Aggregation-induced Emission: A Novel Approach to Studying Polymer Science

Shun-jie Liu; Ben Zhong Tang

doi:10.11777/j.issn1000-3304.2021.21013

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Aggregation-induced Emission: A Novel Approach to Studying Polymer Science

Feature Articles | 更新时间：2021-05-07

- Aggregation-induced Emission: A Novel Approach to Studying Polymer Science
- Acta Polymerica Sinica Vol. 52, Issue 5, Pages: 456-466(2021)
- 作者机构：
  
  1.中国科学院长春应用化学研究所中国科学院生态环境高分子材料重点实验室　长春 130022
  2.中国科学技术大学应用化学与工程学院　合肥 230026
  3.华南理工大学发光材料与器件国家重点实验室　广州 510640
  4.香港科技大学化学系国家人体组织功能重建工程技术研究中心-香港分中心　香港
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21013
  CLC：
- Published：3 May 2021，
  
  Published Online：12 March 2021，
  
  Received：17 January 2021，
  
  Revised：1 February 2021，
扫描看全文
Shun-jie Liu, Ben Zhong Tang. Aggregation-induced Emission: A Novel Approach to Studying Polymer Science. [J]. Acta Polymerica Sinica 52(5):456-466(2021)
DOI：

Shun-jie Liu, Ben Zhong Tang. Aggregation-induced Emission: A Novel Approach to Studying Polymer Science. [J]. Acta Polymerica Sinica 52(5):456-466(2021) DOI： 10.11777/j.issn1000-3304.2021.21013.

摘要

高分子科学在人类生活和现代社会中发挥了越来越重要的作用，深入理解高分子材料的构效关系及性能尤为重要. 现代仪器表征手段受制于非原位、样品制备过程冗杂等因素，很难直接“看到”测试过程. 荧光成像技术可以清楚地“看到”材料的结构及形态变化，受到广泛关注. 但是，传统荧光分子易发生聚集导致发光淬灭现象，限制其应用. 相反，聚集诱导发光(AIE)分子基于分子运动受限的发光机理，在聚集态具有强的发光信号，加之荧光量子效率高、对外界刺激灵敏等优点，现已成为化学和材料等领域的前沿. 本专论从AIE的工作原理出发，较系统地总结了基于AIE独特的分子可视化技术如何成为原位研究高分子科学的新方法：监测聚合物的溶液性质，如聚合过程、溶度参数及构效关系等；监测聚合物的聚集体性质，如链段固态分子运动、玻璃化转变、相分离及结晶度等. 最后对AIE技术在高分子科学领域的未来发展进行了展望.

Abstract

Polymer science has played an increasingly important role in human life and modern society. Therefore

it is imperative to understand its structure-function relationship and properties deeply. Modern instruments are limited by

ex situ

and miscellaneous sample preparation

and display “darkness” in the testing process. Fortunately

fluorescence imaging technology has received considerable attention owing to its capacibity to visualize the variation of structure and morphology in materials. Traditional dyes suffer from aggregation-caused quenching effect

significantly restricting its practical applications. In contrast

due to the advantages of high fluorescence quantum efficiency and extreme sensitivity to external stimuli

aggregation-induced emission (AIE) technology has become a forefront of chemistry and materials. This account systematically summarizes how the unique molecular visualization technology based on the working principles of AIE can become a new method for

in-situ

study of polymer science: monitoring polymer solution properties

such as polymerization process

solubility parameters and structure-activity relationship; visualizing the polymer aggregate properties

such as solid-state segmental movement

glass transition

phase separation and crystallinity

etc

. At last

the future development in this field has prospected.

关键词

聚集诱导发光高分子科学可视化荧光探针

Keywords

Aggregation-induced emissionPolymer scienceVisualizationFluorescence probe

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School of Materials Science and Engineering, University of Science and Technology Beijing

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