Copolymerization of Aziridine Derivatives and Cyclic Anhydrides to Form Poly(ester amide)s

Wen-jing Liu; Tian-jun Yue; Wei-min Ren

doi:10.11777/j.issn1000-3304.2021.21011

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Copolymerization of Aziridine Derivatives and Cyclic Anhydrides to Form Poly(ester amide)s

Research Article | 更新时间：2024-02-20

- Copolymerization of Aziridine Derivatives and Cyclic Anhydrides to Form Poly(ester amide)s
- ACTA POLYMERICA SINICA Vol. 52, Issue 7, Pages: 717-722(2021)
- 作者机构：
  
  精细化工国家重点实验室大连理工大学化工学院大连 116024
- 作者简介：
  
  Wei-min Ren, E-mail: wmren@dlut.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21011
  CLC：
- Published：20 July 2021，
  
  Published Online：25 May 2021，
  
  Received：13 January 2021，
  
  Revised：02 February 2021，
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刘文静,乐天俊,任伟民.氮丙啶衍生物与环状酸酐共聚合成聚酯酰胺[J].高分子学报,2021,52(07):717-722.

Wen-jing Liu, Tian-jun Yue, Wei-min Ren. Copolymerization of Aziridine Derivatives and Cyclic Anhydrides to Form Poly(ester amide)s. [J]. ACTA POLYMERICA SINICA 52(7):717-722(2021)
刘文静,乐天俊,任伟民.氮丙啶衍生物与环状酸酐共聚合成聚酯酰胺[J].高分子学报,2021,52(07):717-722. DOI： 10.11777/j.issn1000-3304.2021.21011.

Wen-jing Liu, Tian-jun Yue, Wei-min Ren. Copolymerization of Aziridine Derivatives and Cyclic Anhydrides to Form Poly(ester amide)s. [J]. ACTA POLYMERICA SINICA 52(7):717-722(2021) DOI： 10.11777/j.issn1000-3304.2021.21011.

摘要

开发高效合成聚酯酰胺的方法一直是该领域研究的重点和难点. 本文发展了一种以有机碱为催化剂，以苄醇为引发剂，先通过易合成的氮丙啶衍生物与环状酸酐反应得到

-取代的共聚物，再通过氧化法由K

/Na

HPO

体系脱去氮原子上取代基从而合成聚酯酰胺的新方法. 通过该方法合成了9种不同结构的聚酯酰胺，为其在生物医学领域的应用提供了新的选择.

Abstract

Poly(ester amide)s (PEAs) are important synthetic polymeric materials. The excellent biodegradability and mechanical properties make the synthesis of such kinds polymers a research hotspot in the field of polymer chemistry. Herein

we report a novel strategy for accessing PEAs

via

the alternating copolymerization of easily synthesized aziridine derivatives and cyclic anhydrides with binary catalytic system consisting of benzyl alcohol (BnOH) and organic base (7-methyl-1

‍5

7-triazabicyclo[4.4.0]dec-5-ene (MTBD)) as catalyst

followed by the deprotection for the substitutes on the N atoms groups of the resultant copolymers using K

/Na

HPO

system. A detailed study on the debenzylation reaction was carried out. It was found that the K

/Na

HPO

system can effectively realize the debenzylation reaction involving the copolymer from 2

‍4-dimethoxy

-N

-benzylaziridine. The nine kinds of PEAs with different structures were synthesized from two types of monomers. The metal-free strategy

give these PEAs the potential to be utilized as hydrogels

tissue engineering

elastomers and smart materials as well as high-performance engineering plastics. Studies focused on further expanding the monomer scope and controlling the stereochemistry are currently in progress.

关键词

聚酯酰胺脱苄基化反应无金属催化交替共聚

Keywords

Poly(ester amide)sDebenzylationMetal-free catalysisAlternating copolymerization

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Related Institution

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University

Key Laboratory of Biobased Polymer Materials, Shandong Provincial Education Department, College of Polymer Science and Engineering, Qingdao University of Science and Technology

Collgene of Chemical Engineering, Qingdao University of Science and Technology

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