Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2′,3′-d]pyran)

Xin Ke; Ling-xian Meng; Xiang-jian Wan; Xin Zhang; Mei-jia Chang; Chen-xi Li; Yong-sheng Chen

doi:10.11777/j.issn1000-3304.2019.19131

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Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2′,3′-d]pyran)

更新时间：2021-01-26

- Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2′,3′-d]pyran)
- Acta Polymerica Sinica Vol. 51, Issue 2, Pages: 148-157(2020)
- 作者机构：
  
  南开大学化学学院元素有机化学国家重点实验室纳米科学与技术研究中心功能高分子材料重点实验室　天津 300071
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.19131
  CLC：
- Published：2020-2，
  
  Published Online：31 August 2019，
  
  Received：8 July 2019，
  
  Revised：1 August 2019，
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Xin Ke, Ling-xian Meng, Xiang-jian Wan, Xin Zhang, Mei-jia Chang, Chen-xi Li, Yong-sheng Chen. Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2′,3′-d]pyran). [J]. Acta Polymerica Sinica 51(2):148-157(2020)
DOI：

Xin Ke, Ling-xian Meng, Xiang-jian Wan, Xin Zhang, Mei-jia Chang, Chen-xi Li, Yong-sheng Chen. Synthesis and Properties of a Conjugated Acceptor Material for Organic Solar Cells Based on Indacenobis(dithieno[3,2-b:2′,3′-d]pyran). [J]. Acta Polymerica Sinica 51(2):148-157(2020) DOI： 10.11777/j.issn1000-3304.2019.19131.

摘要

设计合成了一个基于引达省并二噻吩吡喃的稠环有机受体材料. 吡喃环的引入提高了分子中间核的给电子能力，使分子的最高占有轨道能级(HOMO)显著提升，进而使分子的吸收光谱红移. 通过理论计算，证实了分子的设计思路的可行性. 紫外吸收光谱分析发现，该受体材料具有较窄的带隙(1.30 eV)，其最大吸收峰在843 nm，吸收截止到956 nm，有利于活性层材料对太阳光的充分吸收利用. 将该受体材料与聚合物给体材料PM6共混制备有机太阳能电池器件，获得了0.86 V的开路电压(open-circuit voltage，

)、20.61 mA cm

−2

的短路电流密度(short-circuit current density，

)和10.85%的能量转化效率(power conversion efficiency，PCE).

Abstract

We designed and synthetized a new non fullerene acceptor with an A-D-A structure

named IDTO2HT-2F

based on indacenobis(dithieno[3

2-b:2′

3′-d]pyran) for organic solar cells. The dithieno[3

2-b:2′

3′-d]

pyran will improve the electron-donating capability of the unit and lift the highest occupied molecular orbital (HOMO). Thus

the band gap decreases

making the maximum absorption peak red-shift. Theoretical calculation based on density functional theory (DFT) proved the feasibility of this molecular design. The molecule IDTO2HT-2F has a narrow bang gap of 1.30 eV with the solid absorption edge extended to 956 nm

which is complementary to that of the polymer PM6 film. The broad absorption of the active layer ensures the photovoltaic device to produce high photocurrent. With 0.5% DIO additive and thermal annealing at 120 °C for 10 min

the organic solar cell based on the acceptor IDTO2HT-2F and the polymer PM6 exhibits a power conversion efficiency (PCE) of 10.85% with a short circuit current density (

) of 20.61 mA cm

−2

an open-circuit voltage (

) of 0.86 V and a fill factor (FF) of 0.62. The results indicate that the strategy of introducing pyran into the molecular backbone is an effective way to tune the absorption and energy level of the molecules

which is also a promising method to design new non fullerene acceptors.

关键词

有机太阳能电池受体材料二噻吩吡喃

Keywords

Organic solar cellsAcceptor materialsDithieno[32-b:2′3′-d]pyran

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Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University

College of Textiles & Clothing, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao University

School of Materials, Sun Yat-sen University

State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences

Institute of Polymer Science and Engineering, School of Chemical Engineering, Hebei University of Technology

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