A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents

Zhi-yao Liu; Zheng Wang; Yu-hua Yin; Run Jiang; Bao-hui Li

doi:10.11777/j.issn1000-3304.2019.19072

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A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents

Research Article | 更新时间：2021-01-26

- A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents
  增强出版
- Acta Polymerica Sinica Vol. 50, Issue 11, Pages: 1220-1228(2019)
- 作者机构：
  
  南开大学物理科学学院教育部功能高分子材料重点实验室　天津 300071
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.19072
  CLC：
- Published：2019-11，
  
  Published Online：11 June 2019，
  
  Received：12 April 2019，
  
  Revised：11 May 2019，
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Zhi-yao Liu, Zheng Wang, Yu-hua Yin, Run Jiang, Bao-hui Li. A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents. [J]. Acta Polymerica Sinica 50(11):1220-1228(2019)
DOI：

Zhi-yao Liu, Zheng Wang, Yu-hua Yin, Run Jiang, Bao-hui Li. A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents. [J]. Acta Polymerica Sinica 50(11):1220-1228(2019) DOI： 10.11777/j.issn1000-3304.2019.19072.

摘要

采用模拟退火方法研究了两嵌段共聚物AB/均聚物C共混体系在溶液中的相行为. 关注于C与A/B为排斥作用时溶剂对它们的增容作用. 考察了溶剂的加入量(以聚合物链节的浓度

表征)、加入C的体积分数

、C与AB的链长比

、C与AB排斥作用、溶剂S与C吸引作用强度等对体系相容性及组装行为的影响. 构建了作为

和

的函数的形态相图. 研究表明，当

小于0.5，且C与A/B间的排斥作用不是很强时，加入强亲A/C的溶剂能够提高体系的相容性. 并获得了层状相、连通相、层中柱状相、核壳柱状相等相结构，其中层中柱状相是纯两嵌段共聚物体系中没有的结构. 在高

值的体系中，C分布在A/B的界面上；在低

值的体系中，C分布在A相区中. 研究表明，

越小，C与A、B嵌段的接触数越大，均聚物越容易与两嵌段共聚物相容；

越大，加入少量的均聚物体系就发生宏观相分离，且增加B/C间的排斥作用会降低体系的相容性. 体系形态结构的转变以及微相分离到宏观相分离的转变都是体系的能量与熵之间竞争的结果. 溶液体系中宏观相分离与熔体时的不同，溶液中部分C链节在AB的界面上以减小AB的接触，而熔体时全部的C链节均与AB宏观相分离.

Abstract

The phase behavior of diblock copolymer AB/homopolymer C blends in solution was studied by simulated annealing method. The study was focused on the compatibilization between the homopolymer and the copolymer with repulsive interactions due to the addition of solvent. We investigated the amount of solvent (characterized by the concentration of the polymer segments

)

the volume fraction

of the homopolymer C

the ratio of homopolymer chain length to the copolymer chain length

the repulsion between C and A or B segments

and

and the attraction between solvent and C on the phase behavior of the blending system. We built phase diagrams in the space of

and

at different

. Studies have shown that when

is less than 0.5

and the values of

and

are not very large

the addition of solvent strongly selective to A and C segments can improve the compatibility of the system. In solution

lamellae

gyroids

cylinders in layers

core-shell cylinders and cylindrical structures are formed. Moreover

the structure of cylinders in layers has not been observed in the neat diblock copolymer system. C-segments are distributed at the interfaces between A/B domains at high

region

while they are inside the A domain at low

region. Short homopolymer chains are easily compatible with diblock copolymers. Macroscopic phase separation has taken place in long homopolymer chains even with a small amount of homopolymer added. Moreover

increasing the values of

and

will reduce the compatibility of the system. The transformation between different phases and that from microphase separation to macrophase separation are the results of the competition between the energy and entropy of the system. The macrophase separation in the solution system is different from that in the melt system. Some C-segments are at the interface of AB domains to reduce the contact between A and B segments in the solution system

while all C-segments are separated from the AB domains in the melts.

关键词

嵌段共聚物均聚物共混溶剂增容

Keywords

Block copolymerHomopolymerBlendSolventCompatibilization

references

Wang Jian(王健), Lu Yuyuan(卢宇源), Xu Yuci(徐玉赐), Ruan Yongjin(阮永金), Li Liangyi(李良一), An Lijia(安立佳). Acta Polymerica Sinica(高分子学报) , 2016 . ( 3 ): 271 - 287 . DOI:10.11777/j.issn1000-3304.2016.15340http://doi.org/10.11777/j.issn1000-3304.2016.15340 .

Semenov A N. Macromolecules , 1993 . 26 2273 - 2281 . DOI:10.1021/ma00061a021http://doi.org/10.1021/ma00061a021 .

Matsen M W. Macromolecules , 1995 . 28 5765 - 5773 . DOI:10.1021/ma00121a011http://doi.org/10.1021/ma00121a011 .

Likhtman A E, Semenov A N. Macromolecules , 1997 . 30 7273 - 7278 . DOI:10.1021/ma9702713http://doi.org/10.1021/ma9702713 .

Shull K R, Winey K I. Macromolecules , 1992 . 25 2637 - 2644 . DOI:10.1021/ma00036a013http://doi.org/10.1021/ma00036a013 .

Matsen M W. Macromolecules , 2003 . 36 9647 - 9657 . DOI:10.1021/ma0349377http://doi.org/10.1021/ma0349377 .

Duranty E R, Baschnagel J, Dadmun M J. Chem Phys , 2017 . 146 054905 DOI:10.1063/1.4975022http://doi.org/10.1063/1.4975022 .

Uneyama T, Doi M. Macromolecules , 2005 . 38 196 - 205 . DOI:10.1021/ma049385mhttp://doi.org/10.1021/ma049385m .

Lo C T, Li M H, Lin W T. J. Chem Phys , 2015 . 142 ( 18 ): 184903 .

Tanakat T, Hashimoto T. Macromolecules , 1991 . 24 5713 - 5720 . DOI:10.1021/ma00020a035http://doi.org/10.1021/ma00020a035 .

Inoue T, Soen T, Hashimoto T, Kawai H. Macromolecules , 1970 . 3 87 - 92 . DOI:10.1021/ma60013a018http://doi.org/10.1021/ma60013a018 .

Torikai N, Takabayashi N, Noda I, Koizumi S. Morii Y, Matsushita Y. Macromolecules , 1997 . 30 5698 - 5703 . DOI:10.1021/ma961936ohttp://doi.org/10.1021/ma961936o .

Wei M J, Sun W, Shi X S, Wang Z G, Wang Y. Macromolecules , 2016 . 49 215 - 223 . DOI:10.1021/acs.macromol.5b02133http://doi.org/10.1021/acs.macromol.5b02133 .

Wang Y C, Kim M I, Akasaka S, Saijo K, Hasegawa H, Hikima T, Takenaka M. Macromolecules , 2016 . 49 2257 - 2261 . DOI:10.1021/acs.macromol.6b00007http://doi.org/10.1021/acs.macromol.6b00007 .

Li Y F, Pearce E, Lyons J W, Murray D, Chatterjee T, Meunier D M. J Chromatogr A , 2016 . 1475 41 - 54 . DOI:10.1016/j.chroma.2016.10.070http://doi.org/10.1016/j.chroma.2016.10.070 .

Floudas G, Meramveliotaki K. Macromolecules , 1999 . 32 7496 - 7503 . DOI:10.1021/ma990524nhttp://doi.org/10.1021/ma990524n .

Dobrosielska K, Wakao S, Suzuki J, Noda K, Takano A, Matsushita Y. Macromolecules , 2009 . 42 7098 - 7102 . DOI:10.1021/ma901212phttp://doi.org/10.1021/ma901212p .

Matsushita Y. Macromolecules , 2007 . 40 771 - 776 . DOI:10.1021/ma062266hhttp://doi.org/10.1021/ma062266h .

Dobrosielska K, Wakao S, Takano A, Matsushita Y. Macromolecules , 2008 . 41 7695 - 7698 . DOI:10.1021/ma801330phttp://doi.org/10.1021/ma801330p .

Dehghan A, Shi A C. Macromolecules , 2013 . 46 ( 14 ): 5796 - 5805 . DOI:10.1021/ma4008576http://doi.org/10.1021/ma4008576 .

Hameed N, Guo Q. Polymer , 2008 . 49 5268 - 5275 . DOI:10.1016/j.polymer.2008.09.032http://doi.org/10.1016/j.polymer.2008.09.032 .

Hameed N, Liu J, Guo Q. Macromolecules , 2008 . 41 7596 - 7605 . DOI:10.1021/ma800703bhttp://doi.org/10.1021/ma800703b .

Hameed N, Guo Q. Polymer , 2008 . 49 922 - 933 . DOI:10.1016/j.polymer.2007.12.040http://doi.org/10.1016/j.polymer.2007.12.040 .

Salim N V, Hanley T, Guo Q. Macromolecules , 2010 . 43 7695 - 7704 . DOI:10.1021/ma101199whttp://doi.org/10.1021/ma101199w .

Li J G, Lin Y D, Kuo S W. Macromolecules , 2011 . 44 9295 - 9309 . DOI:10.1021/ma2010734http://doi.org/10.1021/ma2010734 .

Salim N V, Hameed N, Guo Q. J Polym Sci, Part B: Polym Phys , 2009 . 47 1894 - 1905 . DOI:10.1002/polb.v47:19http://doi.org/10.1002/polb.v47:19 .

Hameed N, Salim N V, Guo Q. J Chem Phys , 2009 . 131 214905 DOI:10.1063/1.3268779http://doi.org/10.1063/1.3268779 .

Lin Ruichong(林瑞崇), Guo Shaowei(郭绍伟). Acta Polymerica Sinica(高分子学报) , 2018 . ( 8 ): 1016 - 1032 . DOI:10.11777/j.issn1000-3304.2018.18020http://doi.org/10.11777/j.issn1000-3304.2018.18020 .

Park H, Kim J U, Park S. Nanoscale , 2012 . 4 1362 - 1367 . DOI:10.1039/c2nr11792dhttp://doi.org/10.1039/c2nr11792d .

Tsai S C, Lin Y C, Lin E L, Chiang Y W, Kuo S W. Polym Chem , 2016 . 7 2395 - 2409 . DOI:10.1039/C6PY00195Ehttp://doi.org/10.1039/C6PY00195E .

Chen S C, Kuo S W, Jeng U S, Su C J, Chang F C. Macromolecules , 2010 . 43 1083 - 1092 . DOI:10.1021/ma901729thttp://doi.org/10.1021/ma901729t .

Zhou Jiajia. Phase behavior of diblock copolymer/homopilymer blends. Doctoral Dissertation of Mc University, 2010

Zhang J, Kong W X, Duan H. Langmuir , 2017 . 33 ( 12 ): 3123 - 3133 . DOI:10.1021/acs.langmuir.7b00181http://doi.org/10.1021/acs.langmuir.7b00181 .

Yang R Q, Li B H. Langmuir , 2012 . 28 1569 - 1578 . DOI:10.1021/la204449xhttp://doi.org/10.1021/la204449x .

Cui Baobao(崔宝宝), Pan Junxing(潘俊星), Zhang Jinjun(张进军), Sun Minna(孙敏娜), Guo Yuqi(郭宇琦), Cen Jianyong(岑建勇), Wu Haishun (武海顺). Acta Polymerica Sinica(高分子学报) , 2017 . ( 6 ): 959 - 966 . DOI:10.11777/j.issn1000-3304.2017.16285http://doi.org/10.11777/j.issn1000-3304.2017.16285 .

Xia Shankai(夏杉凯), Li Weihua (李卫华), Qiu Feng(邱枫). Acta Chimica Sinica(化学学报) , 2014 . 72 30 - 34 . DOI:10.7503/cjcu20130854http://doi.org/10.7503/cjcu20130854 .

Qiu H B, Qliver A M, Gwyther J, Cai J D, Harniman R L, Hayward D W, Manners L. Macromolecules , 2019 . 52 ( 1 ): 113 - 120 . DOI:10.1021/acs.macromol.8b02227http://doi.org/10.1021/acs.macromol.8b02227 .

Shi T F, Wen G Y, Jiang W, An L J, Li B Y. Eur Polym J , 2003 . 39 551 - 560 . DOI:10.1016/S0014-3057(02)00237-9http://doi.org/10.1016/S0014-3057(02)00237-9 .

Kirkpatrick S, Gelatt C D, Vecchi M P. Science , 1983 . 220 671 - 680 . DOI:10.1126/science.220.4598.671http://doi.org/10.1126/science.220.4598.671 .

Carmesin I, Kremer K. Macromolecules , 1988 . 21 2819 - 2823 . DOI:10.1021/ma00187a030http://doi.org/10.1021/ma00187a030 .

Larson R G. J Chem Phys , 1989 . 84 2479 - 2488.

Larson R G. J Chem Phys , 1992 . 96 7904 - 7918.

Wu J P, Wang Z, Yin Y H, Jiang R, Li B H, Shi A C. Macromolecules , 2015 . 48 8897 - 8906 . DOI:10.1021/acs.macromol.5b01993http://doi.org/10.1021/acs.macromol.5b01993 .

Sun P C, Yin Y H, Li B H, Chen T H, Jin Q H, Ding D T, Shi A C. J Chem Phys , 2005 . 12 204905 .

Kong W X, Li B H, Jin Q H, Ding D T, Shi A C. J Am Chem Soc , 2009 . 131 8503 - 8512 . DOI:10.1021/ja900405rhttp://doi.org/10.1021/ja900405r .

W Kong, Jiang W, Zhu Y T, Li B H. Langmuir , 2012 . 28 11714 - 11724 . DOI:10.1021/la3014943http://doi.org/10.1021/la3014943 .

Xu Jihua(徐纪华), Jiang Ru(蒋润), Yin Yuhua(尹玉华), Wang Zheng(王铮), Li Baohui(李宝会). Acta Polymerica Sinica(高分子学报) , 2013 . ( 10 ): 1227 - 1284.

Li Qingxiao(李青霄), Wang Zheng(王铮), Yin Yuha(尹玉华), Jiang Run(蒋润), Li Baohui(李宝会). Acta Polymerica Sinica(高分子学报) , 2018 . ( 10 ): 1351 - 1358 . DOI:10.11777/j.issn1000-3304.2018.18072http://doi.org/10.11777/j.issn1000-3304.2018.18072 .

Hao Jinlong(郝金龙), Wang Zhan(汪湛), Wang Zheng(王铮), Yin Yuhua(尹玉华), Jiang Run(蒋润), Li Baohui(李宝会). Acta Polymerica Sinica(高分子学报) , 2017 . ( 11 ): 1841 - 1850 . DOI:10.11777/j.issn1000-3304.2017.17031http://doi.org/10.11777/j.issn1000-3304.2017.17031 .

Yu B, Li B H, Jin Q H, Ding D T, Shi A C. Macromolecules , 2007 . 40 9133 - 9142 . DOI:10.1021/ma071624thttp://doi.org/10.1021/ma071624t .

Yang Rongqiao(杨荣巧), Ding Datong(丁大同), Li Baohui(李宝会). Acta Polymerica Sinica(高分子学报) , 2011 . ( 11 ): 1335 - 1360.

Zimm B H, Stockmayer W H. J Chem Phys , 1949 . 17 1301 - 1314 . DOI:10.1063/1.1747157http://doi.org/10.1063/1.1747157 .

Matsen M W. Phys Rev Lett , 1995 . 74 4225 - 4228 . DOI:10.1103/PhysRevLett.74.4225http://doi.org/10.1103/PhysRevLett.74.4225 .

Jeon S, Yi G, Koo M, Yang S. Macromolecules , 2007 . 40 8430 - 8439 . DOI:10.1021/ma0712302http://doi.org/10.1021/ma0712302 .

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