Synthesis of Primary Amine Functionalized Styrene/Butadiene Copolymer and Contol of Its Composition Distribution

He-yu Shen; Xue-fei Leng; Li Han; Lin-can Yang; Chao Li; Song-bo Zhang; Lan Lei; Hong-wei Ma; Yang Li

doi:10.11777/j.issn1000-3304.2020.20107

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Synthesis of Primary Amine Functionalized Styrene/Butadiene Copolymer and Contol of Its Composition Distribution

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- Synthesis of Primary Amine Functionalized Styrene/Butadiene Copolymer and Contol of Its Composition Distribution
  增强出版
- Acta Polymerica Sinica Vol. 51, Issue 12, Pages: 1385-1393(2020)
- 作者机构：
  
  大连理工大学化工学院　大连 116024
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20107
  CLC：
- Published：21 October 2020，
  
  Published Online：8 July 2020，
  
  Received：21 April 2020，
  
  Revised：21 May 2020，
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He-yu Shen, Xue-fei Leng, Li Han, Lin-can Yang, Chao Li, Song-bo Zhang, Lan Lei, Hong-wei Ma, Yang Li. Synthesis of Primary Amine Functionalized Styrene/Butadiene Copolymer and Contol of Its Composition Distribution. [J]. Acta Polymerica Sinica 51(12):1385-1393(2020)
DOI：

He-yu Shen, Xue-fei Leng, Li Han, Lin-can Yang, Chao Li, Song-bo Zhang, Lan Lei, Hong-wei Ma, Yang Li. Synthesis of Primary Amine Functionalized Styrene/Butadiene Copolymer and Contol of Its Composition Distribution. [J]. Acta Polymerica Sinica 51(12):1385-1393(2020) DOI： 10.11777/j.issn1000-3304.2020.20107.

摘要

苯乙烯/丁二烯共聚物是一种有广泛应用基础的弹性体材料，对其结构的控制是调控材料性能的关键. 对于序列无法精准控制的共聚合体系，需要对其结构进行组成分布控制. 本文在伯胺DPE衍生物、苯乙烯和丁二烯的三元共聚合体系中，通过改变投料顺序，合成分子量相近、组成分布不同的伯胺功能化丁苯共聚物(

ran

-NFSBC和

grad

-NFSBC)，并对聚合动力学开展研究. 在

ran

-NFSBC中，苯乙烯对伯胺DPE衍生物的竞聚率为2.58，伯胺DPE衍生物的转化率为71.7%，且苯乙烯组成为无规分布趋势. 在

grad

-NFSBC中，伯胺DPE衍生物完全转化，并利用定时取样测定其组成分布，苯乙烯组成呈现梯度分布趋势. 最后，利用DSC测试初步揭示了组成分布对丁苯共聚物热性能的影响.

Abstract

The styrene/butadiene copolymer is widely used as elastomer in various applications of packing material

such as shoes

asphalt modifiers

etc

. The control of structure is the key to control the properties of material. Living anionic polymerization is still state of the art for the precise preparation of SBC. However

the sequence distribution of the copolymerization of styrene and butadiene cannot be as precise as that of styrene and DPE derivatives

because the product of reactivity ratios of styrene and butadiene is not approximately equal to 0. The composition distribution control was proposed to describe the behaviour of monomers in the statistical anionic copolymerisation. Herein

the primary amine DPE derivative was copolymerized with styrene and butadiene. In the terpolymerization

two primary amine functionalized SBC with similar molecular weight but different composition distributions were synthesized by varying feeding orders (

i.e. ran

-NFSBC and

grad

-NFSBC). The kinetics of copolymerizations were calculated. In

ran

-NFSBC

the reactivity ratio of St to DPE derivative was 2.58. The conversion of primary amine DPE derivative was 71.7%. The composition distribution was random distribution. In

grad

-NFSBC

the primary amine DPE derivative was totally consumed. The composition distribution was determined to be gradient distribution using the timing sample method. Finally

the relationship between composition distribution and thermal behavior of SBC was preliminarily studied by DSC.

关键词

活性阴离子聚合伯胺功能化丁苯共聚物组成分布

Keywords

Living anonic polymerizationAmine functionalziedStyrene/Butadiene copolymerComposition distribution

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