Design and Fabrication of Silk Fibroin-based Fibers and Functional Materials

Su-na Fan; Jie Chen; Zhang-hong Gu; Xiang Yao; Yao-peng Zhang

doi:10.11777/j.issn1000-3304.2020.20172

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Design and Fabrication of Silk Fibroin-based Fibers and Functional Materials

Feature Articles | 更新时间：2021-05-15

- Design and Fabrication of Silk Fibroin-based Fibers and Functional Materials
- Acta Polymerica Sinica Vol. 52, Issue 1, Pages: 29-46(2021)
- 作者机构：
  
  东华大学纤维材料改性国家重点实验室材料科学与工程学院　上海 201620
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20172
  CLC：
- Published：3 January 2021，
  
  Published Online：28 September 2020，
  
  Received：20 July 2020，
  
  Revised：19 August 2020，
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Su-na Fan, Jie Chen, Zhang-hong Gu, Xiang Yao, Yao-peng Zhang. Design and Fabrication of Silk Fibroin-based Fibers and Functional Materials. [J]. Acta Polymerica Sinica 52(1):29-46(2021)
DOI：

Su-na Fan, Jie Chen, Zhang-hong Gu, Xiang Yao, Yao-peng Zhang. Design and Fabrication of Silk Fibroin-based Fibers and Functional Materials. [J]. Acta Polymerica Sinica 52(1):29-46(2021) DOI： 10.11777/j.issn1000-3304.2020.20172.

摘要

随着环境污染、资源枯竭和医疗健康等问题的加剧，研发同时满足特定使用性能、安全性及可再生性的新型材料成为当前的发展趋势. 而丝素蛋白材料正是以天然蚕丝为基本原材料，经一定的加工和功能化而形成的具有特殊结构、独特性能和广泛应用的生物质材料，近年来在生物医药、生物电子、智能传感等领域展现出巨大的应用潜力. 本专论总结了丝素蛋白纤维及功能化材料的最新成果，结合本课题组相关工作，重点阐述了再生丝素蛋白纤维的仿生制备、生物医用支架的构筑与功能化、智能电子材料的设计以及天然多功能蚕丝及其构筑基元制备的研究进展，以期为高性能丝素蛋白材料的设计与构筑提供指导和借鉴.

Abstract

With the advent of environmental pollution

resource depletion

and medical and health problems

the fabrication of new materials that meet specific performance standards

green safety and reproducibility has become the focus of current research. Silk fibroin

originating from natural silkworm cocoons

is among the most important renewable material due to its excellent biocompatibility

biodegradability

optical properties

thermal stability

and mechanical strength. Furthermore

silk fibroin can be processed

functionalized and produced in a variety of forms

such as porous scaffolds

hydrogels

membranes

and fibers

which endows silk fibroin-based materials (SFBM) with special structure

unique performance and increases their potential fields of application into biomedicine

bioelectronics

and intelligent sensing. However

there are still many challenges to fabricate SFBM with excellent performance on a large scale. Firstly

conventional methods of processing destroy the multilevel structure of silk firoin

which restricts its biomimetic design and results in degradation of its performance. Secondly

it is difficult to precisely regulate the structure of silk fibroin and ensure consistent performance across different batches. Thirdly

the performance of SFBM is comparatively inferior to that of synthetic polymers and can easily deteriorate when exposed to light

heat

or radiation. Therefore

the development of simple

efficient

biomimetic processing strategies to regulate the structure

improve the performance

and clarify the structure-function relationships of SFBM is of considerable significance. The present review summaries the latest achievements and developments of silk fibroin-based fibers and functional materials

focusing on the progress of research into biomimetic preparation of regenerated silk fibroin

the construction and functionalization of biomedical scaffolds

the design of intelligent electronic materials

and the fabrication of natural multi-functional silk and its building blocks. The aim of this review is to provide guidance and a reference for the design and construction of high-performance SFBM.

关键词

丝素蛋白多级结构功能材料仿生构筑

Keywords

Silk fibroinHierarchical structureFunctional materialsBiomimetic fabrication

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