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Supramolecular Polymorphic Crystals with Luminescence and Elasticity Based on a Single Benzene Framework
- ACTA POLYMERICA SINICA Vol. 52, Issue 8, Pages: 1015-1023(2021)
- 作者机构：
超分子结构与材料国家重点实验室 吉林大学化学学院 长春 130012
- 作者简介：
Hong-yu Zhang, E-mail: hongyuzhang@jlu.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2021.21076
CLC：Published：20 August 2021，
Published Online：25 June 2021，
Received：11 March 2021，
Revised：06 May 2021，
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唐保磊,于旭,张红雨.基于单苯环分子的多晶相发光超分子弹性晶体[J].高分子学报,2021,52(08):1015-1023.
Tang Bao-lei,Yu Xu,Zhang Hong-yu.Supramolecular Polymorphic Crystals with Luminescence and Elasticity Based on a Single Benzene Framework[J].ACTA POLYMERICA SINICA,2021,52(08):1015-1023.
唐保磊,于旭,张红雨.基于单苯环分子的多晶相发光超分子弹性晶体[J].高分子学报,2021,52(08):1015-1023. DOI： 10.11777/j.issn1000-3304.2021.21076.
Tang Bao-lei,Yu Xu,Zhang Hong-yu.Supramolecular Polymorphic Crystals with Luminescence and Elasticity Based on a Single Benzene Framework[J].ACTA POLYMERICA SINICA,2021,52(08):1015-1023. DOI： 10.11777/j.issn1000-3304.2021.21076.
摘要
提出了一种利用超分子相互作用实现多晶型及晶体机械柔性制备的策略，通过对5-氨基间苯二甲酸二甲酯的结晶条件进行微调，得到了2种具有弹性的单苯环发光有机超分子晶体
1B
和
1G
. 引人注目的是2种晶型的晶体均能在直形及弹性弯曲状态下有效地传导光信号，证明了它们在柔性光学器件中的实用性. 本研究不仅对设计有机超分子晶体的多晶型和机械柔性具有重要的科学意义，而且对柔性晶体在光学领域的应用也具有重要的指导意义.
Abstract
In order to study the relationship between structure and property of organic supramolecular crystals
polymorph is an ideal research model because a single molecule can have various packing mode and supramolecular interaction motifs. Notwithstanding
the polymorph of organic supramolecular crystals with different mechanical properties still remain rare
which limit the exploration of mechanism of mechanical properties. In this report
we raised a strategy to obtain polymorphism with different mechanical flexibilities by controlling the concentration and solvent of dimethyl 5-aminoisophthalate
which could further modify the supramolecular weak interaction. The
1B
with blue emission and
1G
with green emission were obtained. For
1B
crystal
it does not have
π
-
π
packing; for
1G
it was H-aggregation that induced red-shift of fluorescence. Both of the crystals could be elastic bendable with low elastic modulus
that is
1.5 GPa for
1B
and 2.1 GPa for
1G
. It is interrelated to the weak supramolecular interaction between layer to layer:
1G
has C―H…
π
and H―C…O and
1B
has C―H…
π
. The above supramolecular interactions prevent the crystal from relative slippage. Based on those properties
those materials have potential application as optical waveguide and polarizer. For optical waveguide
both
1B
and
1G
could possess optical waveguiding property in straight and bend state
where the optical loss coefficient of
1B
was 0.374 dB/mm in straight state and 0.388 dB/mm in bend state and that of
1G
was 0.233 dB/mm in straight state and 0.242 dB/mm in bend state. Furthermore
the material could also be a polarizer. It is of great importance that crystals of two polymorphs can conduct optical signal efficiently in both straight and bent states which shows their application in flexible optical device. The research is not only of important scientific meaning for the design of polymorphism and mechanical flexibility in organic supramolecular crystals
but also of important instructive significance in optical application of flexible crystals.
关键词
超分子作用力多晶型机械柔性弹性模量光波导
Keywords
Supramolecular interactionPolymorphsMechanical flexibilityElastic modulusOptical waveguide
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