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深圳大学化学与环境工程学院 深圳 518000
Published:15 August 2020,
Published Online:27 July 2020,
Received:14 April 2020,
Revised:8 May 2020,
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Ben Wang, Fan Chen, Stephan Handschuh-Wang, Tian-sheng Gan, Xue-chang Zhou. Progresses in Anti-dehydration and Anti-freezing Hydrogels. [J]. Acta Polymerica Sinica 51(9):969-982(2020)
Ben Wang, Fan Chen, Stephan Handschuh-Wang, Tian-sheng Gan, Xue-chang Zhou. Progresses in Anti-dehydration and Anti-freezing Hydrogels. [J]. Acta Polymerica Sinica 51(9):969-982(2020) DOI: 10.11777/j.issn1000-3304.2020.20100.
水凝胶在柔性可穿戴式器件、电子皮肤和软体机器人等领域具有巨大的应用潜力. 然而,大部分水凝胶材料仍然面临容易失水变干,在严寒气候下容易冻结失效等挑战,严重限制了水凝胶材料的应用范围和发展前景. 近年来,为了解决水凝胶在干旱地域和严寒气候的失效问题,研究人员设计和制备了一系列抗失水抗结冰的水凝胶材料. 在本综述里,我们主要从制备策略和应用这两方面归纳并总结了抗失水和抗结冰水凝胶在近些年来的发展情况,着重讨论了表面修饰弹性体的水凝胶、盐凝胶、有机-水双溶剂凝胶以及纳米限域水凝胶各类水凝胶材料的制备原理和研究进展. 这些策略极大地改善了水凝胶材料的抗失水性和抗结冰性. 基于这些制备方法,介绍了抗失水抗结冰水凝胶在储能器件、柔性可穿戴设备、传感器和集水等领域的应用. 最后,我们对这个领域的发展现状进行总结,指出当前所面临的挑战,并讨论了未来可能的发展方向.
Extreme-temperature adaptable hydrogels have attracted peoples’ interests in recent years because they possess the capability to extend the range of the application of the current hydrogels in extremely arid and freezing environment
making the hydrogel-based wearable electronics
sensors and soft robots are able to function in such harsh environment. Various strategies have been developed to fabricate the anti-dehydration and anti-freezing hydrogels
including the surface modification by the elastomers
construction of poly(ionic liquid) gel
generation of organohydrogels
nanoconfinement and so forth. In this review
we encompassed and reviewed the fabrication strategies of the anti-dehydration and anti-freezing hydrogels. The anti-dehydration and anti-freezing hydrogels can be fabricated by the surface modification of the hydrogels with the elastomer
introduction of salt inside the hydrogels
gelation in the organic/water solvent
partial displacement of the water by the organic solvents and the structural confinement. Moreover
combination of these strategies may endow an enhanced performance in the anti-freezing and arid tolerance functions. Some additional properties can be also improved based on the employed synthesis strategies
such as self-healing property
mechanical toughness
and the electrical conductivity
making the as-prepared hydrogels multi-functional for various application. After discussion of the fabrication approaches
we further introduced the potential applications of these hydrogels
including the soft sensors of the strain
temperature and gas
wearable electronic devices such as flexible display and triboelectric nanogenerators
flexible energy storage devices containing the supercapacitors and batteries
and water harvesting materials powered by the solar energy. Finally
we summarized the current challenges and the future orientation of this field.
水凝胶抗结冰抗失水穿戴器件柔性传感器
HydrogelsAnti-freezingAnti-dehydrationWearable electronicsSoft sensors
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