Research Progress in Eco-polymers

Xue-si Chen; Guo-qiang Chen; You-hua Tao; Yu-zhong Wang; Xiao-bing Lv; Li-qun Zhang; Jin Zhu; Jun Zhang; Xian-hong Wang

doi:10.11777/j.issn1000-3304.2019.19124

您当前的位置：

首页 >

文章列表页 >

Research Progress in Eco-polymers

Reviews | 更新时间：2021-01-26

- Research Progress in Eco-polymers
- Acta Polymerica Sinica Vol. 50, Issue 10, Pages: 1068-1082(2019)
- 作者机构：
  
  1.中国科学院长春应用化学研究所生态环境高分子材料实验室　长春 130022
  2.清华大学生命学院　北京 100084
  3.四川大学化学学院高分子材料工程国家重点实验室环保型高分子材料国家地方联合工程实验室　成都 610064
  4.大连理工大学精细化工国家重点实验室　大连 116024
  5.北京化工大学有机无机复合材料国家重点实验室碳纤维及功能高分子教育部重点实验室　北京 100029
  6.中国科学院宁波材料技术与工程研究所　宁波 315201
  7.中国科学院化学研究所　北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.19124
  CLC：
- Published：2019-10，
  
  Published Online：4 September 2019，
  
  Received：31 May 2019，
  
  Revised：24 June 2019，
扫描看全文
Xue-si Chen, Guo-qiang Chen, You-hua Tao, Yu-zhong Wang, Xiao-bing Lv, Li-qun Zhang, Jin Zhu, Jun Zhang, Xian-hong Wang. Research Progress in Eco-polymers. [J]. Acta Polymerica Sinica 50(10):1068-1082(2019)
DOI：

Xue-si Chen, Guo-qiang Chen, You-hua Tao, Yu-zhong Wang, Xiao-bing Lv, Li-qun Zhang, Jin Zhu, Jun Zhang, Xian-hong Wang. Research Progress in Eco-polymers. [J]. Acta Polymerica Sinica 50(10):1068-1082(2019) DOI： 10.11777/j.issn1000-3304.2019.19124.

摘要

生态环境高分子是指全生命周期内低环境负荷甚至没有环境负荷的一类环保高分子. 作为响应自然呼唤的高分子，生态环境高分子诞生于20世纪90年代高分子工业飞速发展的年代，目前已经成为高分子科学的前沿研究方向. 我国学者以可再生资源的单体为核心(但不限于该类单体)，从催化剂设计、可控聚合方法、聚合物性能调控、聚合物功能化、物理表征和加工方法等方面取得了一系列重要的创新成果，有力推动了世界范围内该研究领域的发展. 本综述以聚乳酸等8类典型生态环境高分子为例，总结和评述了最近30年我国学者在生态环境高分子领域的基础研究进展，并对其未来发展趋势进行了展望.

Abstract

Eco-polymers are a kind of sustainable polymers with low environmental loads through their whole life cycles. As polymers respording to the call of environment

eco-polymers were born in the 1990s while the polymer industry in the world developed very fast. Now

such research grows into a hot point in polymer science. Employing monomers from renewable resources (not limited to renewable resources)

much great progress has been made in the past three decades in China

most of which started from highly active and selective catalyst design to controllable polymerization method

till performance adjustment and functionalization

constituting a major force to drive the fast development of eco-polymers in the world. In this review

we try to summarized the fundamental contributions from Chinese scientists in eco-polymers

such as poly(lactic acid)s

polyhydroxyalkanoates

amino acid based polymers

poly(1

4-dioxan-2-one)

copolymers

bio-based elastomers

5-furandicarboxylic acid based polyesters

and cellulose derivatives

and provide a perspective on the future of these polymers.

关键词

生态环境高分子聚乳酸聚羟基脂肪酸酯氨基酸基高分子聚对二氧环己酮二氧化碳共聚物生物基弹性体呋喃二甲酸基聚酯纤维素基高分子

Keywords

Eco-polymersPoly(lactic acid)sPolyhydroxyalkanoatesAmino acid based polymersPoly(14-dioxan-2-one)CO2 copolymersBio-based elastomers25-Furandicarboxylic acid based polyestersCellulose derivatives

references

Schneiderman D K, Hillmyer M A. Macromolecules , 2017 . 50 3733 - 3749.

Pang X, Zhuang X L, Tang Z H, Chen X S. Biotechnol J , 2010 . 5 1125 - 1136 . DOI:10.1002/biot.v5.11http://doi.org/10.1002/biot.v5.11 .

Thomas C M. Chem Soc Rev , 2010 . 39 165 - 173 . DOI:10.1039/B810065Ahttp://doi.org/10.1039/B810065A .

Du H Z, Pang X, Yu H Y, Zhuang X L, Chen X S, Cui D M, Wang X H, Jing X B. Macromolecules , 2007 . 40 1904 - 1913 . DOI:10.1021/ma062194uhttp://doi.org/10.1021/ma062194u .

Duan R L, Hu C Y, Li X, Pang X, Sun Z Q, Chen X S, Wang X H. Macromolecules , 2017 . 50 9188 - 9195 . DOI:10.1021/acs.macromol.7b01766http://doi.org/10.1021/acs.macromol.7b01766 .

Hu C Y, Duan R L, Yang S C, Pang X, Chen X S. Macromolecules , 2018 . 51 4699 - 4704 . DOI:10.1021/acs.macromol.8b00696http://doi.org/10.1021/acs.macromol.8b00696 .

Zhou Y C, Hu C Y, Zhang T H, Xu X W, Duan R L, Luo Y, Sun Z Q, Pang X, Chen X S. Macromolecules , 2019 . 52 3462 - 3470 . DOI:10.1021/acs.macromol.9b00001http://doi.org/10.1021/acs.macromol.9b00001 .

Pang X, Duan R L, Li X, Hu C Y, Wang X H, Chen X S. Macromolecules , 2018 . 51 906 - 913 . DOI:10.1021/acs.macromol.7b02662http://doi.org/10.1021/acs.macromol.7b02662 .

Shao J, Sun J R, Bian X C, Cui Y, Zhou Y C, Li G, Chen X S. Macromolecules , 2013 . 46 6963 - 6971 . DOI:10.1021/ma400938vhttp://doi.org/10.1021/ma400938v .

Gadgil B S T, Killi N, Rathna G V. Med Chem Comm , 2017 . 8 ( 9 ): 1774 - 1787 . DOI:10.1039/C7MD00252Ahttp://doi.org/10.1039/C7MD00252A .

Chen G Q, Jiang X R. Curr Opin Biotechnol , 2018 . 50 94 - 100.

Tan D, Wu Q, Chen J C, Chen G Q. Metab Eng , 2014 . 26 34 - 47 . DOI:10.1016/j.ymben.2014.09.001http://doi.org/10.1016/j.ymben.2014.09.001 .

Zhao H, Zhang H M, Chen X, Li T, Wu Q, Ouyang Q, Chen G Q. Metab Eng , 2017 . 39 128 - 140 . DOI:10.1016/j.ymben.2016.11.007http://doi.org/10.1016/j.ymben.2016.11.007 .

Chen G Q, Wang Y. Chinese J Polym Sci , 2013 . 31 ( 5 ): 719 - 736 . DOI:10.1007/s10118-013-1280-1http://doi.org/10.1007/s10118-013-1280-1 .

Leuchs H. Chem Ber , 1906 . 41 1721 - 1726.

Curtius T, Sieber W. Ber Dtsch Chem Ges B , 1921 . 54 1430 - 1437 . DOI:10.1002/cber.19210540707http://doi.org/10.1002/cber.19210540707 .

Li Guangxian(李光宪), Yang Xidong(杨曦东), Yu Tongyin(于同隐). Journal of Functional Polymers(功能高分子学报) , 1989 . ( 2 ): 53 - 58.

Tao Youhua(陶友华). Acta Polymerica Sinica(高分子学报) , 2016 . ( 9 ): 1151 - 1159.

Tao Y H, Chen X, Fan J, Wang S, Xiao C, Cui F, Li Y, Bian Z, Chen X S, Wang X H. Chem Sci , 2015 . 6 6385 - 6391 . DOI:10.1039/C5SC02479Jhttp://doi.org/10.1039/C5SC02479J .

Wu Y, Zhang D, Ma P, Zhou R, Hua L, Liu R. Nat Commun , 2018 . 9 5297 - 6306 . DOI:10.1038/s41467-018-07711-yhttp://doi.org/10.1038/s41467-018-07711-y .

Chen C, Wang Z, Li Z B. Biomacromolecules , 2011 . 12 2859 - 2863 . DOI:10.1021/bm200849mhttp://doi.org/10.1021/bm200849m .

Xiao C S, Zhao C, He P, Tang Z H, Chen X S, Jing X B. Macromol Rapid Commun , 2010 . 31 991 - 997 . DOI:10.1002/marc.200900821http://doi.org/10.1002/marc.200900821 .

Hou Y, Yuan J, Zhou Y, Yu J, Lu H. J Am Chem Soc , 2016 . 138 10995 - 11000 . DOI:10.1021/jacs.6b05413http://doi.org/10.1021/jacs.6b05413 .

Yang K K, Wang X L, Wang Y Z. J Macromol Sci, Polym Rev , 2002 . C42 373 - 398.

Li X Y, Zhou Q, Wen Z B, Hui Y, Yang K K, Wang Y Z. Polym Degrad Stab , 2015 . 121 253 - 260 . DOI:10.1016/j.polymdegradstab.2015.09.016http://doi.org/10.1016/j.polymdegradstab.2015.09.016 .

Dong F X, Xu C, Tong X Z, Wang X L, Song F, Wang Y Z. J Mol Catal B: Enzym , 2013 . 96 40 - 45 . DOI:10.1016/j.molcatb.2013.06.004http://doi.org/10.1016/j.molcatb.2013.06.004 .

Chen R Y, Zhang Y R, Wang Y Z. J Mol Catal B: Enzym , 2009 . 57 224 - 228 . DOI:10.1016/j.molcatb.2008.09.013http://doi.org/10.1016/j.molcatb.2008.09.013 .

Liu W, Tian G Q, Yang D D, Wu G, Chen S C, Wang Y Z. Polym Chem , 2019 . 10 1526 - 1536 . DOI:10.1039/C9PY00111Ehttp://doi.org/10.1039/C9PY00111E .

Chen Y Y, Wu G, Qiu Z C, Wang X L, Zhang Y, Lu F, Wang Y Z. J Polym Sci, Part A: Polym Chem , 2008 . 46 3207 - 3213 . DOI:10.1002/pola.22656http://doi.org/10.1002/pola.22656 .

Yuan Y, Ding S D, Zhao Y Q, Wang Y Z. Chinese J Polym Sci , 2014 . 32 1678 - 1689 . DOI:10.1007/s10118-014-1545-3http://doi.org/10.1007/s10118-014-1545-3 .

Inoue S, Koinuma H, Tsuruta T. J Polym Sci B Polym Lett , 1969 . 7 287 - 292 . DOI:10.1002/pol.1969.110070408http://doi.org/10.1002/pol.1969.110070408 .

Chen X H, Shen Z Q, Zhang Y F. Macromolecules , 1991 . 24 ( 19 ): 5305 - 5308 . DOI:10.1021/ma00019a014http://doi.org/10.1021/ma00019a014 .

Liu B Y, Zhao X J, Wang X H, Wang F S. J Polym Sci, Part A: Polym Chem , 2001 . 39 ( 16 ): 2751 - 2754 . DOI:10.1002/(ISSN)1099-0518http://doi.org/10.1002/(ISSN)1099-0518 .

Zhang X H, Wei R J, Zhang Y Y, D u, B Y, Fan Z Q. Macromolecules , 2015 . 48 536 - 544 . DOI:10.1021/ma5023742http://doi.org/10.1021/ma5023742 .

Lu X B, Wang Y. Angew Chem Int Ed , 2004 . 43 ( 27 ): 3574 - 3577 . DOI:10.1002/(ISSN)1521-3773http://doi.org/10.1002/(ISSN)1521-3773 .

Lu X B, Ren W M, Wu G P. Acc Chem Res , 2012 . 45 ( 10 ): 1721 - 1735 . DOI:10.1021/ar300035zhttp://doi.org/10.1021/ar300035z .

Liu Y, Ren W M, Liu J, Lu X B. Angew Chem Int Ed , 2013 . 52 ( 44 ):11594 - 11598 . DOI:10.1002/anie.201305154http://doi.org/10.1002/anie.201305154 .

Liu Y, Ren W M, Liu C, Fu S, Wang M, He K K, Li R R, Lu X B. Macromolecules , 2014 . 47 ( 22 ): 7775 - 7788 . DOI:10.1021/ma5019186http://doi.org/10.1021/ma5019186 .

Liu Y, Ren W M, Wang M, Liu C, Lu X B. Angew Chem Int Ed , 2015 . 54 ( 7 ): 2241 - 2244 . DOI:10.1002/anie.201410692http://doi.org/10.1002/anie.201410692 .

Liu Y, Wang M, Ren W M, Xu Y C, Lu X B. Angew Chem Int Ed , 2015 . 54 ( 24 ): 7042 - 7046 . DOI:10.1002/anie.201501417http://doi.org/10.1002/anie.201501417 .

Lv Xiaobing(吕小兵). Acta Polymerica Sinica(高分子学报) , 2016 . ( 9 ): 1166 - 1178 . DOI:10.11777/j.issn1000-3304.2016.16151http://doi.org/10.11777/j.issn1000-3304.2016.16151 .

Sheng X F, Wu W, Qin Y S, Wang X H, Wang F S. Polym Chem , 2015 . 6 ( 26 ): 4719 - 4724 . DOI:10.1039/C5PY00335Khttp://doi.org/10.1039/C5PY00335K .

Wei T, Lei L J, Kang H L, Qiao B, Wang Z, Zhang L Q, Coates P, Hua K C, Kulig J. Adv Eng Mater , 2011 . 14 112 - 118.

Wang R G, Ma J, Zhou X X, Wang Z, Kang H L, Zhang L Q, Hua K C, Kulig J. Macromolecules , 2012 . 45 ( 17 ): 6830 - 6839 . DOI:10.1021/ma301183khttp://doi.org/10.1021/ma301183k .

Lei W W, Russell T P, Hu L, Zhou X X, Qiao H, Wang W C, Wang R G, Zhang L Q. ACS Sustain Chem Eng , 2017 . 5 5214 - 5223 . DOI:10.1021/acssuschemeng.7b00574http://doi.org/10.1021/acssuschemeng.7b00574 .

Qiao H, Wang R G, Yao H, Zhou X X, Lei W W, Hu X R, Zhang L Q. Polym Chem , 2015 . 6 ( 34 ): 6140 - 6151 . DOI:10.1039/C5PY00720Hhttp://doi.org/10.1039/C5PY00720H .

Wang J G, Liu X Q, Zhang Y J, Liu F, Zhu J. Polymer , 2016 . 103 1 - 8 . DOI:10.1016/j.polymer.2016.09.030http://doi.org/10.1016/j.polymer.2016.09.030 .

Wang J G, Liu X Q, Liu F, Zhang X Q, Zhu J. J Polym Sci, Part A: Polym Chem , 2017 . 55 3298 - 3307 . DOI:10.1002/adma.200601521http://doi.org/10.1002/adma.200601521 .

Hu H, Zhang R Y, Wang J G, Ying W B, Zhu J. ACS Sustain Chem Eng , 2018 . 6 ( 6 ): 7488 - 7498 . DOI:10.1021/acssuschemeng.8b00174http://doi.org/10.1021/acssuschemeng.8b00174 .

Cai J, Zhang L N. Macromol Biosci , 2005 . 5 ( 6 ): 539 - 548 . DOI:10.1002/(ISSN)1616-5195http://doi.org/10.1002/(ISSN)1616-5195 .

Cai J, Zhang L N, Liu S L, Liu Y T, Xu X J, Chen X M, Chu B, Guo X L, Xu J, Cheng H, Han C C, Kuga S. Macromolecules , 2008 . 41 ( 23 ): 9345 - 9351 . DOI:10.1021/ma801110ghttp://doi.org/10.1021/ma801110g .

Cai J, Zhang L N. Biomacromolecules , 2006 . 7 ( 1 ): 183 - 189 . DOI:10.1021/bm0505585http://doi.org/10.1021/bm0505585 .

Wang S, Lu A, Zhang L N. Prog Polym Sci , 2016 . 53 169 - 206 . DOI:10.1016/j.progpolymsci.2015.07.003http://doi.org/10.1016/j.progpolymsci.2015.07.003 .

Cai J, Zhang L N, Zhou J P, Qi H S, Chen H, Kondo T, Chen X M, Chu B. Adv Mater , 2007 . 19 ( 6 ): 821 - 825 . DOI:10.1002/(ISSN)1521-4095http://doi.org/10.1002/(ISSN)1521-4095 .

Xu DF, Chen C J, Xie J, Zhang B, Miao L, Cai J, Huang Y H, Zhang L N. Adv Energy Mater , 2016 . 6 ( 6 ): 1501929 DOI:10.1002/aenm.201501929http://doi.org/10.1002/aenm.201501929 .

Yang X F, Liu G Q, Peng L, Guo J H, Tao L, Yuan J Y, Chang C Y, Wei Y, Zhang L N. Adv Funct Mater , 2017 . 27 ( 40 ): 1703174 DOI:10.1002/adfm.v27.40http://doi.org/10.1002/adfm.v27.40 .

Zhao D, Huang J C, Zhong Y, Li K, Zhang L N, Cai J. Adv Funct Mater , 2016 . 26 ( 34 ): 6279 - 6287 . DOI:10.1002/adfm.v26.34http://doi.org/10.1002/adfm.v26.34 .

Cai J, Liu SL, Feng J, Kimura S, Wada M, Kuga S, Zhang L N. Angew Chem Int Ed , 2012 . 51 ( 9 ): 2076 - 2079 . DOI:10.1002/anie.201105730http://doi.org/10.1002/anie.201105730 .

Dong Y, Jia B Q, Fu F Y, Zhang H Y, Zhang L N, Zhou J P. Angew Chem Int Ed , 2016 . 55 ( 43 ): 13504 - 13508 . DOI:10.1002/anie.201607455http://doi.org/10.1002/anie.201607455 .

Shi Z Q, Gao H C, Feng J, Ding B B, Cao X D, Kuga S, Wang Y J, Zhang L N, Cai J. Angew Chem Int Ed , 2014 . 53 ( 21 ): 5380 - 5384 . DOI:10.1002/anie.v53.21http://doi.org/10.1002/anie.v53.21 .

Ren Qiang(任强), Wu Jin(武进), Zhang Jun(张军), He Jiasong(何嘉松), Guo Meili(过梅丽). Acta Polymerica Sinica(高分子学报) , 2003 . ( 3 ): 448 - 451 . DOI:10.3321/j.issn:1000-3304.2003.03.025http://doi.org/10.3321/j.issn:1000-3304.2003.03.025 .

Zhang H, Wu J, Zhang J, He J S. Macromolecules , 2005 . 38 8272 - 8277 . DOI:10.1021/ma0505676http://doi.org/10.1021/ma0505676 .

Zhang J M, Zhang H, Wu J, Zhang J, He J S, Xiang J F. Phys Chem Chem Phys , 2010 . 12 1941 - 1947 . DOI:10.1039/b920446fhttp://doi.org/10.1039/b920446f .

Zhang H, Wang Z G, Zhang Z N, Wu J, Zhang J, He J S. Adv Mater , 2007 . 19 698 - 704 . DOI:10.1002/adma.200600442http://doi.org/10.1002/adma.200600442 .

Zhang J M, Wu J, Yu J, Zhang X Y, He J S, Zhang J. Mater Chem Front , 2017 . 1 1273 - 1290 . DOI:10.1039/C6QM00348Fhttp://doi.org/10.1039/C6QM00348F .

Fu F Y, Zhou J P, Zhou X M, Zhang L N, Li D X, Kondo T. ACS Sustain Chem Eng , 2014 . 2 ( 10 ): 2363 - 2370 . DOI:10.1021/sc5003787http://doi.org/10.1021/sc5003787 .

Fu F Y, Li L Y, Liu L J, Cai J, Zhang Y P, Zhou J P, Zhang L N. ACS Appl Mater Interfaces , 2015 . 7 ( 4 ): 2597 - 2606 . DOI:10.1021/am507639bhttp://doi.org/10.1021/am507639b .

Song Y B, Sun Y X, Zhang X Z, Zhou J P, Zhang L N. Biomacromolecules , 2008 . 9 ( 8 ): 2259 - 2264 . DOI:10.1021/bm800429ahttp://doi.org/10.1021/bm800429a .

You J, Xie S Y, Cao J F, Ge H, Xu M, Zhou J P, Zhang L N. Macromolecules , 2016 . 49 ( 3 ): 1049 - 1059 . DOI:10.1021/acs.macromol.5b02231http://doi.org/10.1021/acs.macromol.5b02231 .

Wu J, Zhang J, Zhang H, He J S, Ren Q, Guo M L. Biomacromolecules , 2004 . 5 ( 2 ): 266 - 268 . DOI:10.1021/bm034398dhttp://doi.org/10.1021/bm034398d .

Cao Y, Wu J, Meng T, Zhang J, He J S, Li H Q, Zhang Y. Carbohyd Polym , 2007 . 69 ( 4 ): 665 - 672 . DOI:10.1016/j.carbpol.2007.02.001http://doi.org/10.1016/j.carbpol.2007.02.001 .

Luan Y H, Zhang J M, Zhan M S, Wu J, Zhang J, He J S. Carbohyd Polym , 2013 . 92 ( 1 ): 307 - 311 . DOI:10.1016/j.carbpol.2012.08.111http://doi.org/10.1016/j.carbpol.2012.08.111 .

Zhang J M, Wu J, Cao Y, Sang S M, Zhang J, He J S. Cellulose , 2009 . 16 ( 2 ): 299 - 308 . DOI:10.1007/s10570-008-9260-2http://doi.org/10.1007/s10570-008-9260-2 .

Yan C H, Zhang J M, Lv Y X, Yu J, Wu J, Zhang J, He J S. Biomacromolecules , 2009 . 10 ( 8 ): 2013 - 2018 . DOI:10.1021/bm900447uhttp://doi.org/10.1021/bm900447u .

Tian W G, Zhang J M, Yu J, Wu J, Nawaz H, Zhang J, He J S, Wang F S. Adv Optical Mater , 2016 . 4 ( 12 ): 2044 - 2050 . DOI:10.1002/adom.v4.12http://doi.org/10.1002/adom.v4.12 .

Tian W G, Zhang J M, Yu J, Wu J, Zhang J, He J S, Wang F S. Adv Funct Mater , 2018 . 28 ( 9 ): 1703548 DOI:10.1002/adfm.v28.9http://doi.org/10.1002/adfm.v28.9 .

Jia R N, Tian W G, Bai H T, Zhang J M, Wang S, Zhang J. Nat Commun , 2019 . 10 795 DOI:10.1038/s41467-019-08675-3http://doi.org/10.1038/s41467-019-08675-3 .

Chen Wenshuai(陈文帅), Yu Haipeng(于海鹏), Liu Yixing(刘一星), Jiang Naixiang(蒋乃翔), Chen Peng(陈鹏). Acta Polymerica Sinica(高分子学报) , 2010 . ( 11 ): 1320 - 1326 . DOI:10.3724/SP.J.1105.2010.09438http://doi.org/10.3724/SP.J.1105.2010.09438 .

Chen W S, Yu H P, Liu Y X, Chen P. Carbohyd Polym , 2011 . 83 ( 4 ): 1804 - 1811 . DOI:10.1016/j.carbpol.2010.10.040http://doi.org/10.1016/j.carbpol.2010.10.040 .

Li Y N, Liu Y Z, Chen W S, Wang Q W, Liu Y X, Li J, Yu H P. Green Chem , 2016 . 18 ( 4 ): 1010 - 1018 . DOI:10.1039/C5GC02576Ahttp://doi.org/10.1039/C5GC02576A .

Liu Y Z, Chen W S, Xia Q Q, Guo B T, Wang Q W, Liu S X, Liu Y X, Li J, Yu H P. ChemSusChem , 2017 . 10 ( 8 ): 1692 - 1700 . DOI:10.1002/cssc.201601795http://doi.org/10.1002/cssc.201601795 .

Chen W S, Yu H P, Lee S Y, Wei T, Li J, Fan Z J. Chem Soc Rev , 2018 . 47 ( 8 ): 2837 - 2872 . DOI:10.1039/C7CS00790Fhttp://doi.org/10.1039/C7CS00790F .

Rao X M, Kuga S, Wu M, Huang Y. Cellulose , 2015 . 22 2341 - 2348 . DOI:10.1007/s10570-015-0659-2http://doi.org/10.1007/s10570-015-0659-2 .

Zhao M M, Kuga S, Jiang S D, Wu M, Huang Y. Cellulose , 2016 . 23 ( 5 ): 2809 - 2818 . DOI:10.1007/s10570-016-1033-8http://doi.org/10.1007/s10570-016-1033-8 .

Zhao M M, Kuga S, Wu M, Huang Y. Green Chem , 2016 . 18 ( 10 ): 3006 - 3012 . DOI:10.1039/C6GC00660Dhttp://doi.org/10.1039/C6GC00660D .

Li Y, Jiang K, Feng J, Liu J Z, Huang R, Chen Z J, Yang J C, Dai Z H, Chen Y, Wang N X, Zhang W J, Zheng W F, Yang G, Jiang X Y. Adv Healthc Mater , 2017 . 6 ( 11 ): 1601343 DOI:10.1002/adhm.v6.11http://doi.org/10.1002/adhm.v6.11 .

Li S, Huang D, Zhang B, Xu X, Wang M, Yang G, Yan S. Adv Energy Mater , 2014 . 4 ( 10 ): 1301655 DOI:10.1002/aenm.201301655http://doi.org/10.1002/aenm.201301655 .

Gao M H; Li J, Bao Z X, Hu M D, Nian R, Feng D X, An D, Li X, Xian M, Zhang H B. Nat Commun , 2019 . 10 437 DOI:10.1038/s41467-018-07879-3http://doi.org/10.1038/s41467-018-07879-3 .

Hong M, Chen E Y. Nat Chem , 2016 . 8 ( 1 ): 42 - 49 . DOI:10.1038/nchem.2391http://doi.org/10.1038/nchem.2391 .

Zhao N, Ren C, Li H, Li Y, Liu S, Li Z. Angew Chem Int Ed , 2017 . 56 ( 42 ): 12987 - 12990 . DOI:10.1002/anie.201707122http://doi.org/10.1002/anie.201707122 .

Shen Y, Zhao Z, Li Y, Liu S, Liu F, Li Z. Polym Chem , 2019 . 10 ( 10 ): 1231 - 1237 . DOI:10.1039/C8PY01812Jhttp://doi.org/10.1039/C8PY01812J .

Zhang C J, Hu L F, Wu H L, Cao X H, Zhang X H. Macromolecules , 2018 . 51 ( 21 ): 8705 - 8711 . DOI:10.1021/acs.macromol.8b01757http://doi.org/10.1021/acs.macromol.8b01757 .

更多指标>

Views

273

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Chemical Synthesis of Crystalline Biodegradable Polyhydroxyalkanoates

Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters

Related Author

No data

Related Institution

Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education

Collgene of Chemical Engineering, Qingdao University of Science and Technology

Key Laboratory of Biobased Polymer Materials, Shandong Provincial Education Department, College of Polymer Science and Engineering, Qingdao University of Science and Technology

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰