Recent Progress of Aggregation-induced Emission Molecular Oligomers

Yang Yang; Bin Chen; Ting-ting Zhai; Ling-yu Feng; Jian-lei Shen; Li-hua Wang

doi:10.11777/j.issn1000-3304.2021.21067

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Recent Progress of Aggregation-induced Emission Molecular Oligomers

Review | 更新时间：2023-05-22

- Recent Progress of Aggregation-induced Emission Molecular Oligomers
- ACTA POLYMERICA SINICA Vol. 52, Issue 9, Pages: 1100-1117(2021)
- 作者机构：
  
  1.中国科学院上海应用物理研究所上海 201800
  2.中国科学院大学北京 100049
  3.上海交通大学化学化工学院上海 200240
  4.中国科学院上海高等研究院上海 201210
- 作者简介：
  
  Jian-lei Shen, E-mail: shenjianlei@sjtu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21067
  CLC：
- Published：20 September 2021，
  
  Published Online：17 August 2021，
  
  Received：05 March 2021，
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杨阳,陈斌,翟婷婷等.聚集诱导发光分子寡聚体研究进展[J].高分子学报,2021,52(09):1100-1117.

Yang Yang,Chen Bin,Zhai Ting-ting,et al.Recent Progress of Aggregation-induced Emission Molecular Oligomers[J].ACTA POLYMERICA SINICA,2021,52(09):1100-1117.
杨阳,陈斌,翟婷婷等.聚集诱导发光分子寡聚体研究进展[J].高分子学报,2021,52(09):1100-1117. DOI： 10.11777/j.issn1000-3304.2021.21067.

Yang Yang,Chen Bin,Zhai Ting-ting,et al.Recent Progress of Aggregation-induced Emission Molecular Oligomers[J].ACTA POLYMERICA SINICA,2021,52(09):1100-1117. DOI： 10.11777/j.issn1000-3304.2021.21067.

摘要

分子聚集行为与细胞内多种代谢过程息息相关，如细胞衰老过程中色斑形成，A

肽在阿尔茨海默病病人的脑中聚集行为等. 定量化的研究分子聚集效应对于研究分子间的弱相互作用，分子聚集成核过程至关重要. 目前，针对聚集效应初期分子寡聚体形成过程的研究仍然处于初期阶段. 聚集诱导发光(aggregation-induced emission，AIE)为研究分子聚集行为提供了一种直观、便捷的策略. 但是，由于聚集过程的难以精细控制，定量化描述聚集分子数目与发光行为的关系仍然是巨大的挑战. 本综述对近期制备聚集诱导发光分子寡聚体的工作进行汇总. 根据形成分子寡聚体的作用力的不同，将目前构建荧光分子寡聚体方法分为以下4类：化学成键作用、主客体相互作用、DNA限域作用和微纳空间限域作用. 进一步地，还讨论了分子聚集体的发光行为. 通过本综述，有望推动AIE分子寡聚体发光性质的量化研究并为研究分子聚集成核过程带来一定的启示.

Abstract

关键词

聚集诱导发光自组装分子寡聚体共价有机框架DNA

Keywords

Aggregation-induced emissionSelf-assemblyMolecule aggregatesCovalent organic frameworksDNA

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