Polyborosiloxane-based Photonic Elastomers with Self-healing Capability

Miao-miao Li; Quan-qian Lyu; Jin-tao Zhu; Lian-bin Zhang

doi:10.11777/j.issn1000-3304.2019.18213

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Polyborosiloxane-based Photonic Elastomers with Self-healing Capability

Research Article | 更新时间：2021-01-26

- Polyborosiloxane-based Photonic Elastomers with Self-healing Capability
- Acta Polymerica Sinica Vol. 50, Issue 3, Pages: 271-280(2019)
- 作者机构：
  
  华中科技大学化学与化工学院能量转换与存储材料化学教育部重点实验室　武汉 430074
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.18213
  CLC：
- Published：2019-3，
  
  Published Online：26 November 2018，
  
  Received：10 October 2018，
  
  Revised：3 November 2018，
扫描看全文
Miao-miao Li, Quan-qian Lyu, Jin-tao Zhu, Lian-bin Zhang. Polyborosiloxane-based Photonic Elastomers with Self-healing Capability. [J]. Acta Polymerica Sinica 50(3):271-280(2019)
DOI：

Miao-miao Li, Quan-qian Lyu, Jin-tao Zhu, Lian-bin Zhang. Polyborosiloxane-based Photonic Elastomers with Self-healing Capability. [J]. Acta Polymerica Sinica 50(3):271-280(2019) DOI： 10.11777/j.issn1000-3304.2019.18213.

摘要

通过硼酸(BA)交联羟基封端的聚二甲基硅氧烷(Hydroxyl-PDMS)得到聚硼硅氧烷(PBS)弹性体，并与单分散的SiO

纳米粒子(SiO

NPs)和炭黑纳米粒子(CB NPs)共组装，进而得到无角度依赖的光子晶体弹性体. 通过光纤光谱仪表征了不同结构色光子晶体弹性体的光学性质，利用光学显微镜和应力-应变测试分别对光子晶体弹性体表面划痕和裂痕的自愈合性能进行了系统表征. 结果表明，该光子晶体弹性体材料的结构色不随观测角度的改变而发生变化，即具有无角度依赖的结构色. 同时，该光子晶体弹性体在形变过程中可实现颜色改变；更为重要的是，光子晶体弹性体的链柔性及动态可逆键使其在室温条件下即可展现出自愈合性能

可实现表面划痕及裂痕的快速愈合. 此外，通过喷涂法可简单快速地制备具有明亮结构色的大面积光子晶体膜材料，拓展了该光子晶体材料在彩色涂层、显示板、印刷等领域的应用.

Abstract

Recently

photonic crystals with short-range ordered structures have aroused extensive interest in scientific research owing to their structural color independent of angle variation. This unique property sets mateirals free from the angle-dependent color variation and plays a critical role in the practical applications involving color observation. However

such fascinating applications may be undesirably compromised by the poor durability of photonic crystals due to their delicate structures. In this study

we developed a series of polyborosiloxane-based photonic elastomers that possessed angle-independent structural color and self-healing capability. Specifically

hydroxyl-terminated poly(dimethylsiloxane) (Hydroxyl-PDMS) was reacted with boric acid (BA) by forming reversible dynamic covalent bonds

dative bonds

and hydrogen bonds

and as-obtained polyborosiloxane (PBS) elastomers were further incorporated with isotropically arranged SiO

nanoparticles (NPs) and carbon black NPs. Optical properties of the photonic elastomers were characterized by reflection spectroscopy at varied detection angles

and angle independence was found for structural colors. Futhermore

the structural color of these elastomers could be tuned by simply adjusting the size or loading fraction of the SiO

NPs in elastomers. The mateirals obtained had a Young’s modulus up to ~200 kPa and also exhibited mechanochromic behavior thanks to the good flexibility of polymeric matrix. Moreover

the intriguing combination of flexibility with reversible bonding endowed the photonic elastomers with a rapid self-healing ability towards superficial scratches or cuts at room temperature

which in turn afforded the necessary durabilities both optically and mechanically. In addition

since photonic elastomer films with a large area could be readily fabricated through a simple spray-coating process

the materials developed have shown great prospects for applications in color-coating

displaying

sensing

and printing.

关键词

光子晶体无角度依赖结构色自愈合弹性体聚硼硅氧烷

Keywords

Photonic crystalAngle-independent structural colorSelf-healingElastomerPolyborosiloxane

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School of Polymer Science and Engineering, Qingdao University of Science and Technology

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