Preparation and Multifunctional Applications of Nitrogen-doped Porous Carbon Materials

Hui-min Gao; Qian Wang; Zuo-lin Cao; Shi-jie Ren

doi:10.11777/j.issn1000-3304.2020.20067

您当前的位置：

首页 >

文章列表页 >

Preparation and Multifunctional Applications of Nitrogen-doped Porous Carbon Materials

更新时间：2021-01-26

- Preparation and Multifunctional Applications of Nitrogen-doped Porous Carbon Materials
- Acta Polymerica Sinica Vol. 51, Issue 10, Pages: 1160-1168(2020)
- 作者机构：
  
  四川大学高分子科学与工程学院高分子材料工程国家重点实验室　成都 610065
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20067
  CLC：
- Published：1 September 2020，
  
  Published Online：8 June 2020，
  
  Received：16 March 2020，
  
  Revised：1 April 2020，
扫描看全文
Hui-min Gao, Qian Wang, Zuo-lin Cao, Shi-jie Ren. Preparation and Multifunctional Applications of Nitrogen-doped Porous Carbon Materials. [J]. Acta Polymerica Sinica 51(10):1160-1168(2020)
DOI：

Hui-min Gao, Qian Wang, Zuo-lin Cao, Shi-jie Ren. Preparation and Multifunctional Applications of Nitrogen-doped Porous Carbon Materials. [J]. Acta Polymerica Sinica 51(10):1160-1168(2020) DOI： 10.11777/j.issn1000-3304.2020.20067.

摘要

使用Suzuki偶联反应合成含氮共轭微孔聚合物作为碳化前驱体，制备了2种氮掺杂多孔碳材料(C-TNCMP1、C-TNCMP2)，研究了碳化过程和结构单元平面性的不同对多孔碳材料二氧化碳吸附和超级电容器性能的影响. 碳化得到的2种多孔碳材料具有相似的孔结构，两者都表现出优异的二氧化碳吸附性能，吸附量最高可达3.19 mmol/g. 能量储存方面，含有咔唑结构单元的C-TNCMP2由于具有更好的平面性表现出优异的超级电容器性能，其容量在0.1 A/g的电流密度下达219 F/g. 此研究可为设计具有良好二氧化碳吸附和能量存储性能的多孔碳材料提供一定的参考意义.

Abstract

Porous carbon materials (PCMs) have drawn wide attention in gas adsorption and energy storage due to their large specific surface areas

physical and chemical stability and structural diversity. Doping heteroatoms such as nitrogen species has been considered as a reasonable method to enhance the application performance of PCMs by improving the interactions between PCMs and adsorbates. However

heteroatom-doped PCMs prepared with traditional methods such as chemical activation have disadvantages of broad pore size distribution and difficulty in accurately locating heteroatoms on the skeleton of PCMs

thus limiting their applications in gas adsorption and energy storage. Conjugated microporous polymers (CMPs) with excellent structural controllability and permanent microporous properties are considered to be a new choice for the preparation of PCMs. In this work

two nitrogen-doped PCMs with different structural units were prepared by using CMPs as the precursors. First of all

two CMPs (TNCMP1

TNCMP2) were synthesized by Pd-catalyzed Suzuki coupling reaction. Then the CMPs were pyrolyzed at 700 °C to give two PCMs (C-TNCMP1

C-TNCMP2). The effects of carbonization and planarity adjustment on carbon dioxide (CO

) adsorption and supercapacitor performance of the PCMs were studied. Compared with their precursors

the obtained PCMs exhibit narrower pore size distribution and higher microporosity up to 93%. Thus

both of the PCMs show higher CO

adsorption ability than their precursors

among which the CO

adsorption capability of C-TNCMP1 is up to 3.19 mmol/g. Compared with C-TNCMP1

C-TNCMP2 with better structural planarity has larger graphite nitrogen content of 57.39 at% and higher conductivity of 3.89 × 10

−5

S/m

thus showing better supercapacitor performance. C-TNCMP2 exhibits a decent specific capacitance of 219 F/g at the current density of 0.1 A/g and a good rate capability at high current density. This work could provide a rational principle for the preparation of high performance porous carbon materials for the applications of gas adsorption and energy storage.

关键词

多孔碳材料氮掺杂二氧化碳吸附超级电容器

Keywords

Porous carbon materialsNitrogen dopingCarbon dioxide adsorptionSupercapacitor

references

Lee J, Kim J, Hyeon T. Adv Mater , 2006 . 18 2073 - 2094 . DOI:10.1002/adma.200501576http://doi.org/10.1002/adma.200501576 .

Vix-Guterl C, Frackowiak E, Jurewicz K, Friebe M, Parmentier J, Béguin F. Carbon , 2005 . 43 1293 - 1302 . DOI:10.1016/j.carbon.2004.12.028http://doi.org/10.1016/j.carbon.2004.12.028 .

Li M M, Xu F, Li H, Wang Y. Catal Sci Technol , 2016 . 6 3670 - 3693 . DOI:10.1039/C6CY00544Fhttp://doi.org/10.1039/C6CY00544F .

Su F B, Poh C K, Chen J S, Xu G W, Wang D, Li Q, Lin J Y, Lou X W. Energy Environ Sci , 2011 . 4 717 - 724 . DOI:10.1039/C0EE00277Ahttp://doi.org/10.1039/C0EE00277A .

Mikova N M, Chesnokov N V, Ivanov I P, Zhizhaev A M. Russ J Appl Chem , 2013 . 86 1526 - 1536 . DOI:10.1134/S1070427213100108http://doi.org/10.1134/S1070427213100108 .

Dmitruk A F, Lesishina Y O, Shendrik T G, Galushko L Y. Solid Fuel Chem , 2007 . 41 302 - 306 . DOI:10.3103/S0361521907050060http://doi.org/10.3103/S0361521907050060 .

Kuznetsov B N, Chesnokov N V, Tsyganova S I, Mikova N M, Ivanov I P, Ivanchenko N M. Solid Fuel Chem , 2016 . 50 23 - 30 . DOI:10.3103/S0361521916010067http://doi.org/10.3103/S0361521916010067 .

Frackowiak E. Phys Chem Chem Phys , 2007 . 9 1774 - 1785 . DOI:10.1039/b618139mhttp://doi.org/10.1039/b618139m .

Liu X, Dai L M. Nat Rev Mater , 2016 . 1 16064 .

Xiao Z C, Kong D B, Liang J X, Wang B, Iqbal R, Yang Q H, Zhi L J. Carbon , 2017 . 116 633 - 639 . DOI:10.1016/j.carbon.2017.02.041http://doi.org/10.1016/j.carbon.2017.02.041 .

Lee J M, Briggs M E, Hasell T, Cooper A I. Adv Mater , 2016 . 28 9804 - 9810 . DOI:10.1002/adma.201603051http://doi.org/10.1002/adma.201603051 .

Zhang C, Kong R, Wang X, Xu Y F, Wang F, Ren W F, Wang Y H, Su F B, Jiang J X. Carbon , 2017 . 114 608 - 618 . DOI:10.1016/j.carbon.2016.12.064http://doi.org/10.1016/j.carbon.2016.12.064 .

Liao H P, Wang H M, Ding H M, Meng X S, Xu H, Wang B S, Ai X P, Wang C. J Mater Chem A , 2016 . 4 7416 - 7421 . DOI:10.1039/C6TA00483Khttp://doi.org/10.1039/C6TA00483K .

Liang R R, Zhao X. Org Chem Front , 2018 . 5 3341 - 3356 . DOI:10.1039/C8QO00830Bhttp://doi.org/10.1039/C8QO00830B .

Hao L, Ning J, Luo B, Wang B, Zhang Y, Tang Z, Yang J H, Thomas A, Zhi L J. J Am Chem Soc , 2015 . 137 219 - 225 . DOI:10.1021/ja508693yhttp://doi.org/10.1021/ja508693y .

Su Y Z, Liu Y X, Liu P, Wu D Q, Zhuang X D, Zhang F, Feng X L. Angew Chem , 2015 . 54 1812 - 1816 . DOI:10.1002/anie.201410154http://doi.org/10.1002/anie.201410154 .

Kou Y, Xu Y H, Guo Z Q, Jiang D L. Angew Chem Int Ed , 2011 . 50 8753 - 8757 . DOI:10.1002/anie.201103493http://doi.org/10.1002/anie.201103493 .

Xu Y H, Jin S B, Xu H, Nagai A, Jiang D L. Chem Soc Rev , 2013 . 42 8012 - 8031 . DOI:10.1039/c3cs60160ahttp://doi.org/10.1039/c3cs60160a .

Xu Y J, Wu S P, Ren S J, Ji J Y, Yue Y, Shen J J. RSC Adv , 2017 . 7 32496 - 32501 . DOI:10.1039/C7RA05551Jhttp://doi.org/10.1039/C7RA05551J .

Wang S, Liu Y C, Yu Y, Du J F, Cui Y Z, Song X W, Liang Z Q. New J Chem , 2018 . 42 9482 - 9487 . DOI:10.1039/C8NJ01306Chttp://doi.org/10.1039/C8NJ01306C .

Lee J S M, Wu T H, Alston B M, Briggs M E, Hasell T, Hu C C, Cooper A I. J Mater Chem A , 2016 . 4 7665 - 7673 . DOI:10.1039/C6TA02319Chttp://doi.org/10.1039/C6TA02319C .

Li Y Q, Ni B, Li X D, Wang X H, Zhang D F, Zhao Q F, Li J L, Lu T, Mai W J, Pan L K. Nano-Micro Lett , 2019 . 11 1 - 13 . DOI:10.1007/s40820-018-0235-zhttp://doi.org/10.1007/s40820-018-0235-z .

Wang H G, Cheng Z H, Liao Y Z, Li J H, Weber J, Thomas A, Faul C F J. Chem Mater , 2017 . 29 4885 - 4893 . DOI:10.1021/acs.chemmater.7b00857http://doi.org/10.1021/acs.chemmater.7b00857 .

Yang M, Zhou Z. Adv Sci , 2017 . 4 1600408 DOI:10.1002/advs.201600408http://doi.org/10.1002/advs.201600408 .

Meier C B, Sprick R S, Monti A, Guiglion P, Lee J S M, Zwijnenburg M A, Cooper A I. Polymer , 2017 . 126 283 - 290 . DOI:10.1016/j.polymer.2017.04.017http://doi.org/10.1016/j.polymer.2017.04.017 .

Kim J Y, Yokoyama D, Adachi C. J Phys Chem C , 2012 . 116 8699 - 8706 . DOI:10.1021/jp301650xhttp://doi.org/10.1021/jp301650x .

Shi H P, Dai J X, Shi L W, Wang M H, Fang L, Shuang S M, Dong C. Chem Comm , 2012 . 48 8586 - 8588 . DOI:10.1039/c2cc34345bhttp://doi.org/10.1039/c2cc34345b .

You B, Li N, Zhu H Y, Zhu X L, Yang J. ChemSusChem , 2013 . 6 474 - 480 . DOI:10.1002/cssc.201200709http://doi.org/10.1002/cssc.201200709 .

Jia Z Y, Zuo Z C, Yi Y P, Liu H B, Li D, Li Y J, Li Y L. Nano Energy , 2017 . 33 343 - 349 . DOI:10.1016/j.nanoen.2017.01.049http://doi.org/10.1016/j.nanoen.2017.01.049 .

更多指标>

Views

133

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress on the Application of Electrically Conductive Hydrogel Electrodes in Flexible Energy Storage Systems

Preparation and Electrochemical Performance of NiCo₂O₄ Decorated N-Doped Cross-linked Carbon Nanofiber Electrodes

Studies on Preparation and Electrochemical Properties of Electrochromic Conductive Polyaniline Solid Supercapacitor

Preparation of Bamboo-based Porous Carbon Materials and Their Synergistic Flame-retardant Effect for Epoxy Resin

AQUEOUS DISPERSED POLYANILINE NANOWIRES FOR ELECTRODE MATERIAL OF SUPERCAPACITOR

Related Author

No data

Related Institution

School of Materials Science and Engineering, Southeast University

College of Textiles, Donghua University

College of Materials Science and Engineering, Donghua University

The Institute of Molecular Science, Key Laboratory of Shanxi Province for Energy Conversion and Storage Materials

College School of Materials Science and Engineering, Beijing Institute of Technology

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰