Shape Memory Polymers with Regionally Defined Glass Transition Temperature <italic style="font-style: italic">via</italic> Digital Photocuring

Guan-cong Chen; Zi-zheng Fang; Yu-kun Hou; Zhang-fa Tong; Qian Zhao

doi:10.11777/j.issn1000-3304.2019.18229

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Shape Memory Polymers with Regionally Defined Glass Transition Temperature via Digital Photocuring

Research Article | 更新时间：2021-01-26

- Shape Memory Polymers with Regionally Defined Glass Transition Temperature via Digital Photocuring
- Acta Polymerica Sinica Vol. 50, Issue 3, Pages: 311-318(2019)
- 作者机构：
  
  1.广西大学化学化工学院　南宁 530004
  2.浙江大学生物工程与化学工程学院化学工程国家重点实验室　杭州 310027
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.18229
  CLC：
- Published：2019-3，
  
  Published Online：27 December 2018，
  
  Received：2 November 2018，
  
  Revised：28 November 2018，
扫描看全文
Guan-cong Chen, Zi-zheng Fang, Yu-kun Hou, Zhang-fa Tong, Qian Zhao. Shape Memory Polymers with Regionally Defined Glass Transition Temperature via Digital Photocuring. [J]. Acta Polymerica Sinica 50(3):311-318(2019)
DOI：

Guan-cong Chen, Zi-zheng Fang, Yu-kun Hou, Zhang-fa Tong, Qian Zhao. Shape Memory Polymers with Regionally Defined Glass Transition Temperature via Digital Photocuring. [J]. Acta Polymerica Sinica 50(3):311-318(2019) DOI： 10.11777/j.issn1000-3304.2019.18229.

摘要

用热聚合合成了一种带有未反应不饱和双键的形状记忆环氧树脂. 通过第二步光固化过程，可以将未反应的双键聚合，形成第二重交联点以增加材料的交联密度，同时提高其玻璃化温度. 利用数字化光掩膜技术对热聚合后的材料进行区域化地曝光，并控制各局部区域的曝光时间，可引发网络中的双键进行第二步光固化，并使材料区域的玻璃化温度在40 ~ 70 °C区间内可调. 二次固化前后的材料均表现出良好的形状记忆性能，形状固定率与回复率均接近100%. 区域化玻璃化温度可控的材料可进行程序化的多形状记忆回复过程，并有望用做具有应变隔离功能的新型柔性电子基底材料.

Abstract

Thermal transition temperatures (

e.g.

glass transition temperatures) play an important role in various applications of shape memory polymers that can recover from temporary shapes to original (permanent) shapes upon heating. This study reports a shape memory epoxy with unsaturated double bonds

enabling a secondary photocuring process. Dual-functional epoxy monomer

E44

and monofunctional epoxy monomer

glycidyl methacrylate

are first thermally cured

via

a polyether amine crosslinker. Properties of the cured epoxy can be finely tuned by controlling the feed compositions. The increase of feed ratio of glycidyl methacrylate will lead to lower glass transition temperature and elastic modulus

whereas larger strain at break. In the secondary photocuring process

the unsaturated bonds provided by glycidyl methacrylate are polymerized after light exposure

forming additional crosslinking points. As a result

the glass transition temperature of the material increases. Herein

digital photo-masking technique is applied for the photocuring process

via

a commercial projector. The regional exposure time of the material can be conducted

and thus

the local glass transition temperature can be controlled in a range of approximately 40 − 70 °C. Storage modulus at the rubbery state of the material increases from approximately 0.5 MPa to 8 MPa after photo exposure for 240 s

implying that there is a remarkable increase of the crosslinking density

via

the secondary photocuring. Both the materials before and after the secondary photocuring provide ideal shape memory performance. The shape fixity ratios and shape recovery ratios retain nearly 100% during six shape memory cycles

indicating good thermo-mechanical stability of the material. The material with regional controllable glass transition temperature enables a programmable multi-shape recovery process. Complex original shapes can be fabricated if the secondary photocuring is conducted towards a thermally cured epoxy. In addition

the material can be potentially applied as a novel substrate for stretchable electronics due to its strain isolation functionality.

关键词

形状记忆聚合物玻璃化转变温度环氧树脂光固化

Keywords

Shape memory polymersGlass transition temperatureEpoxy resinPhotocuring

references

Zheng Ning (郑宁), Xie Tao(谢涛) . 高分子学报 , Acta Polymerica Sinica , 2017 . ( 11 ): 1715 - 1724.

Zhao Q, Qi H J, Xie T . Prog Polym Sci , 2015 . 49-50 79 - 120 . DOI:10.1016/j.progpolymsci.2015.04.001http://doi.org/10.1016/j.progpolymsci.2015.04.001 .

Lendlein A, Behl M, Hiebl B, Wischke C . Expert Rev Med Devices , 2010 . 7 357 - 79 . DOI:10.1586/erd.10.8http://doi.org/10.1586/erd.10.8 .

Chen H M, Wang L, Zhou S B . Chinese J Polym Sci , 2018 . 36 905 - 917 . DOI:10.1007/s10118-018-2118-7http://doi.org/10.1007/s10118-018-2118-7 .

Zhang Y Y, Gao H J, Wang H, Xu Z Y, Chen X W, Liu B, Shi Y, Lu Y, Wen L F, Li Y, Li Z S, Men Y F, Feng X Q, Liu W G . Adv Funct Mater , 2018 . 28 1705962 DOI:10.1002/adfm.v28.9http://doi.org/10.1002/adfm.v28.9 .

Liu Y J, Du H Y, Liu L W, Leng J S . Smart Mater Struct , 2014 . 23 023001 DOI:10.1088/0964-1726/23/2/023001http://doi.org/10.1088/0964-1726/23/2/023001 .

Zhang G G, Peng W J, Wu J J, Zhao Q, Xie T . Nat Commun , 2018 . 9 4002 DOI:10.1038/s41467-018-06420-whttp://doi.org/10.1038/s41467-018-06420-w .

Dong J T, Zou W K, Chen F, Zhao Q . Chinese J Polym Sci , 2018 . 36 953 - 959 . DOI:10.1007/s10118-018-2119-6http://doi.org/10.1007/s10118-018-2119-6 .

Zhang X Z, Zhou Q Q, Liu H R, Liu H W . Soft Matter , 2014 . 10 3748 - 3754 . DOI:10.1039/c4sm00218khttp://doi.org/10.1039/c4sm00218k .

Lendlein A, Jiang H Y, Junger O, Langer R . Nature , 2005 . 434 875 - 882.

Yang L, Wang Z H, Fei G X, Xia H S . Macromol Rapid Commun , 2017 . 38 1700421 DOI:10.1002/marc.v38.23http://doi.org/10.1002/marc.v38.23 .

Xie T . Rousseau I A. Polymer , 2009 . 50 1852 - 1856.

Zheng N, Fang G Q, Cao ZL, Zhao Q, Xie T . Polym Chem , 2015 . 6 3046 - 3053 . DOI:10.1039/C5PY00172Bhttp://doi.org/10.1039/C5PY00172B .

Huang Miaoming(黄淼铭), Dong Xia(董侠), Liu Weili(刘伟丽), Gao Xia(高峡), Wang Dujin(王笃金) . 高分子学报 , Acta Polymerica Sinica , 2017 . ( 4 ): 563 - 579.

Mohr R, Kratz K, Weigel T, Lucka-Gabor M, Moneke M, Lendlein A . P Natl Acad Sci USA , 2006 . 103 3540 - 3545 . DOI:10.1073/pnas.0600079103http://doi.org/10.1073/pnas.0600079103 .

Koerner H, Price G, Pearce NA, Alexander M, Vaia R A . Nat Mater , 2004 . 3 115 - 20 . DOI:10.1038/nmat1059http://doi.org/10.1038/nmat1059 .

Qi X, Yao X, Deng S, Zhou T, Fu Q . J Mater Chem A , 2014 . 2 2240 - 2249 . DOI:10.1039/C3TA14340Fhttp://doi.org/10.1039/C3TA14340F .

Liu Y, Zhang Q L, Feng J C . Polymer , 2018 . 146 267 - 274 . DOI:10.1016/j.polymer.2018.05.047http://doi.org/10.1016/j.polymer.2018.05.047 .

Lu W, Le X X, Zhang J W, Huang Y J, Chen T . Chem Soc Rev , 2017 . 46 1284 - 1294 . DOI:10.1039/C6CS00754Fhttp://doi.org/10.1039/C6CS00754F .

Dong Z Q, Cao Y, Yuan Q J, Wang Y F, Li J H, Li B J, Zhang S . Macromol Rapid Commun , 2013 . 34 867 - 872 . DOI:10.1002/marc.201300084http://doi.org/10.1002/marc.201300084 .

Zeng C, Seino H, Ren J, Yoshie N . ACS Appl Mater Interfaces , 2014 . 6 2753 - 2758 . DOI:10.1021/am405287phttp://doi.org/10.1021/am405287p .

Pei Z Q, Yang Y, Chen Q M, Wei Y, Ji Y . Adv Mater , 2016 . 28 156 - 160 . DOI:10.1002/adma.201503789http://doi.org/10.1002/adma.201503789 .

Mao Y Q, Yu K, Isakov M S, Wu J, Dunn M L, Qi H J . Sci Rep , 2015 . 5 13616 - 13628 . DOI:10.1038/srep13616http://doi.org/10.1038/srep13616 .

Cao Y, Zhang G G, Zhang Y C, Yue M K, Chen Y, Cai S S, Xie T, Feng X . Adv Funct Mater , 2018 . 28 1804604 .

Nair D P, Cramer N B, Gaipa J C, McBride M K, Matherly E M, McLeod R R, Shandas R, Bowman C N . Adv Funct Mater , 2012 . 53 2429 - 2438.

Huang L M, Jiang R Q, Wu J J, Song J Z, Bai H, Li B G, Zhao Q, Xie T . Adv Mater , 2017 . 29 1605390 DOI:10.1002/adma.201605390http://doi.org/10.1002/adma.201605390 .

Zhao Q, Zou W, Luo Y, Xie T . Sci Adv , 2016 . 2 e1501297 DOI:10.1126/sciadv.1501297http://doi.org/10.1126/sciadv.1501297 .

Zheng N, Fang Z Z, Zou W K, Zhao Q, Xie T . Angew Chem Int Ed , 2016 . 55 11421 - 11425 . DOI:10.1002/anie.201602847http://doi.org/10.1002/anie.201602847 .

Ware T, Simon D, Hearon K, Liu C, Shah S, Reeder J, Khodaparast N, Kilgard M P, Maitland D J, Rennaker R L, Voit W E . Macromol Mater Eng , 2012 . 297 1193 - 1202 . DOI:10.1002/mame.v297.12http://doi.org/10.1002/mame.v297.12 .

Wu J J, Huang L M, Zhao Q, Xie T . Chinese J Polym Sci , 2018 . 36 ( 5 ): 563 - 575 . DOI:10.1007/s10118-018-2089-8http://doi.org/10.1007/s10118-018-2089-8 .

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Related Institution

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences

School of Chemical Engineering and Technology, Sun Yat-sen University

State Key Laboratory of Supramolecular Molecular Structure and Materials, College of Chemistry, Jilin University

CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Polymer science and Engineering, University of Science and Technology of China

School of Mechatronic Engineering, Lanzhou Jiaotong University

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Shape Memory Polymers with Regionally Defined Glass Transition Temperature via Digital Photocuring

DOI：10.11777/j.issn1000-3304.2019.18229

摘要

Abstract

关键词

Keywords

references