Progress in the Viscoelasticity Study of Giant Molecules

Jin-tian Luo; Xi-kai Ouyang; Geng-xin Liu

doi:10.11777/j.issn1000-3304.2020.20056

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Progress in the Viscoelasticity Study of Giant Molecules

更新时间：2021-01-26

- Progress in the Viscoelasticity Study of Giant Molecules
- Acta Polymerica Sinica Vol. 51, Issue 7, Pages: 687-697(2020)
- 作者机构：
  
  东华大学先进低维材料中心纤维材料改性国家重点实验室材料科学与工程学院　上海 201620
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20056
  CLC：
- Published：2020-7，
  
  Published Online：24 June 2020，
  
  Received：5 March 2020，
  
  Revised：14 April 2020，
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Jin-tian Luo, Xi-kai Ouyang, Geng-xin Liu. Progress in the Viscoelasticity Study of Giant Molecules. [J]. Acta Polymerica Sinica 51(7):687-697(2020)
DOI：

Jin-tian Luo, Xi-kai Ouyang, Geng-xin Liu. Progress in the Viscoelasticity Study of Giant Molecules. [J]. Acta Polymerica Sinica 51(7):687-697(2020) DOI： 10.11777/j.issn1000-3304.2020.20056.

摘要

巨型分子是一类新型高分子，其构建基元为结构更具刚性的分子纳米粒子，如多面体齐聚倍半硅氧烷(POSS)等. 将多个分子纳米粒子三维连接而形成的一类巨型分子能够保持三维形状，这不同于传统的一维链状高分子. 我们采用流变学手段研究了一系列处于本体条件、且具有不同直径的巨型分子，发现在玻璃化转变温度之上，其动力学由其直径决定. 这与传统高分子中缠结主导的动力学截然不同：当巨型分子的直径跨过临界直径时，其松弛时间增加至少10

倍；在临界直径以上的巨型分子不能扩散和松弛，表现出储能模量的平台，而且模量随温度线性增加，对应于分子纳米粒子的受限运动. 跳出传统高分子的框架，巨型分子展现出不同于“蛇形运动”、“缠结”和“管子模型”的新规律，成为连接高分子体系和胶体体系的桥梁. 随机一级相变理论推测，玻璃化转变时协同运动区域的直径大约为微观运动单元直径的6倍，这个分界与实验中巨型分子的临界直径一致，因此我们将这种类似于玻璃化的状态称为协同玻璃态. 以这些巨型分子为代表的软团簇或可类比为玻璃化中的协同运动区域，将为研究玻璃化转变提供新的实验支持.

Abstract

Giant molecules are a new type of precise polymers whose building blocks are rather rigid molecular nanoparticles

e.g.

polyhedral oligomeric silsesquioxane (POSS). Giant molecules containing a large number of molecular nanoparticles connected in 3-dimension have persistent 3-dimensional shape

and are different from traditional chain-like polymers. We studied a series of hydrophilic giant molecules and associated clusters of hydrophobic giant molecules. Their dynamics in the bulk state

above their glass transition temperature (

) is governed by their diameter

unlike the dynamics of traditional polymers which is governed by entanglement. The relaxation of giant molecules slows down by at least 10

when their diameters increases across the critical diameter. Giant molecules that are larger than the critical diameter cannot relax or diffuse. The exhibited elastic modulus plateau is proportional to temperature

corresponding to the confinement on individual “nanoatom”. 3-Dimensional giant molecules exhibit new rules other than reptation

entanglement

and tube in traditional polymer

and may bridge polymers and colloids. Random First Order Transition theory derived that

at the onset of glass transition

cooperative rearranging regions are 6 times the diameter of basic moving units. This is in accordance with our results. We claim large giant molecules are in a glass-like state

namely cooperative glass. Soft clusters such as giant molecules may resemble the cooperative rearranging region

thus experimentally supporting deeper understanding on glass transition.

关键词

巨型分子流变学动力学软团簇协同玻璃态缠结

Keywords

Giant moleculesRheologyDynamicsSoft-clusterCooperative glassEntanglement

references

Staudinger H. Berichte der deutschen chemischen Gesellschaft (A and B Series) , 1920 . 53 ( 6 ): 1073 - 1085 . DOI:10.1002/cber.19200530627http://doi.org/10.1002/cber.19200530627 .

Zhang Xi(张希). Acta Polymerica Sinica(高分子学报) , 2020 . 51 ( 1 ): 1 DOI:10.11777/j.issn1000-3304.2020.19162http://doi.org/10.11777/j.issn1000-3304.2020.19162 .

An Lijia(安立佳), Chen Erqiang(陈尔强), Cui Shuxun(崔树勋), Dong Xia(董侠), Fu Qiang(傅强), Han Yanchun(韩艳春), He Jiasong(何嘉松), Hu Wenbing(胡文兵), Hu Zuming(胡祖明), Jiang Ming(江明), Li Baohui(李宝会),Li Liangbin(李良彬), Li Lin(李林), Li Weihua(李卫华), Lin Jiaping(林嘉平), Lv Zhongyuan(吕中元), Men Yongfeng(门永锋), Shen Zhihao(沈志豪), Sun Pingchuan(孙平川), Tong Zhen(童真), Wang Dujin(王笃金), Wu Peiyi(武培怡), Xie Xuming(谢续明), Xu Jian(徐坚), Xu Zhikang(徐志康), Xue Qi(薛奇), Yan Shouke(闫寿科), Yang Yuliang(杨玉良), Yu Wei(俞炜), Yu Yanlei(俞燕蕾), Zhang Guangzhao(张广照), Zhang Jun(张军), Zhang Lina(张俐娜), Zhang Pingwen(张平文), Zhang Wenke(张文科), Zhao Jiang(赵江), Zheng Qiang(郑强), Zhou Dongshan(周东山). Acta Polymerica Sinica(高分子学报) , 2019 . 50 ( 10 ): 1047 - 1067 . DOI:10.11777/j.issn1000-3304.2019.19118http://doi.org/10.11777/j.issn1000-3304.2019.19118 .

Yang Yuliang(杨玉良), Zhang Hongdong(张红东). Acta Polymerica Sinica(高分子学报) , 2020 . 51 ( 1 ): 87 - 90 . DOI:10.3321/j.issn:1000-3304.2006.01.017http://doi.org/10.3321/j.issn:1000-3304.2006.01.017 .

de Gennes P G. J Chem Phys , 1971 . 55 ( 2 ): 572 - 579 . DOI:10.1063/1.1675789http://doi.org/10.1063/1.1675789 .

Ruan Yongjin(阮永金), Lu Yuyuan(卢宇源), An Lijia(安立佳). Acta Polymerica Sinica(高分子学报) , 2018 . 12 ( 12 ): 1493 - 1506 . DOI:10.11777/j.issn1000-3304.2018.18172http://doi.org/10.11777/j.issn1000-3304.2018.18172 .

Wang Z, Ma Z, Li L. Macromolecules , 2016 . 49 ( 5 ): 1505 - 1517 . DOI:10.1021/acs.macromol.5b02688http://doi.org/10.1021/acs.macromol.5b02688 .

Lu Yuyuan(卢宇源), An Lijia(安立佳), Wang Jian(王健). Acta Polymerica Sinica(高分子学报) , 2016 . ( 6 ): 688 - 697 . DOI:10.11777/j.issn1000-3304.2016.16108http://doi.org/10.11777/j.issn1000-3304.2016.16108 .

Schroeder C M. J Rheol , 2018 . 62 ( 1 ): 371 - 403 . DOI:10.1122/1.5013246http://doi.org/10.1122/1.5013246 .

Li D, Yang J, Zhao J. Chin Chem Lett , 2018 . 29 ( 3 ): 374 - 380 . DOI:10.1016/j.cclet.2017.07.010http://doi.org/10.1016/j.cclet.2017.07.010 .

Qu Zhichao(瞿志超), Zhang Junsheng(张俊生), Chen Wei(陈葳). Journal of Nanjing University(Natural Science)(南京大学学报(自然科学)) , 2019 . 55 ( 05 ): 819 - 824 . DOI:10.13232/j.cnki.jnju.2019.05.015http://doi.org/10.13232/j.cnki.jnju.2019.05.015 .

Liu C Y, He J, Ruymbeke E v, Keunings R, Bailly C. Polymer , 2006 . 47 ( 13 ): 4461 - 4479 . DOI:10.1016/j.polymer.2006.04.054http://doi.org/10.1016/j.polymer.2006.04.054 .

Graessley W W. The Entanglement Concept in Polymer Rheology. New York: Springer, 1974

Yang Le(杨乐), Wei Jiangtao(魏江涛), Luo Zhu(罗筑), Zheng Qiang(郑强), Liang Xiaokun(梁晓坤). Acta Polymerica Sinica(高分子学报) , 2017 . ( 8 ): 1339 - 1349 . DOI:10.11777/j.issn1000-3304.2017.16342http://doi.org/10.11777/j.issn1000-3304.2017.16342 .

Lou Lijuan(娄立娟), Liu Jianye(刘建叶), Yu Wei(俞炜), Zhou Chixing(周持兴). Polymer Bulletin(高分子通报) , 2009 . ( 10 ): 15 - 23.

Johnson K J, Glynos E, Sakellariou G, Green P. Macromolecules , 2016 . 49 ( 15 ): 5669 - 5676 . DOI:10.1021/acs.macromol.6b00456http://doi.org/10.1021/acs.macromol.6b00456 .

Chen Q, Uneyama T. Rheol Acta , 2014 . 53 ( 9 ): 701 - 714 . DOI:10.1007/s00397-014-0790-2http://doi.org/10.1007/s00397-014-0790-2 .

Liu J, Yu W, Zhou C. J Rheol , 2011 . 55 ( 3 ): 545 - 570 . DOI:10.1122/1.3569136http://doi.org/10.1122/1.3569136 .

Zhu Ziting(朱子霆), Gao Huanhuan(高欢欢), Hu Wenbing(胡文兵). Acta Polymerica Sinica(高分子学报) , 2017 . ( 9 ): 1471 - 1478 . DOI:10.11777/j.issn1000-3304.2017.17055http://doi.org/10.11777/j.issn1000-3304.2017.17055 .

Yan Z C, Costanzo S, Jeong Y, Chang T, Vlassopoulos D. Macromolecules , 2016 . 49 ( 4 ): 1444 - 1453 . DOI:10.1021/acs.macromol.5b02651http://doi.org/10.1021/acs.macromol.5b02651 .

Michieletto D, Turner M S. Proc Natl Acad Sci , 2016 . 113 ( 19 ): 5195 - 5200 . DOI:10.1073/pnas.1520665113http://doi.org/10.1073/pnas.1520665113 .

Chen Ke(陈科). Acta Physica Sinica(物理学报) , 2017 . 66 ( 17 ): 178201 DOI:10.7498/aps.66.178201http://doi.org/10.7498/aps.66.178201 .

Weeks E R, Crocker J C, Levitt A C, Schofield A, Weitz D A. Science , 2000 . 287 ( 5453 ): 627 - 631 . DOI:10.1126/science.287.5453.627http://doi.org/10.1126/science.287.5453.627 .

Zhang Huijun(张会军), Zhang Qi(章琪), Wang Feng(王峰), Han Yilong(韩一龙). Physics(物理) , 2019 . 48 ( 2 ): 69 - 81 . DOI:10.7693/wl20190201http://doi.org/10.7693/wl20190201 .

Wang L, Xu N, Wang W H, Guan P. Phys Rev Lett , 2018 . 120 ( 12 ): 125502 DOI:10.1103/PhysRevLett.120.125502http://doi.org/10.1103/PhysRevLett.120.125502 .

Xu W S, Sun Z Y, An L J. Soft Matter , 2015 . 11 ( 3 ): 627 - 634 . DOI:10.1039/C4SM02290Dhttp://doi.org/10.1039/C4SM02290D .

Mason T G, Weitz D A. Phys Rev Lett , 1995 . 75 ( 14 ): 2770 - 2773 . DOI:10.1103/PhysRevLett.75.2770http://doi.org/10.1103/PhysRevLett.75.2770 .

Ninarello A, Berthier L, Coslovich D. Phys Rev X , 2017 . 7 ( 2 ): 021039 DOI:10.1103/PhysRevX.7.021039http://doi.org/10.1103/PhysRevX.7.021039 .

Mayer C, Zaccarelli E, Stiakakis E, Likos C N, Sciortino F, Munam A, Gauthier M, Hadjichristidis N, Iatrou H, Tartaglia P, Lowen H, Vlassopoulos D. Nat Mater , 2008 . 7 ( 10 ): 780 - 784 . DOI:10.1038/nmat2286http://doi.org/10.1038/nmat2286 .

Uppuluri S, Morrison F A, Dvornic P R. Macromolecules , 2000 . 33 ( 7 ): 2551 - 2560 . DOI:10.1021/ma990634uhttp://doi.org/10.1021/ma990634u .

Agrawal A, Yu H Y, Sagar A, Choudhury S, Archer L A. Macromolecules , 2016 . 49 ( 22 ): 8738 - 8747 . DOI:10.1021/acs.macromol.6b01280http://doi.org/10.1021/acs.macromol.6b01280 .

Hore M J A. Soft Matter , 2019 . 15 ( 6 ): 1120 - 1134 . DOI:10.1039/C8SM02110Dhttp://doi.org/10.1039/C8SM02110D .

Ruan Yingbo(阮英波), Liu Chenyang(刘琛阳). Polymer Bulletin(高分子通报) , 2016 . ( 9 ): 241 - 253 . DOI:10.14028/j.cnki.1003-3726.2016.09.022http://doi.org/10.14028/j.cnki.1003-3726.2016.09.022 .

Tuteja A, Mackay M E, Hawker C J, van Horn B, Ho D L. J Polym Sci, Part B: Polym Phys , 2006 . 44 ( 14 ): 1930 - 1947 . DOI:10.1002/polb.20826http://doi.org/10.1002/polb.20826 .

Chen T, Zhao H Y, Shi R, Lin W F, Jia X M, Qian H J, Lu Z Y, Zhang X X, Li Y K, Sun Z Y. Nat Commun , 2019 . 10 ( 1 ): 5552 DOI:10.1038/s41467-019-13410-zhttp://doi.org/10.1038/s41467-019-13410-z .

Arbe A, Rubio-Cervilla J, Alegría A, Moreno A J, Pomposo J A, Robles-Hernández B, Malo de Molina P, Fouquet P, Juranyi F, Colmenero J. Macromolecules , 2019 . 52 ( 18 ): 6935 - 6942 . DOI:10.1021/acs.macromol.9b01264http://doi.org/10.1021/acs.macromol.9b01264 .

Pomposo J A, Perez-Baena I, Lo Verso F, Moreno A J, Arbe A, Colmenero J. ACS Macro Lett , 2014 . 3 ( 8 ): 767 - 772 . DOI:10.1021/mz500354qhttp://doi.org/10.1021/mz500354q .

Antonietti M, Pakula T, Bremser W. Macromolecules , 1995 . 28 ( 12 ): 4227 - 4233 . DOI:10.1021/ma00116a025http://doi.org/10.1021/ma00116a025 .

van der Scheer P, van de Laar T, van der Gucht J, Vlassopoulos D, Sprakel J. ACS Nano , 2017 . 11 ( 7 ): 6755 - 6763 . DOI:10.1021/acsnano.7b01359http://doi.org/10.1021/acsnano.7b01359 .

Vlassopoulos D, Cloitre M. Curr Opin Colloid Interface Sci , 2014 . 19 ( 6 ): 561 - 574 . DOI:10.1016/j.cocis.2014.09.007http://doi.org/10.1016/j.cocis.2014.09.007 .

Vlassopoulos D, Cloitre M. Soft Matter , 2012 . 8 ( 15 ): 4010 - 4013 . DOI:10.1039/c2sm90031ahttp://doi.org/10.1039/c2sm90031a .

Zhang Z, Yunker P J, Habdas P, Yodh A G. Phys Rev Lett , 2011 . 107 ( 20 ): 208303 DOI:10.1103/PhysRevLett.107.208303http://doi.org/10.1103/PhysRevLett.107.208303 .

Chen K, Still T, Schoenholz S, Aptowicz K B, Schindler M, Maggs A C, Liu A J, Yodh A G. Phys Rev E , 2013 . 88 ( 2 ): 022315 DOI:10.1103/PhysRevE.88.022315http://doi.org/10.1103/PhysRevE.88.022315 .

Li L, Chen Q, Jin F, Wu C. Polymer , 2015 . 67 A1 - A13 . DOI:10.1016/j.polymer.2015.04.063http://doi.org/10.1016/j.polymer.2015.04.063 .

Jiang Z B, Peng M J, Li L L, Zhou D S, Wang R, Xue G. Chin Phys B , 2015 . 24 ( 7 ): 76801 - 076801 . DOI:10.1088/1674-1056/24/7/076801http://doi.org/10.1088/1674-1056/24/7/076801 .

Forrest J A, Dalnoki-Veress K. Adv Colloid Interface Sci , 2001 . 94 ( 1 ): 167 - 195 . DOI:10.1016/S0001-8686(01)00060-4http://doi.org/10.1016/S0001-8686(01)00060-4 .

Wang D, Hu R, Mabry J N, Miao B, Wu D T, Koynov K, Schwartz D K. J Am Chem Soc , 2015 . 137 ( 38 ): 12312 - 12320 . DOI:10.1021/jacs.5b07108http://doi.org/10.1021/jacs.5b07108 .

Niu Q, Wang D. Curr Opin Colloid Interface Sci , 2019 . 39 162 - 172 . DOI:10.1016/j.cocis.2019.01.015http://doi.org/10.1016/j.cocis.2019.01.015 .

Zhang W B, Yu X, Wang C L, Sun H J, Hsieh I F, Li Y, Dong X H, Yue K, van Horn R, Cheng S Z D. Macromolecules , 2014 . 47 ( 4 ): 1221 - 1239 . DOI:10.1021/ma401724phttp://doi.org/10.1021/ma401724p .

Wang X, Yang Y, Gao P, Li D, Yang F, Shen H, Guo H, Xu F, Wu D. Chem Commun , 2014 . 50 ( 46 ): 6126 - 6129 . DOI:10.1039/c4cc01859ahttp://doi.org/10.1039/c4cc01859a .

Huang M, Hsu C H, Wang J, Mei S, Dong X, Li Y, Li M, Liu H, Zhang W, Aida T, Zhang W B, Yue K, Cheng S Z D. Science , 2015 . 348 ( 6233 ): 424 - 428 . DOI:10.1126/science.aaa2421http://doi.org/10.1126/science.aaa2421 .

Feng X, Zhang R, Li Y, Hong Y l, Guo D, Lang K, Wu K Y, Huang M, Mao J, Wesdemiotis C, Nishiyama Y, Zhang W, Zhang W, Miyoshi T, Li T, Cheng S Z D. ACS Cent Sci , 2017 . 3 ( 8 ): 860 - 867 . DOI:10.1021/acscentsci.7b00188http://doi.org/10.1021/acscentsci.7b00188 .

Tang Wen(唐雯), Yue Kan(岳衎), Cheng Stephen Z D(程正迪). Acta Polymerica Sinica(高分子学报) , 2018 . ( 8 ): 959 - 972 . DOI:10.11777/j.issn1000-3304.2018.18102http://doi.org/10.11777/j.issn1000-3304.2018.18102 .

Feng X, Liu G, Guo D, Lang K, Zhang R, Huang J, Su Z, Li Y, Huang M, Li T, Cheng S Z D. ACS Macro Lett , 2019 . 8 ( 7 ): 875 - 881 . DOI:10.1021/acsmacrolett.9b00287http://doi.org/10.1021/acsmacrolett.9b00287 .

Liu G, Feng X, Lang K, Zhang R, Guo D, Yang S, Cheng S Z D. Macromolecules , 2017 . 50 ( 17 ): 6637 - 6646 . DOI:10.1021/acs.macromol.7b01058http://doi.org/10.1021/acs.macromol.7b01058 .

Liu Y, Liu G, Zhang W, Du C, Wesdemiotis C, Cheng S Z D. Macromolecules , 2019 . 52 ( 11 ): 4341 - 4348 . DOI:10.1021/acs.macromol.9b00549http://doi.org/10.1021/acs.macromol.9b00549 .

Wang X, Gao P, Yang Y, Guo H, Wu D. Nat Commun , 2018 . 9 ( 1 ): 2772 DOI:10.1038/s41467-018-05142-3http://doi.org/10.1038/s41467-018-05142-3 .

Ye Q, Zhou H, Xu J. Chem-Asian J , 2016 . 11 ( 9 ): 1322 - 1337 . DOI:10.1002/asia.201501445http://doi.org/10.1002/asia.201501445 .

Yu S J, Han Y K, Wang W. Polymer , 2019 . 162 73 - 79 . DOI:10.1016/j.polymer.2018.12.035http://doi.org/10.1016/j.polymer.2018.12.035 .

Alexandris S, Franczyk A, Papamokos G, Marciniec B, Matyjaszewski K, Koynov K, Mezger M, Floudas G. Macromolecules , 2015 . 48 ( 10 ): 3376 - 3385 . DOI:10.1021/acs.macromol.5b00663http://doi.org/10.1021/acs.macromol.5b00663 .

Zheng X H, Zhao J F, Zhao T P, Yang T, Ren X K, Liu C Y, Yang S, Chen E Q. Macromolecules , 2018 . 51 ( 12 ): 4484 - 4493 . DOI:10.1021/acs.macromol.8b00302http://doi.org/10.1021/acs.macromol.8b00302 .

Chai S C, Xu T Y, Cao X, Wang G, Chen Q, Li H L. Chinese J Polym Sci , 2019 . 37 ( 8 ): 797 - 805 . DOI:10.1007/s10118-019-2262-8http://doi.org/10.1007/s10118-019-2262-8 .

Qian Hujun(钱虎军), Lu Zhongyuan(吕中元). Acta Polymerica Sinica(高分子学报) , 2019 . 51 ( 1 ): 55 - 65 . DOI:10.11777/j.issn1000-3304.2018.18166http://doi.org/10.11777/j.issn1000-3304.2018.18166 .

Stillinger F H, Debenedetti P G. Annu Rev Condens Matter Phys , 2013 . 4 ( 1 ): 263 - 285 . DOI:10.1146/annurev-conmatphys-030212-184329http://doi.org/10.1146/annurev-conmatphys-030212-184329 .

Biroli G, Garrahan J P. J Chem Phys , 2013 . 138 ( 12 ): 12A301 DOI:10.1063/1.4795539http://doi.org/10.1063/1.4795539 .

Lubchenko V, Wolynes P G. Annu Rev Phys Chem , 2007 . 58 235 - 266 . DOI:10.1146/annurev.physchem.58.032806.104653http://doi.org/10.1146/annurev.physchem.58.032806.104653 .

Anderson P W. Science , 1995 . 267 ( 5204 ): 1615 - 1616 . DOI:10.1126/science.267.5204.1615-ehttp://doi.org/10.1126/science.267.5204.1615-e .

. Science , 2005 . 309 ( 5731 ): 78 - 102 . DOI:10.1126/science.309.5731.78bhttp://doi.org/10.1126/science.309.5731.78b .

David R R, Patrick C. J Stat Mech , 2005 . 2005 ( 5 ): P05013 DOI:10.1088/1742-5468/2005/05/P05013http://doi.org/10.1088/1742-5468/2005/05/P05013 .

Turnbull D, Cohen M H. J Chem Phys , 1961 . 34 ( 1 ): 120 - 125 . DOI:10.1063/1.1731549http://doi.org/10.1063/1.1731549 .

Cohen M H, Grest G S. Phys Rev B , 1979 . 20 ( 3 ): 1077 - 1098 . DOI:10.1103/PhysRevB.20.1077http://doi.org/10.1103/PhysRevB.20.1077 .

Xia X, Wolynes P G. Proc Natl Acad Sci USA , 2000 . 97 ( 7 ): 2990 - 2994 . DOI:10.1073/pnas.97.7.2990http://doi.org/10.1073/pnas.97.7.2990 .

Schweizer K S, Saltzman E J. J Chem Phys , 2003 . 119 ( 2 ): 1181 - 1196 . DOI:10.1063/1.1578632http://doi.org/10.1063/1.1578632 .

Schweizer K S. J Chem Phys , 2005 . 123 ( 24 ): 244501 DOI:10.1063/1.2137701http://doi.org/10.1063/1.2137701 .

Donati C, Douglas J F, Kob W, Plimpton S J, Poole P H, Glotzer S C. Phys Rev Lett , 1998 . 80 ( 11 ): 2338 - 2341 . DOI:10.1103/PhysRevLett.80.2338http://doi.org/10.1103/PhysRevLett.80.2338 .

Angelini M C, Biroli G. Proc Natl Acad Sci , 2017 . 114 ( 13 ): 3328 - 3333 . DOI:10.1073/pnas.1613126114http://doi.org/10.1073/pnas.1613126114 .

Royall C P, Williams S R. Phys Rep , 2015 . 560 1 - 75 . DOI:10.1016/j.physrep.2014.11.004http://doi.org/10.1016/j.physrep.2014.11.004 .

Wisitsorasak A, Wolynes P G. Proc Natl Acad Sci USA , 2012 . 109 ( 40 ): 16068 - 16072 . DOI:10.1073/pnas.1214130109http://doi.org/10.1073/pnas.1214130109 .

Leheny R L, Rogers M C, Chen K, Narayanan S, Harden J L. Curr Opin Colloid Interface Sci , 2015 . 20 ( 4 ): 261 - 271 . DOI:10.1016/j.cocis.2015.10.001http://doi.org/10.1016/j.cocis.2015.10.001 .

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