Intrinsic Self-healing Polysiloxane Materials: From Single Dynamic Crosslinked Network to Multiple Dynamic Crosslinked Networks

Juan Ye; Zhao-ji Zu; Zi-qian Lin; Hong-ping Xiang; Ming-qiu Zhang

doi:10.11777/j.issn1000-3304.2022.22362

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Intrinsic Self-healing Polysiloxane Materials: From Single Dynamic Crosslinked Network to Multiple Dynamic Crosslinked Networks

Review | 更新时间：2023-06-21

- Intrinsic Self-healing Polysiloxane Materials: From Single Dynamic Crosslinked Network to Multiple Dynamic Crosslinked Networks
- ACTA POLYMERICA SINICA Vol. 54, Issue 7, Pages: 1028-1054(2023)
- 作者机构：
  
  1.广东工业大学材料与能源学院广东省功能软凝聚态物质重点实验室广州 510006
  2.中山大学化学学院广东省高性能树脂基复合材料重点实验室聚合物复合材料及功能材料教育部重点实验室广州 510275
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22362
  CLC：
- Published：20 July 2023，
  
  Published Online：16 January 2023，
  
  Received：31 October 2022，
  
  Accepted：14 December 2022
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叶娟,祖兆基,林子谦等.本征型自修复聚硅氧烷材料：从单重动态交联网络到多重动态交联网络[J].高分子学报,2023,54(07):1028-1054.

Ye Juan,Zu Zhao-ji,Lin Zi-qian,et al.Intrinsic Self-healing Polysiloxane Materials: From Single Dynamic Crosslinked Network to Multiple Dynamic Crosslinked Networks[J].ACTA POLYMERICA SINICA,2023,54(07):1028-1054.
叶娟,祖兆基,林子谦等.本征型自修复聚硅氧烷材料：从单重动态交联网络到多重动态交联网络[J].高分子学报,2023,54(07):1028-1054. DOI： 10.11777/j.issn1000-3304.2022.22362.

Ye Juan,Zu Zhao-ji,Lin Zi-qian,et al.Intrinsic Self-healing Polysiloxane Materials: From Single Dynamic Crosslinked Network to Multiple Dynamic Crosslinked Networks[J].ACTA POLYMERICA SINICA,2023,54(07):1028-1054. DOI： 10.11777/j.issn1000-3304.2022.22362.

摘要

近年来，本征型自修复聚硅氧烷材料因兼具聚硅氧烷的优异性能和损伤自修复功能，在复合材料、智能涂层、柔性器件等领域显示出巨大的应用潜能. 本征型自修复聚硅氧烷材料主要通过在聚硅氧烷交联网络中引入各种动态非共价键和动态共价键，借助动态键的可逆断裂与重组来重排交联网络而实现损伤修复. 迄今为止，已有数十种修复机制或体系被相继报道，但仍存在自修复能力与力学性能间的矛盾. 为解决这一根本问题，聚硅氧烷材料的动态交联网络正从单重动态交联向多重动态交联转变，并结合结晶或取向等工艺以及通过与改性纳米粒子复合，这些方法对自修复材料的力学性能和自修复能力的协同调控都有着重要影响. 鉴于此，本文根据本征型自修复聚硅氧烷材料中动态键和动态交联网络的结构差异，对其动态交联网络的结构设计、自修复机制、性能调控以及应用研究等方面进行了综述分析，并展望了本征型自修复聚硅氧烷材料未来的发展方向.

Abstract

Recently

intrinsic self-healing polysiloxane materials owing to the excellent performances of silicone materials like resistance to high/low temperature

electrical insulation

hydrophobicity and biocompatibility

and novel self-healing ability to damages

have shown great potential in smart coatings

sensors

flexible devices and other fields. Intrinsic self-healing polysiloxane materials are mainly constructed by introducing dynamic non-covalent bonds (hydrogen bond

metal-ligand coordination interaction

ionic bond

etc

.) or/and dynamic covalent bonds (Diels-Alder bond

imine bond

boronic ester bond

siloxane bond

disulphide bond

etc

.) into their crosslinked networks. These dynamic bonds can be reversibly dissociated and recombined under moderate external stimuli

which thus enable the polymers to repair damage and restore functions. To date

dozens of self-healing mechanisms or systems for polysiloxane materials have been reported

but there is still a great challenge between excellent self-healing ability and high mechanical strengths. To address this fundamental issue

the crosslinked network of polysiloxane materials is converted from single dynamic bond to multiple dynamic bonds. The synergetic combination of dynamic covalent bond and non-covalent bond plays an important role in the efficient regulation of mechanical performances and self-healing capacities. Besides

the orientation

crystallization or phase separation of polymer chains is also considered as an effective way to improve the comprehensive properties of self-healing polysiloxane materials

because it can compensate for the reduction of mechanical properties to a certain extent. Moreover

the compositing polysiloxane materials with diverse nano-fillers grafted with dynamic bonds not only improve their comprehensive performances but also give new functions such as electric conduction

sensing

heat conduction. In view of this

this paper will review the network structure design

self-healing mechanism

property regulation and potential applications of intrinsic self-healing polysiloxane materials

based on their structural differences of dynamic bonds and dynamic crosslinked networks. Finally

an outlook on the future development of intrinsic self-healing polysiloxane materials is prospected.

关键词

聚硅氧烷材料自修复动态交联网络动态非共价键动态共价键

Keywords

Polysiloxane materialsSelf-healingDynamic crosslinked networkDynamic noncovalent bondsDynamic covalent bonds

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