Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids

Chuan-qiang Zhou; Jie Han; Rong Guo

doi:10.11777/j.issn1000-3304.2020.20010

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Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids

更新时间：2021-01-26

- Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids
- Acta Polymerica Sinica Vol. 51, Issue 5, Pages: 517-529(2020)
- 作者机构：
  
  1.扬州大学化学化工学院　扬州 225002
  2.扬州大学测试中心　扬州 225009
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20010
  CLC：
- Published：2020-5，
  
  Published Online：9 April 2020，
  
  Received：13 January 2020，
  
  Revised：16 February 2020，
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Chuan-qiang Zhou, Jie Han, Rong Guo. Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids. [J]. Acta Polymerica Sinica 51(5):517-529(2020)
DOI：

Chuan-qiang Zhou, Jie Han, Rong Guo. Controllable Synthesis and Catalysis Application of Conducting Polymer/Noble Metal Nanoparticle Hybrids. [J]. Acta Polymerica Sinica 51(5):517-529(2020) DOI： 10.11777/j.issn1000-3304.2020.20010.

摘要

导电高分子/贵金属复合纳米材料因其在催化、传感、表面增强拉曼、光热治疗等诸多领域的应用前景而受到广泛关注. 本文主要介绍我们课题组近年来利用可控合成策略制备的负载型和包埋型两种结构聚苯胺/贵金属复合纳米材料，以及利用复合纳米材料的结构和功能特性，对其在多相催化领域的应用、结构与催化性能之间构效关系的探索.

Abstract

Conducting polymer/noble metal nanoparticle hybrids have aroused increasing interest due to their potential application in ﬁelds of catalysis

sensing

surface-enhanced Raman

photo-thermal therapy and so on. The incorporation of conducting polymers with noble metal nanoparticles can produce new hybrids showing distinct properties that are not observed in the individual components. In general

the strategies in the synthesis of conducting polymer/noble metal nanoparticle hybrids involve the direct mixing of conducting polymers and noble metal nanoparticles

redox reaction between conducting polymers and noble metal ions

redox reaction between aniline monomers and noble metal ions

as well as aniline monomer polymerization in the presence of noble metal nanoparticles. Noble metal nanoparticles are either supported on surfaces of conducting polymer nanostructures or embedded in conducting polymer matrix. Our research focuses on the controllable synthesis of polyaniline/noble metal nanoparticle hybrids with compact interactions

which will show potential application as advanced nanocatalysts in diverse catalytic reactions. This fearfure artcle aims at reviewing our work in recent years on the synthetic strategies and catalysis application of polyaniline/noble metal nanoparticle hybrids. The supported polyaniline/noble metal nanoparticle hybrids can be synthesized through the redox reaction between polyaniline and noble metal ion

where the configuration of hybrids and size of supported noble metal nanoparticles are determined by polyaniline nanostructures and functional doping acids. The embedded polyaniline/noble metal nanoparticle hybrids can be synthesized through the redox reaction between aniline monomer and noble metal ion

where the functional substituents in aniline monomer play the determining role in reducing the size of noble metal nanoparticles in hybrids. In addition

the polymerization of aniline monomer on surfaces of noble metal nanoparticles can also lead to embedded polyaniline/noble metal nanoparticle hybrids with compact interaction. Polyaniline/noble metal nanoparticle hybrids have been successfully applied as nanocatalysts in nitrophenol reduction

alcohol oxidation

Suzuki-Miyaura cross-coupling

and Ullmann reactions. In particular

a novel yolk-in-shell nanostructure of polyaniline/Au hybrids have been emphasized and the synergistic catalytic effect of polyaniline for Au nanoparticles has been discussed.

关键词

导电高分子聚苯胺贵金属纳米粒子复合材料催化

Keywords

Conducting polymerPolyanilineNoble metal nanoparticleHybridCatalysis

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College of Chemistry and Molecular Engineering, Peking University

College of Chemistry and Chemical Engineering, Chongqing University

Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University

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College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University

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