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1.南京邮电大学信息材料与纳米技术研究院 有机电子与信息显示重点实验室 江苏国家先进材料协同创新中心 南京 210023
2.南京大学现代工程与应用科学学院 智能光传感与调控技术教育部重点实验室 南京 210093
Published:2020-5,
Published Online:25 March 2020,
Received:3 January 2020,
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Qing-yi Guo, Sai-bo Wu, Yan Qian, Wei Hu. Hierarchical Structures of Self-assembled Liquid Crystals and Their Applications. [J]. Acta Polymerica Sinica 51(5):484-500(2020)
Qing-yi Guo, Sai-bo Wu, Yan Qian, Wei Hu. Hierarchical Structures of Self-assembled Liquid Crystals and Their Applications. [J]. Acta Polymerica Sinica 51(5):484-500(2020) DOI: 10.11777/j.issn1000-3304.2020.20002.
液晶的分层组装与刺激响应特性使其在先进功能材料的开发与应用领域具有独特的优势. 通过特定的技术手段诱导其自组装行为,可带来新奇的光学、机械、电磁等性能,进而实现一系列全新的技术应用. 本文主要针对近晶相、胆甾相、蓝相这三种特殊的液晶相态,系统介绍了多形态焦锥畴结构,分层油纹,螺旋结构,双螺旋扭曲柱立方晶格等多层级结构,重点论述了材料组分优化,几何结构限制以及外场激励等条件下液晶多层级结构的大面积精细操控,回顾了其在粒子操控、表面改性、光子技术等领域的相关技术应用,并总结展望了液晶组装技术与应用的发展前景.
Liquid crystals
featured by self-assembly property and stimuli responsiveness
have attracted intensive attention not only in fundamental material sciences
but also in advanced functional applications. At different phases
liquid crystals exhibit distinguished structures
such as layered focal conic domains and oil streaks in smectics
lying or standing helical structures in cholesterics
and cubic lattices stacked by double-twisted structures in blue phases. These hierarchical structures present novel optical
mechanical and electromagnetic characteristics
which can be further modulated by external stimuli. In recent years
high-quality liquid crystal hierarchical structures have been realized in large scales
via
optimizing material components and introducing external confinements. Multi-dimensional manipulations of these hierarchical structures have been achieved by adopting various external stimuli. A series of remarkable applications of such liquid crystal hierarchical structures in particle manipulation
surface modification and optical devices have been demonstrated. This paper reviews the latest research progress in above fields and aims to extend the understanding of soft matter architectures.
液晶光配向软物质粒子操控光子元件
Liquid crystalPhotoalignmentSoft matterParticle manipulationOptical device
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