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Progress in the Polymerization of 1-Chloro-2-phenylacetylene Derivatives
- ACTA POLYMERICA SINICA Vol. 52, Issue 8, Pages: 911-919(2021)
- 作者机构：
1.浙江大学高分子科学与工程学系 教育部高分子合成与功能构造重点实验室 杭州 310027
2.香港中文大学（深圳）理工学院 分子聚集体科学实验室 深圳 518172
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2021.21066
CLC：Published：20 August 2021，
Published Online：12 July 2021，
Received：04 March 2021，
Revised：12 May 2021，
扫 描 看 全 文
杨富麟,张洁,孙景志等.聚(1-氯-2-苯基乙炔)衍生物研究进展[J].高分子学报,2021,52(08):911-919.
Yang Fu-lin,Zhang Jie,Sun Jing-zhi,et al.Progress in the Polymerization of 1-Chloro-2-phenylacetylene Derivatives[J].ACTA POLYMERICA SINICA,2021,52(08):911-919.
杨富麟,张洁,孙景志等.聚(1-氯-2-苯基乙炔)衍生物研究进展[J].高分子学报,2021,52(08):911-919. DOI： 10.11777/j.issn1000-3304.2021.21066.
Yang Fu-lin,Zhang Jie,Sun Jing-zhi,et al.Progress in the Polymerization of 1-Chloro-2-phenylacetylene Derivatives[J].ACTA POLYMERICA SINICA,2021,52(08):911-919. DOI： 10.11777/j.issn1000-3304.2021.21066.
摘要
双取代乙炔聚合物在小分子气体渗透与分离、发光弹性体、偏振荧光发射等领域有着突出的表现，成为聚乙炔研究领域的主流方向，聚(1-氯-2-苯基乙炔)衍生物是其中的一个特殊品种，对该类聚合物的聚合反应催化剂、聚合反应机理的深入研究对于发展功能性双取代乙炔聚合物具有重要意义. 本文简要回顾聚(1-氯-2-苯基乙炔)衍生物合成的发展历程，通过典型案例分析催化剂体系的演进过程中研究者们解决的一系列科学问题，总结催化剂体系、推拉电子取代基对聚合反应的影响，同时沿着超高透气性聚(双取代乙炔)研究及其在气体分离领域中的应用探索的发展脉络，指出该领域在催化剂研制、反应路线设计等方面的关键问题和可能解决方案，为制备具有先进功能的聚(双取代乙炔)提供了新思路.
Abstract
Poly(disubstituted acetylenes) (PDSAs) have shown excellent performance in gas permeability
polarized light emission
and fluorescent elastomers
and therefore have attracted great attention from researchers in relevant fields. Among a variety of PDSAs
the development history of poly(1-chloro-2-phenylacetylene)s is an ideal epitome of the progress of polyacetylenes. In this mini review
from traditional polymerization catalysts of late transition metal complexes to newly developed Pd-based catalyst systems
from nonpolar substituents to various polar functional groups on monomers
from inner apolar solvents to common polar solvents as polymerization media
different aspects of the polymerization of 1-chloro-1-alkynes
especially 1-chloro-2-phenylacetylenes are retrospected with a series of examples. Meanwhile
this review lays another clue
or the efforts on pursuing for PDSAs possessing ultrahigh permeability and good separation property of gases such as H
2
N
2
O
2
CO
2
and CH
4
an utmost important application of polymer materials. The greatly enhanced tolerance to polar groups of the Pd-based catalyst systems
in contrast with the traditional catalyst complexes
allows to introduce polar functionalities and active sites into the structure of PDSAs
thereby offering the chances to tackle the problem of the very low selectivity to different gas pairs. The realistic demands for gas collection and separation prompt the development of novel catalyst systems and synthetic strategies to PDSAs with intrinsic microporous structures. Moreover
due to the unique conjugated polyene main-chain and regioregular configuration
PDSAs are conceived as one of the promising candidates for the construction of PIMs. Finally
perspectives and suggestions of the functional design and synthetic efforts are presented.
关键词
聚(双取代乙炔)1-氯-2-苯基乙炔Pd-基复合催化剂本征微孔聚合物气体透过性
Keywords
Poly(disubstituted acetylene)s1-Chloro-2-phenylacetylenePd-based complex catalystPolymers with intrinsic microporousGas permeability
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