Progress in Dynamic Covalent Polymers

Xing-xing Chen; Qian-yun Zhong; Shu-juan Wang; You-shen Wu; Ji-dong Tan; Heng-xin Lei; Shao-yong Huang; Yan-feng Zhang

doi:10.11777/j.issn1000-3304.2019.18277

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Progress in Dynamic Covalent Polymers

Reviews | 更新时间：2021-01-26

- Progress in Dynamic Covalent Polymers
- Acta Polymerica Sinica Vol. 50, Issue 5, Pages: 469-484(2019)
- 作者机构：
  
  1.西安交通大学理学院　西安 710049
  2.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室　长春 130022
  3.西安市可持续能源材料化学重点实验室　西安 710049
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.18277
  CLC：
- Published：2019-5，
  
  Published Online：3 April 2019，
  
  Received：28 December 2018，
  
  Revised：26 January 2019，
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Xing-xing Chen, Qian-yun Zhong, Shu-juan Wang, You-shen Wu, Ji-dong Tan, Heng-xin Lei, Shao-yong Huang, Yan-feng Zhang. Progress in Dynamic Covalent Polymers. [J]. Acta Polymerica Sinica 50(5):469-484(2019)
DOI：

Xing-xing Chen, Qian-yun Zhong, Shu-juan Wang, You-shen Wu, Ji-dong Tan, Heng-xin Lei, Shao-yong Huang, Yan-feng Zhang. Progress in Dynamic Covalent Polymers. [J]. Acta Polymerica Sinica 50(5):469-484(2019) DOI： 10.11777/j.issn1000-3304.2019.18277.

摘要

动态共价键在外界刺激(光、热、力、pH)作用下处于可逆的断裂和重新形成的平衡，与传统热固性树脂相比，动态共价键交联的高分子材料(Vitrimer或类玻璃高分子)的分子拓扑结构可动态调整，重排，且其结构构筑和性能研究对于高分子材料的加工成型、循环回收以及自愈合具有重要意义. 本文以可逆共价键反应为线索，整理分析了动态共价键的类型及其动态影响因素，对多种动态共价键在高分子材料设计和构建中的应用做出评述，并对动态共价键高分子材料的未来发展作了展望.

Abstract

New materials which have the potential to reversible topology rearrangement based on the dynamic covalent bonds are continually emerging. In the past decade

the research on dynamic covalent polymers has achieved notable progress in the preparation and proof-of-concept applications. Dynamic covalent polymer is a type of polymer material containing dynamic covalent bond in molecular chains. The bond energy of dynamic covalent bonds is lower than that of stable covalent bonds

but higher than that of non-covalent bonds

such as ionic bonds

coordination bonds

hydrogen bonds

or van der Waals forces. The reversible reaction can be triggered by external stimulus such as light

heat

force

and pH

while polymers with dynamic covalent bonds can maintain structural stability as the irreversible covalent polymers after removing the applied stimuli. Compared with the traditional thermosets with three-dimensional cross-linker networks

the dynamic reversible process endows the cross-linker polymer with certain degree of controllable degradation

recycling

self-healing

and other excellent properties

which is hard for conventional covalent polymers to achieve. Dynamic covalent polymers possess both the mechanical properties of traditional thermosets and the thermodynamic lability of supramolecular polymers. It has shown great potential in the application of intelligent devices such as flexible electronic skin

shape memory

3D and 4D printing

intelligent sensors

etc.

and presented great potential in industrial scale. In this review

various types of dynamic covalent bonds and their reactions are introduced

including carbon radical exchange

olefin metathesis

DA reaction

disulfide bond exchange

disulfide-thiol exchange

etc

. Then the structural design

properties

and applications of polymer materials containing different types of dynamic covalent bonds are briefly summarized. This provides a certain theoretical guidance for the study of reversible polymers. Finally

the future development and scientific challenge of dynamic covalent polymers are prospected and discussed

which involved in three aspects: (a) preparation of high performance structural materials based on dynamic covalent bonds

(b) the relationship between dynamic covalent bonds and rheology behavior of materials

and (c) the combination of various dynamic bonds to prepare functional materials.

关键词

动态共价键可逆反应类玻璃高分子自愈合热固性树脂

Keywords

Dynamic covalent bondReversible reactionsGlass-like polymersSelf-healingSmart materials

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