Supramolecular Topological Polymers: Synthesis, Self-assembly and Functionality

Hao Yao; Jing-xia Wang; Wei Tian

doi:10.11777/j.issn1000-3304.2021.21010

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Supramolecular Topological Polymers: Synthesis, Self-assembly and Functionality

Feature Articles | 更新时间：2021-11-03

- Supramolecular Topological Polymers: Synthesis, Self-assembly and Functionality
- Acta Polymerica Sinica Vol. 52, Issue 6, Pages: 578-601(2021)
- 作者机构：
  
  1.中南大学土木工程学院　长沙 410075
  2.西北工业大学化学与化工学院　西安 710072
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21010
  CLC：
- Published：3 June 2021，
  
  Published Online：10 May 2021，
  
  Received：13 January 2021，
  
  Revised：29 January 2021，
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Hao Yao, Jing-xia Wang, Wei Tian. Supramolecular Topological Polymers: Synthesis, Self-assembly and Functionality. [J]. Acta Polymerica Sinica 52(6):578-601(2021)
DOI：

Hao Yao, Jing-xia Wang, Wei Tian. Supramolecular Topological Polymers: Synthesis, Self-assembly and Functionality. [J]. Acta Polymerica Sinica 52(6):578-601(2021) DOI： 10.11777/j.issn1000-3304.2021.21010.

摘要

超分子拓扑高分子结合了非共价键的动态可逆特性和共价型拓扑高分子的结构特点，是一种具有广泛应用前景的高分子物种. 本文从超分子拓扑高分子的合成、组装及功能等三个方面综述了该领域的最新研究进展. 首先重点强调了利用直接或间接方法来构筑超支化、树枝状、星形、刷形、交联型和环形等超分子拓扑高分子的策略，其次从内部结构参数和外部环境响应两方面介绍了调控超分子自组装行为的主要方法，然后对其在生物医用材料、光电活性材料以及自修复材料等领域的潜在应用进行了较为全面的总结，最后指出了超分子拓扑高分子研究领域目前存在的关键问题和重要挑战.

Abstract

Supramolecular topological polymers not only possess the dynamic and tunable characteristics of non-covalent band

but also have the unique chemical and physical properties of covalent topological polymers. Furthermore

they display fascinating features such as reversibility

adaptiveness

self-healing and stimuli-responsiveness. Hence

supramolecular topological polymers provide new ideas for the creation of new polymer species and functional materials. In this paper

we reviewed the recent and important progress of supramolecular topological polymers from the synthesis

self-assembly to function and application. The synthetic methodologies of hyperbranched

dendritic

star

brush

crosslinking and cyclic supramolecular polymers including the direct and indirect strategies

were first emphasized. The controlled self-assembly behaviors of supramolecular topological polymers were then summarized from two aspects including the internal structure parameters (such as hydrophilic-hydrophobic ratio

topological structure

non-covalent bond types and force strengths) and external stimuli-responsiveness (such as thermal

light

redox

ion

and enzyme). As a result

the above supramolecular topological polymers can easily self-assemble to form hierarchical supramolecular structures with multiple stimuli-responsiveness at different scales and dimensions

such as spherical/cylindrical micelles

vesicles

and fibers/helical tubes. On the other hand

supramolecular topological polymers can achieve specific functional properties by the introduction of functional molecules

such as chromophore groups and biological targeted molecules. Next

the potential applications of supramolecular topological polymers in the fields of biomedical

photoelectric and self-healing materials were comprehensively discussed. Finally

the key scientific issues and possible challenges in the field of supramolecular topological polymers were briefly summarized.

关键词

超分子聚合物拓扑高分子超分子超支化聚合物可控自组装功能组装体

Keywords

Supramolecular polymerTopological polymerSupramolecular hyperbranched polymerControlled self-assemblyFunctional assemblies

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Department of Chemistry, The Hong Kong University of Science and Technology, Hongkong

State Key Laboratory of Luminescent Materials and Devices, South China University of Technology

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