Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters

Yong Shen; Zhi-bo Li

doi:10.11777/j.issn1000-3304.2020.20050

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Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters

更新时间：2021-01-26

- Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters
- Acta Polymerica Sinica Vol. 51, Issue 8, Pages: 777-790(2020)
- 作者机构：
  
  1.青岛科技大学化工学院　青岛 266042
  2.山东省高等学校生物基高分子材料重点实验室青岛科技大学高分子科学与工程学院　青岛 266042
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20050
  CLC：
- Published：2020-8，
  
  Published Online：3 July 2020，
  
  Received：2 April 2020，
  
  Revised：12 April 2020，
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Yong Shen, Zhi-bo Li. Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters. [J]. Acta Polymerica Sinica 51(8):777-790(2020)
DOI：

Yong Shen, Zhi-bo Li. Ring-opening Polymerization of Cyclic Esters by Utilizing Organophosphazene Bases toward Biodegradable Polyesters. [J]. Acta Polymerica Sinica 51(8):777-790(2020) DOI： 10.11777/j.issn1000-3304.2020.20050.

摘要

脂肪族聚酯作为一类重要的高分子材料，具有优异的生物相容性和生物可降解性以及良好的力学性能，在可吸收手术缝合线、组织工程支架、食品包装等方面已经取得了广泛应用. 环内酯开环聚合是制备脂肪族聚酯材料的一种重要方法. 有机磷腈碱作为一类非离子型、非亲核性有机强碱，在催化环内酯开环聚合方面已经取得了巨大的成功. 本专论综述了有机磷腈碱在催化

-丁内酯及其衍生物、己内酯、戊内酯、丙交酯和大环内酯开环聚合方面的研究进展，对聚合机理进行了适当讨论，并对其未来发展方向作了展望.

Abstract

Given their great biocompatibility

biodegradability and good mechanical properties

aliphatic polyesters as important polymers have been widely used in many applications as absorbable sutures

tissue engineering scaffolds and food packing materials. Aliphatic polyesters can be synthesized by ring-opening polymerization (ROP) of cyclic lactones or lactides. Organophosphazene bases are a family of uncharged

non-nucleophilic organobases

which have achieved great success as organocatalysts for the ROP of cyclic lactones and lactides. This feature article reviewed the recent progresses for ROP of cyclic lactones and lactides by utilizing phosphazene bases as catalysts

including

-butyrolactone and its derivatives

-carprolactone

-valerolactone

lactide and macrolactones. The challenges and perspectives on the further development of phosphazene base catalyzed ROP were also discussed.

关键词

生态环境高分子开环聚合聚酯有机催化磷腈碱

Keywords

Eco-polymersRing-opening polymerizationPolyestersOrganocatalystsPhosphazene bases

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