The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy

Rong-chun Zhang

doi:10.11777/j.issn1000-3304.2019.19175

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The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy

更新时间：2021-01-26

- The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy
- Acta Polymerica Sinica Vol. 51, Issue 2, Pages: 136-147(2020)
- 作者机构：
  
  华南理工大学分子科学与工程学院华南软物质科学与技术高等研究院　广州 510640
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2019.19175
  CLC：
- Published：2020-2，
  
  Published Online：25 November 2019，
  
  Received：29 September 2019，
  
  Revised：28 October 2019，
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Rong-chun Zhang. The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy. [J]. Acta Polymerica Sinica 51(2):136-147(2020)
DOI：

Rong-chun Zhang. The Microstructures and Molecular Interactions in Multiphase Polymers: Insights from Solid-State NMR Spectroscopy. [J]. Acta Polymerica Sinica 51(2):136-147(2020) DOI： 10.11777/j.issn1000-3304.2019.19175.

摘要

近年来固体核磁共振(NMR)技术在聚合物材料表征领域正发挥着越来越重要的作用，已经成为研究聚合物微观结构、链段动力学、分子间相互作用等微观信息及阐明材料结构-功能-性质关系必不可少的重要手段. 本文将综述我们近年来系统构建和发展的固体NMR方法及其在研究多相聚合物微观结构、分子间相互作用和交联网络等问题中的应用. 此外，针对存在不均匀性动力学的多相聚合物体系，我们发展了增强固体NMR谱图灵敏度的新方法.

Abstract

In recent decades

solid-state nuclear magnetic resonance (NMR) spectroscopy has been playing an important role in the characterization of polymer materials. To some degree

it has become one of the indispensable tools for studying the microstructures

segmental dynamics and inter-/intra-molecular interactions and elucidating the structure-functionality-property relationship of multiphase polymer materials

because the anisotropic spin interactions in the molecules can be selectively manipulated

via

various radiofrequency pulse sequence design. As a result

NMR can provide important information on a length scale from 0.1 nm to 100 nm and a time scale from 1 ns to 100 s. Herein

in this current review article

we will review some of our recently developed solid-state NMR approaches specifically for applications in polymers

including quantitative determination of compositional contents

characterization of crosslinking/entanglement density and inhomogeneity of the network

hydrogen bonding interactions between segments

and so on. A variety of typical examples

including self-healing supramolecular rubbers

thermal reversible polyurethanes

dual-cross-linked hydrogels

elastomers

etc

are given in detail

showing how various solid-state NMR approaches were implemented to quantitatively characterizing the structures

molecular interactions

and crosslinking network. Furthermore

due to the presence of heterogeneous dynamic in multiphase polymers

the applications of traditional solid-state NMR techniques are sustainably limited

and we also developed corresponding novel solid-state NMR approaches to overcome the limitations and enhance the spectral resolution and signal sensitivity.

关键词

多相聚合物固体核磁结构和动力学交联网络链段相互作用

Keywords

Multiphase polymerSolid-state NMRStructures and dynamicsCrosslinking networkSegmental interactions

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