%热失重(

)在406 ~ 453 °C之间；含有二苯并二氧六环结构的生物基聚酰亚胺(PI-III系列)的

最高可达424 °C，

最高可达508 °C. 聚合物的拉伸强度、弹性模量和断裂伸长率分别为70 ~ 115 MPa、1.8 ~ 2.8 GPa和3.5% ~ 20.4%. 上述结果表明，基于4-甲基愈创木酚的生物基聚酰亚胺具有与石油基聚酰亚胺相当的热和机械性能.

Abstract

The development of high-performance polymers using bio-renewable feedstocks will promote a sustainable society. However

it remains a challenge to fabricate polyimides rich in bio-based component while high in heat resistance. In this work

three types of bio-based dianhydrides were synthesized using bio-renewable creosol as the raw material

which were then applied for preparing three series of polyimides

via

polycondensation with petroleum- or bio-based diamines. The molecular weights of these bio-based polyimides were in the range of 14 – 233 kg mol

−1

. The inherent viscosity of these polymers spanned a range 0.4 – 2.06 dL g

−1

. Most of the polyimides were soluble in common organic solvents

and flexible films could be readily cast from their solutions. The bio-based contents of these polymers ranged from 31.8% to 56.4%. The temperatures at 5% weight loss (

) and the glass transition temperatures (

) of bio-based polyetherimides (PI-I and PI-II series) were 406 – 453 °C and 213 – 235 °C

respectively

while PI-III series containing dioxin segments exhibited a

at 490 – 508 °C and

at 378 – 424 °C due to the existence of fused aromatic rings. The tensile strength

modulus

and elongation at break of these polyimides were 70 – 115 MPa

1.80 – 2.8 GPa

and 3.5% – 20.4%

respectively. The above mentioned results indicated comparable thermal and mechanical properties between the bio-based polyimies in this study and those made from petroleum-based monomers

such as Ultem

and Kapton

. Due to an excellent combination of high bio-based contents and outstanding thermal and mechanical properties

these polyimides showed great potential in various applications as films and engineering plastics

replacing petroleum-based polyimides.

关键词

生物基聚酰亚胺4-甲基愈创木酚二酐热和机械性能

Keywords

Bio-based polyimidesCreosolDianhydridesThermal and mechanical properties

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