Lewis Pairs Catalytic Ring-opening Polymerization of Cyclic Ester and Ring-opening Alternating Copolymerization of Cyclic Anhydride/Epoxide

Bin Wang; He-yuan Ji; Yue-sheng Li

doi:10.11777/j.issn1000-3304.2020.20111

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Lewis Pairs Catalytic Ring-opening Polymerization of Cyclic Ester and Ring-opening Alternating Copolymerization of Cyclic Anhydride/Epoxide

更新时间：2021-01-26

- Lewis Pairs Catalytic Ring-opening Polymerization of Cyclic Ester and Ring-opening Alternating Copolymerization of Cyclic Anhydride/Epoxide
- Acta Polymerica Sinica Vol. 51, Issue 10, Pages: 1104-1120(2020)
- 作者机构：
  
  天津大学材料科学与工程学院　天津 300350
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20111
  CLC：
- Published：1 September 2020，
  
  Published Online：19 August 2020，
  
  Received：27 April 2020，
  
  Revised：18 May 2020，
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Bin Wang, He-yuan Ji, Yue-sheng Li. Lewis Pairs Catalytic Ring-opening Polymerization of Cyclic Ester and Ring-opening Alternating Copolymerization of Cyclic Anhydride/Epoxide. [J]. Acta Polymerica Sinica 51(10):1104-1120(2020)
DOI：

Bin Wang, He-yuan Ji, Yue-sheng Li. Lewis Pairs Catalytic Ring-opening Polymerization of Cyclic Ester and Ring-opening Alternating Copolymerization of Cyclic Anhydride/Epoxide. [J]. Acta Polymerica Sinica 51(10):1104-1120(2020) DOI： 10.11777/j.issn1000-3304.2020.20111.

摘要

近年来，路易斯酸碱对(Lewis pairs)催化聚合已成为高分子化学领域的研究热点之一，受到人们的广泛关注. 利用Lewis pairs催化环酯开环聚合以及环酐/环氧化物开环交替共聚，为合成新型聚酯材料以及聚酯的化学改性提供了简便快捷方法. Lewis 酸和Lewis碱的协同作用不仅提高了催化活性，同时亦可提高单体选择性和开环反应的立体选择性. 本专论总结了近几年课题组在利用Lewis pairs 催化合成环境友好高分子材料方面的研究进展，分析了Lewis pairs催化环酯开环聚合和环酐/环氧化合物开环交替共聚的聚合机理，论述了Lewis pairs结构—催化活性—单体选择性/开环立体化学之间的关系，阐述了混合单体“自切换”聚合制备序列可控脂肪族或半芳香族聚酯材料的新方法，深入讨论了Lewis pairs催化开环聚合的发展前景.

Abstract

In recent years

Lewis pairs catalytic polymerization (LPP) has become one of the hot topics and attracted much attention in the field of polymer chemistry. Some exciting results were reported in polymer synthesis by using Lewis pairs

especially in the addition polymerization of polar vinyl monomers. Great successes were also achieved in the ring-opening polymerization (ROP) of cyclic esters and ring-opening alternating copolymerization (ROAC) of cyclic anhydrides/epoxides catalyzed by Lewis pairs

which provides a relatively simple and efficient approach for synthesizing polyesters with diverse structure and chemical modification of polyester materials. The synergistic effect between Lewis acid and Lewis base significantly improved the catalytic activity as well as the monomer adaptability. This work reviews the recent progress on Lewis pairs catalytic ROP and ROAC in our research group. We discussed the polymerization mechanisms

polymerization behaviors

and the relationships between structures of catalyst and catalytic performance in the ROP and ROAC catalyzed by Lewis pairs. The methodology was also introduced for construction of sequence-controlled polyesters by chemo-selective polymerization of mixed monomer feedstocks. Finally

novel Lewis pairs catalytic systems and methodologies were prospected for the stereo-selective polymerization of racemic monomer and the copolymerization of cyclic anhydrides and epoxides with five-membered rings such as tetrahydrofuran and 2-methyltetrahydrofuran.

关键词

脂肪族聚酯路易斯酸碱对开环聚合开环交替共聚环境友好高分子

Keywords

Aliphatic polyestersLewis pairsRing-opening polymerizationRing-opening alternating copolymerizationEnvironment-friendly

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College of Chemistry and Materials Science, Shanghai Normal University

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

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