Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu<sup>2+</sup> Sensor

Chen-hui Liu; Gen-qi Liu; Chen-rui Ren; Hong-kai Shi; Ke Xue; Yun-lei Cao; Huan-huan Li; Jian-xun Liu

doi:10.11777/j.issn1000-3304.2020.20030

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Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu²⁺ Sensor

更新时间：2021-01-26

- Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu²⁺ Sensor
- Acta Polymerica Sinica Vol. 51, Issue 7, Pages: 762-770(2020)
- 作者机构：
  
  西北工业大学化学与化工学院　西安 710129
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20030
  CLC：
- Published：2020-7，
  
  Published Online：27 May 2020，
  
  Received：12 February 2020，
  
  Revised：18 March 2020，
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Chen-hui Liu, Gen-qi Liu, Chen-rui Ren, Hong-kai Shi, Ke Xue, Yun-lei Cao, Huan-huan Li, Jian-xun Liu. Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu²⁺ Sensor. [J]. Acta Polymerica Sinica 51(7):762-770(2020)
DOI：

Chen-hui Liu, Gen-qi Liu, Chen-rui Ren, Hong-kai Shi, Ke Xue, Yun-lei Cao, Huan-huan Li, Jian-xun Liu. Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu²⁺ Sensor. [J]. Acta Polymerica Sinica 51(7):762-770(2020) DOI： 10.11777/j.issn1000-3304.2020.20030.

摘要

以聚苯乙烯二维光子晶体阵列为模板，戊二醛为交联剂，制备了聚乙烯醇二维光子晶体水凝胶(PVA 2DPCH)，再以巯基乙酸为酯化剂，通过聚乙烯醇(PVA)的巯基化改性，得到巯基化聚乙烯醇二维光子晶体水凝胶(PVA-SH 2DPCH). 利用德拜环法，研究了PVA-SH 2DPCH对Cu

的响应行为. 结果表明，PVA-SH 2DPCH对Cu

具有超灵敏响应，在Cu

溶液中，凝胶收缩，其德拜环直径(

)随Cu

浓度的增大而增大，当Cu

浓度由0增加至10

−15

mol/L时，其德拜环直径即可增加0.45 cm，当浓度继续增大到10

−7

mol/L时，其德拜环直径(Δ

)可增加0.85 cm. 当Cu

浓度在10

−15

~ 10

−7

mol/L范围内时，PVA-SH 2DPCH的德拜环直径变化(Δ

)与Cu

浓度(

)呈线性关系，其线性回归方程为Δ

= 1.195 + 0.0493 × log

，(Δ

cm；

mol/L)，

= 0.99899. 以制备的PVA-SH 2DPCH为Cu

传感器，利用德拜环法表征溶液中Cu

的浓度，方法简单快速兼具无标记、可视化检测的特点，为现场实时检测Cu

提供了可能.

Abstract

Two-dimensional poly(vinyl alcohol) hydrogel (PVA 2DPCH) was prepared by using two-dimensional photonic crystal array of polystyrene as template and glutaraldehyde as cross-linking agent. Then the mercaptopolyvinyl alcohol two-dimensional photonic crystal hydrogel (PVA-SH 2DPCH) was obtained through thiolization modification of poly(vinyl alcohol) (PVA)

with mercaptoacetic acid as esterifying agent. The response behavior of PVA-SH 2DPCH to Cu

was studied with the Debye ring method. The results showed that PVA-SH 2DPCH had a high-sensitive response to Cu

. The gel shrunk in Cu

solution

and its Debye ring diameter (

) increased with increasing concentration of Cu

. When the concentration of Cu

increased from 0 to 10

−15

mol/L

its Debye ring diameter increased by 0.45 cm; when the concentration continued to 10

−7

mol/L

its Debye ring diameter (Δ

) increased by 0.85 cm. To conclude

when the concentration of Cu

is in the range of 10

−15

− 10

−7

mol/L

the Debye ring diameter change (Δ

) of PVA-SH 2DPCH has a linear relationship with the concentration of Cu

(

)

and the linear regression equation is Δ

= 1.195 + 0.0493 × log

(Δ

(cm)

(mol/L))

= 0.99899. With the prepared PVA-SH 2DPCH as a Cu

sensor

and the Debye ring method is adopted to characterize the concentration of Cu

in the solution. Featured by marker-free and visible detection

the Debye ring method is simple but highly efficient

which provides the possibility for real-time detection of Cu

in the field.

关键词

二维光子晶体水凝胶Cu2+化学传感器巯基化聚乙烯醇德拜环

Keywords

Two-dimentional photonic crystalHydrogelDetermination of Cu2+Chemical sensorThiolated polyvinyl alcoholDebye ring

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⁰

Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu2+ Sensor

DOI：10.11777/j.issn1000-3304.2020.20030

摘要

Abstract

关键词

Keywords

references

Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu²⁺ Sensor