Photo-thermal Storage and Release of an Azobenzene-grafted Polynorbornene Film

Lin-xia Fu; Yi-yu Feng; Wei Feng

doi:10.11777/j.issn1000-3304.2019.19092

您当前的位置：

首页 >

文章列表页 >

Photo-thermal Storage and Release of an Azobenzene-grafted Polynorbornene Film

Research Article | 更新时间：2021-01-26

- Photo-thermal Storage and Release of an Azobenzene-grafted Polynorbornene Film
- Acta Polymerica Sinica Vol. 50, Issue 12, Pages: 1272-1279(2019)
- 作者机构：
  
  天津大学材料科学与工程学院　天津 300072
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.19092
  CLC：
- Published：2019-12，
  
  Published Online：18 June 2019，
  
  Received：5 May 2019，
  
  Revised：10 May 2019，
扫描看全文
Lin-xia Fu, Yi-yu Feng, Wei Feng. Photo-thermal Storage and Release of an Azobenzene-grafted Polynorbornene Film. [J]. Acta Polymerica Sinica 50(12):1272-1279(2019)
DOI：

Lin-xia Fu, Yi-yu Feng, Wei Feng. Photo-thermal Storage and Release of an Azobenzene-grafted Polynorbornene Film. [J]. Acta Polymerica Sinica 50(12):1272-1279(2019) DOI： 10.11777/j.issn1000-3304.2019.19092.

摘要

将甲氧基和羧基取代偶氮苯共价接枝到开环易位聚合方法制备的聚降冰片烯侧链上，制备了具有光热存储与释放功能的偶氮基聚降冰片烯(PNB-Azo). 结果表明，当偶氮苯在聚合物上的接枝密度为31%(偶氮苯与聚合物结构单元摩尔比)时，可获得具有良好柔韧性和自支撑性的光热膜，拉伸强度和最大应变分别可达21.5 MPa和120%. 通过在波长365 nm的紫外充热后，PNB-Azo膜光热存储的能量密度可达34 Wh/kg. 该薄膜在波长为550 nm的绿光照射和50 °C条件下，能实现存储热量的可控释放，与未充热的膜相比，温差可达1.25 °C. 该结果为制备具有光热循环利用功能的柔性光热膜提供了材料基础.

Abstract

The poor film-formation ability of azobenzene carbon thermal storage materials with graphene as templates limits their practical application due to the rigid structure of graphene sp2 hybridization. In this study

we addressed this issue by employing polynorbornene as the templelate given that polymers much outperform graphene in terms of film formation

flexibility

and self-supporting property. Herein

azobenzene attached with two methoxy and two carboxyl groups was firstly synthesized to regulate the photoisomerization and energy density. Next

polynorbornene (PNB) templates with various molecular weights were prepared by ring-opening metathesis polymerization (ROMP) with different molar ratios between monomer and catalyst. Azobenzene was then grafted onto the side chain of PNB through amidation reaction to afford azobenzene-grafted polynorbornenes with diverse grafting densities. Experimental results showed that with the increasing molecular weight of PNB template

the graft density of azobenzene rose first but subsequently fell. As for the film formation ability

PNB-Azo-500 with the highest graft density (36%) could hardly form an intact film

while PNB-Azo-900 exhibited the best film formation ability despite a slightly lower graft density (31%). Therefore

PNB-Azo-900 was involved in the following measurements. Tensile testing indicated that the PNB-Azo-900 film possessed good flexibility and self-supporting behavior by achieving a strain of 120% and a tensile strength of 21.5 MPa. Photoisomerization and energy density was characterized by UV-absorption spectroscopy and differential scanning calorimetry

respectively

which suggested that the film effectuated energy storage under 365 nm UV-light irradiation and the energy density reached 34 Wh/kg. The stored energy could be released as heat when the film was expoed to 550 nm green light or heat source stimulation

during which the highest temperature was 1.25 °C. Such excellent energy storage and light responsiveness endowed this PBN film with potential applications in the field of space thermal management.

关键词

开环易位聚合聚合物模板柔性薄膜偶氮苯热释放

Keywords

Ring-opening metathesis polymerizationPolymer templateFlexible filmAzobenzeneThermal release

references

Perez M, Perez R. IEA-SHCP-Newsletter , 2015 . 62 ( 11 ): 4 - 6.

Kucharski T J, Tian Y, Akbulatov S, Boulatov R. Energy Environ Sci , 2011 . 4 ( 11 ): 4449 - 4472 . DOI:10.1039/c1ee01861bhttp://doi.org/10.1039/c1ee01861b .

Davis S J, Caldeira K, Matthews H D. Science , 2010 . 329 ( 5997 ): 1330 - 1333 . DOI:10.1126/science.1188566http://doi.org/10.1126/science.1188566 .

Cook T R, Dogutan D K, Reece S Y, Surendranath Y, Teets T S, Nocera D G. Chem Rev , 2010 . 110 ( 11 ): 6474 - 6502 . DOI:10.1021/cr100246chttp://doi.org/10.1021/cr100246c .

Wang Z, Tong Z, Ye Q, Hu H, Nie X, Yan C, Shang W, Song C, Wu J, Wang J, Bao H, Tao P, Deng T. Nat Commun , 2017 . 8 ( 1 ): 1478 - 1486 . DOI:10.1038/s41467-017-01618-whttp://doi.org/10.1038/s41467-017-01618-w .

Zhang Z, Liao M, Lou H, Hu Y, Sun X, Peng H. Adv Mater , 2018 . 30 ( 13 ): 1704261 - 1704279 . DOI:10.1002/adma.v30.13http://doi.org/10.1002/adma.v30.13 .

Zhitomirsky D, Cho E, Grossman J C. Adv Energy Mater , 2016 . 6 ( 6 ): 1501999 - 1502006.

Dreos A, Wang Z, Udmark J. Adv Energy Mater , 2018 . 8 ( 18 ): 1703401 - 1703409 . DOI:10.1002/aenm.v8.18http://doi.org/10.1002/aenm.v8.18 .

Kolpak A M, Grossman J C. Nano Lett , 2011 . 11 ( 8 ): 3156 - 3162 . DOI:10.1021/nl201357nhttp://doi.org/10.1021/nl201357n .

Zhao X, Feng Y, Qin C, Yang W, Si Q, Feng W. ChemSusChem , 2017 . 10 ( 7 ): 1395 - 1404 . DOI:10.1002/cssc.v10.7http://doi.org/10.1002/cssc.v10.7 .

Qing Xin(卿鑫), Lu Jiuan(吕久安), Yu Yanlei(俞燕蕾) . 2017 . ( 11 ): 1679 - 1705.

Jonesii G, Reinhardt T E, Bergmark W R. Sol Energy , 1978 . 20 ( 3 ): 241 - 248 . DOI:10.1016/0038-092X(78)90103-2http://doi.org/10.1016/0038-092X(78)90103-2 .

Olmsted J, Lawrence J, Yee G G. Sol Energy , 1983 . 30 ( 3 ): 271 - 274 . DOI:10.1016/0038-092X(83)90156-1http://doi.org/10.1016/0038-092X(83)90156-1 .

Anders L, Anna R, Kasper M P. Tetrahedron Lett , 2015 . 56 ( 12 ): 1457 - 1465 . DOI:10.1016/j.tetlet.2015.01.187http://doi.org/10.1016/j.tetlet.2015.01.187 .

Kucharski T J, Ferralis N, Kolpak A M, Zheng J O, Nocera D G, Grossman J C. Nat Chem , 2014 . 6 ( 5 ): 441 - 447 . DOI:10.1038/nchem.1918http://doi.org/10.1038/nchem.1918 .

Feng Y, Liu H, Luo W, Liu E, Zhao N, Yoshino K, Feng W. Sci Rep , 2013 . 3 3260 - 3267 . DOI:10.1038/srep03260http://doi.org/10.1038/srep03260 .

Cho E N, Zhitomirsky D, Han G D, Liu Y, Grossman J C. ACS Appl Mater Interfaces , 2017 . 9 ( 10 ): 8679 - 8687 . DOI:10.1021/acsami.6b15018http://doi.org/10.1021/acsami.6b15018 .

Yang W, Feng Y, Si Q, Yan Q, Long P, Dong L, Feng W. J Mater Chem A , 2019 . 7 ( 1 ): 97 - 106 . DOI:10.1039/C8TA05333Bhttp://doi.org/10.1039/C8TA05333B .

Saydjari A K, Weis P, Wu S. Adv Energy Mater , 2017 . 7 ( 3 ): 1601619 - 1601622.

Han G D, Park S S, Liu Y, Zhitomirsky D, Cho E, Dincă M, Grossman J C. J Mater Chem A , 2016 . 4 ( 41 ): 16157 - 16165 . DOI:10.1039/C6TA07086Hhttp://doi.org/10.1039/C6TA07086H .

Zhitomirsky D, Grossman J C. ACS Appl Mater Interfaces , 2016 . 8 ( 39 ): 26319 - 26325 . DOI:10.1021/acsami.6b08034http://doi.org/10.1021/acsami.6b08034 .

Merino E. Chem Soc Rev , 2011 . 40 ( 7 ): 3835 - 3853 . DOI:10.1039/c0cs00183jhttp://doi.org/10.1039/c0cs00183j .

Zhang K, Zha Y, Peng B, Chen Y, Tew G N. J Am Chem Soc , 2013 . 135 ( 43 ): 15994 - 15997 . DOI:10.1021/ja407381fhttp://doi.org/10.1021/ja407381f .

Nguyen S B T, Johnson L K, Grubbs R H. J Am Chem Soc , 1992 . 114 ( 10 ): 3974 - 3975 . DOI:10.1021/ja00036a053http://doi.org/10.1021/ja00036a053 .

Zhang Zhitao(张智涛), Zhang Ye(张晔), Li Yiming(李一明), Peng Huisheng(彭慧胜) . 2016 . ( 10 ): 1284 - 1299 . DOI:10.11777/j.issn1000-3304.2016.16185http://doi.org/10.11777/j.issn1000-3304.2016.16185 .

Zhang Shuo(张朔), Cai Cunhua(蔡春华), Huang Qijing(黄琦婧), Lin Jiaping(林嘉平), Xu Zhanwen(许占文) . 2018 . ( 1 ): 109 - 118 . DOI:10.11777/j.issn1000-3304.2018.17223http://doi.org/10.11777/j.issn1000-3304.2018.17223 .

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis and Self-assembly of Asymmetric Molecular Brushes with Azobenzene-containing Side Chains

Design, Preparation and Visual Detection of Fluorophenyl Polynorbornene Anion Exchange Membrane with Single Quaternary Ammonium Salt

Synthesis and Investigation on Molecular Conformation of Amphiphilic Dendronized Brush Block Copolymer

Self-healing Solid-state Polymer Electrolyte Based on Zwitterions

Related Author

No data

Related Institution

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology

College of Chemistry and Materials Science, Sichuan Normal University

Department of Chemistry, Tsinghua University

School of Materials Science and Engineering, University of Science and Technology Beijing

Institute of Chemistry, Chinese Academy of Sciences

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰