Preparation and Properties Modulation of Multi-component Polymer Complex Fibers

De-zhong Liu; Shu-guang Yang

doi:10.11777/j.issn1000-3304.2021.21060

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Preparation and Properties Modulation of Multi-component Polymer Complex Fibers

Research Article | 更新时间：2023-12-20

- Preparation and Properties Modulation of Multi-component Polymer Complex Fibers
- ACTA POLYMERICA SINICA Vol. 52, Issue 10, Pages: 1353-1360(2021)
- 作者机构：
  
  纤维材料改性国家重点实验室先进低维材料中心东华大学材料科学与工程学院上海 201620
- 作者简介：
  
  Shu-guang Yang, E-mail: shgyang@dhu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21060
  CLC：
- Published：20 October 2021，
  
  Published Online：24 June 2021，
  
  Received：01 March 2021，
  
  Revised：22 March 2021，
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刘德中,杨曙光.多组分高分子复合物纤维的制备与性能调控[J].高分子学报,2021,52(10):1353-1360.

Liu De-zhong,Yang Shu-guang.Preparation and Properties Modulation of Multi-component Polymer Complex Fibers[J].ACTA POLYMERICA SINICA,2021,52(10):1353-1360.
刘德中,杨曙光.多组分高分子复合物纤维的制备与性能调控[J].高分子学报,2021,52(10):1353-1360. DOI： 10.11777/j.issn1000-3304.2021.21060.

Liu De-zhong,Yang Shu-guang.Preparation and Properties Modulation of Multi-component Polymer Complex Fibers[J].ACTA POLYMERICA SINICA,2021,52(10):1353-1360. DOI： 10.11777/j.issn1000-3304.2021.21060.

摘要

多组分是实现纤维性能提升和调控的有效手段. 利用传统方法制备的多组分纤维，不同高分子之间很难达到分子层面相容. 高分子复合物是不同高分子高度相容的聚集组装体系. 本工作研究聚氧化乙烯(PEO)、聚乙烯醇(PVA)和聚丙烯酸(PAA) 3种组分制备复合物纤维. 利用红外光谱、X射线衍射、示差扫描量热、扫描电子显微镜和力学拉伸等方法分别表征氢键复合、纤维的聚集态结构和力学性质. 研究结果表明，PEO/PVA/PAA纤维不同组分高度相容，通过改变纤维中组分的含量，可以实现对多组分复合物纤维的性能调控. 纤维中柔性PEO组分含量增加，可以实现由塑性到弹性的转变，并且纤维在湿度场下表现出形状记忆与可修复行为.

Abstract

A multi-component hydrogen-bonded poly(ethylene oxide)/poly(vinyl alcohol)/poly(acrylic acid) (PEO/PVA/PAA) complex fiber is fabricated by “inhibition-formation method”. PAA powder

PVA powder and PEO powder are dissolved in deionized water

respectively. They are mixed with alkali to obtain a spinning solution by inhibiting the hydrogen complexation. The total concentration of spinning solution is fixed at 6.5 wt%. The molar ratio of repeating unit of PVA to PAA is fixed at 1:‍1

and PEO content is varied. After mixing

the spinning solution is centrifuged at 10000 r/min for 15 min to remove the bubbles. Then the solution is extruded through a spinneret into 2.0 mol/L HCl coagulation bath to form fibers by formation of hydrogen-bonded complex. The nascent fibers are dried in ambient environment for 24 h. The PEO/PVA/PAA fibers with different compositions are characterized by Fourier transform infrared spectroscopy (FTIR)

wide angle X-ray diffraction (XRD)

differential scanning calorimetry (DSC)

scanning electron microscopy (SEM) and mechanical strength tester. The FTIR results demonstrate the formation of hydrogen bonding interactions in fibers. The crystallines of PEO and PVA are inhibited by the hydrogen bonding complexation. Each kind of fibers only shows one

on the DSC curve

indicating the miscibility of different components. With the increase of PEO content

of the fibers decrease. The SEM images show that the cross sections of fractured fibers are rough.Tensile testing exhibites that the fiber becomes soft as PEO content increases. The fiber shows obvious yielding behavior when the PEO content is 20%. When the PEO content increases to 60%

the yielding disappears and the elongation increases dramatically to more than 1000% at room temperature with relative humidity of 65%. The elastic recovery test shows the elastic recovery is low (40%) as the PEO content is 20% and the value is enhanced to 90% when PEO content is 60%. The mechiacial properties of fibers show strong dependence on humidity. The fibers will present shape memory effect as humidity changes

and are endowed with memdable behavior in the high humidity environment.

关键词

氢键多组分复合物纤维形状记忆可修复

Keywords

Hydrogen bondMulti-componentComplex fiberShape memoryMendable

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