Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones

Qi-ran Lu; Wei You

doi:10.11777/j.issn1000-3304.2020.10123

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Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones

更新时间：2021-01-26

- Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones
- Acta Polymerica Sinica Vol. 51, Issue 10, Pages: 1140-1146(2020)
- 作者机构：
  
  1.中国科学院化学研究所北京分子科学国家研究中心中国科学院工程塑料重点实验室　北京 100190
  2.中国科学院大学　北京 100049
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.10123
  CLC：
- Published：1 September 2020，
  
  Published Online：27 July 2020，
  
  Received：15 May 2020，
  
  Revised：1 June 2020，
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Qi-ran Lu, Wei You. Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones. [J]. Acta Polymerica Sinica 51(10):1140-1146(2020)
DOI：

Qi-ran Lu, Wei You. Synthetic Strategies towards Anion Exchange Membranes with Polyethylene Backbones. [J]. Acta Polymerica Sinica 51(10):1140-1146(2020) DOI： 10.11777/j.issn1000-3304.2020.10123.

摘要

随着人们对生活环境的保护和对可持续发展的需求与日俱增，对于能够实现清洁、高效、廉价能源转化的电化学设备的研究也日益深入. 当这些设备在碱性环境下运行时，可以传输氢氧根的阴离子交换膜（AEM）就是核心部件之一，而AEM的离子导电性和碱性稳定性直接关系着设备的能量转化效率和耐久性. 具有聚乙烯骨架的阴离子交换膜(PE-AEM)由于其化学稳定性突出、阳离子兼容性好、机械性能柔韧等优点，近些年来受到了广泛的关注. 本专论归纳了PE-AEM的合成策略，包括聚合氢化法、直接共聚法和后修饰接枝法，在其中着重介绍环辛烯开环易位聚合(ROMP)后还原方法的发展历程，比较不同制备路线的优缺点，总结产物的化学结构和性能的关系，并且对PE-AEM的前景进行了展望.

Abstract

With the emerging demand of environmental protection and sustainable development

devices that can perform clean

efficient

and inexpensive energy conversion (

e.g.

alkaline fuel cells

water electrolysis

redox flow batteries

etc.

) have attracted increasing attention. Anion exchange membranes (AEMs) are a class of solid polyelectrolytes that are key components in the above-mentioned alkaline energy conversion devices to transport hydroxide anions. Two of the key properties of AEMs are ionic conductivity and alkaline stability

as they are directly related to the efficiency and durability of the devices

respectively. The AEMs bearing polyethylene backbones (PE-AEMs) have outstanding chemical stability

good compatibility with various cations

and strong mechanical properties

and thus they become promising candidates for high-performance AEMs. In this account

we summarize the synthetic strategies of PE-AEMs

which include ring-opening-metathesis polymerization (ROMP) followed by hydrogenation

derivatization of poly(ethylene-

-styrene)

direct copolymerization of functionalized terminal alkenes with ethylene

and radiation graft to modify polyethylene films. Among all these strategies

we specifically focus on the development of sequential cyclooctene ROMP and hydrogenation strategy

as it has the advantages of well-defined polymer structures

precise control of functionality distribution

and excellent tolerance to diverse functional groups. We also evaluate the structure-property relationship of the resultant PE-AEM membranes and discuss the future of these materials.

关键词

阴离子交换膜聚乙烯合成策略碱性稳定性

Keywords

Anion exchange membranePolyethyleneSynthetic strategyAlkaline stability

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