Preparation and Characterization of Polystyrene-shelled Polysulfide Rubber Microcapsules

Xuan Wang; Xu-wen Yuan; Ge Wang; Huai-yu Yang

doi:10.11777/j.issn1000-3304.2022.22363

您当前的位置：

首页 >

文章列表页 >

Preparation and Characterization of Polystyrene-shelled Polysulfide Rubber Microcapsules

Research Article | 更新时间：2023-06-21

- Preparation and Characterization of Polystyrene-shelled Polysulfide Rubber Microcapsules
- ACTA POLYMERICA SINICA Vol. 54, Issue 7, Pages: 1103-1112(2023)
- 作者机构：
  
  1.中国科学院金属研究所沈阳 110016
  2.中国科学技术大学材料科学与工程学院合肥 230026
  3.湖北汽车工业学院材料科学与工程学院十堰 442002
- 作者简介：
  
  Xu-wen Yuan, E-mail: 20210015@huat.edu.cn
  Huai-yu Yang, E-mail: hyyang@imr.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22363
  CLC：
- Published：20 July 2023，
  
  Published Online：01 March 2023，
  
  Received：31 October 2022，
  
  Accepted：13 January 2023
扫描看全文
王璇,苑旭雯,王鸽等.以聚苯乙烯为壁材的聚硫橡胶微胶囊制备与表征[J].高分子学报,2023,54(07):1103-1112.

Wang Xuan,Yuan Xu-wen,Wang Ge,et al.Preparation and Characterization of Polystyrene-shelled Polysulfide Rubber Microcapsules[J].ACTA POLYMERICA SINICA,2023,54(07):1103-1112.
王璇,苑旭雯,王鸽等.以聚苯乙烯为壁材的聚硫橡胶微胶囊制备与表征[J].高分子学报,2023,54(07):1103-1112. DOI： 10.11777/j.issn1000-3304.2022.22363.

Wang Xuan,Yuan Xu-wen,Wang Ge,et al.Preparation and Characterization of Polystyrene-shelled Polysulfide Rubber Microcapsules[J].ACTA POLYMERICA SINICA,2023,54(07):1103-1112. DOI： 10.11777/j.issn1000-3304.2022.22363.

摘要

聚硫橡胶特殊的分子结构使其具有优异的密封、防腐、力学性能与粘接能力，但使用过程中暴露出的流动性强、活性期短、装配工艺繁琐等问题，极大地限制了其装配水平与工业应用. 为解决上述问题，本工作以液体聚硫橡胶为芯材、聚苯乙烯为壁材，通过溶剂蒸发法研制出尺寸均匀、表面光滑的微胶囊，使黏度较大的聚硫橡胶实现从液体到固体的转变. 此外，根据壁材在液体聚硫橡胶液滴表面吸附机理、演化过程及固化机制，考察乳化体系、反应温度、搅拌速率、芯壁质量比等条件对微胶囊形貌与分布的影响，实现微胶囊尺寸与成分的可调控性. 实验结果表明，以PVA和NaOA的混合溶液作为乳液体系可获得均匀程度更好的微胶囊，该乳化条件不仅能显著提升微胶囊中聚硫橡胶的含量(芯材含量可增至60 wt%)，而且可大幅降低微胶囊的尺寸，平均粒径可低至2.23 μm. 以上研究为新一代微胶囊基密封剂的工程化应用奠定良好基础，在密封剂装配自动化领域具有研发意义和应用价值.

Abstract

The special molecular structure of polysulfide rubber made it have excellent sealing

anticorrosion

mechanical properties and bonding ability. However

the problems exposed in the use process

such as strong fluidity

short active period and complicated assembly process

greatly limited the assembly level and industrial application of polysulfide rubber. In order to solve the problems above

in this work

liquid polysulfide rubber was used as the core material and polystyrene as the shell material. Microcapsules with uniform size and smooth surface were prepared by solvent evaporation method

so that the viscous polysulfide rubber can be transformed from liquid to solid. According to the adsorption mechanism

evolution process and curing mechanism of wall materials on the surface of polysulfide rubber droplets

the effects of emulsion system conditions

reaction temperature

stirring rate and core-wall mass ratio on the morphology and distribution of microcapsules were investigated to realize the adjustability of microcapsule size and composition. The experimental results showed that the microcapsules with better uniformity can be obtained by using the mixed solution of PVA and NaOA as the emulsion system. This emulsification condition can not only significantly increase the content of polysulfide rubber in the microcapsules (the core content can be increased to 60 wt%)

but also greatly reduce the size of the microcapsules

and the average particle size can be as low as 2.23 μm. The above research laid a good foundation for the engineering application of the new generation microcapsule-based sealant

which was of great significance and application value to the assembly automation of sealants.

关键词

关键工程材料聚硫橡胶聚苯乙烯微胶囊溶剂蒸发法

Keywords

Key engineering materialsLiquid polysulfide rubberPolystyreneMicrocapsulesSolvent evaporation method

references

杜善义. 复合材料创新驱动产业发展. 科技导报, 2016, 34(8), 1.

Li X.; Nie W.; Xu Y.; Zhou Y.; Chen P.; Zhang C. Functionalized GO/polysulfide rubber composites with excellent comprehensive properties based interfacial optimum design. Compos. Part B, 2020, 198, 108234. doi:10.1016/j.compositesb.2020.108234http://dx.doi.org/10.1016/j.compositesb.2020.108234

Tao W. J.; Zeng S. H.; Xu Y.; Nie W. Y.; Zhou Y. F.; Qin P. B.; Wu S. H.; Chen P. P. 3D Graphene-sponge skeleton reinforced polysulfide rubber nanocomposites with improved electrical and thermal conductivity. Compos. Part A, 2021, 143, 106293. doi:10.1016/j.compositesa.2021.106293http://dx.doi.org/10.1016/j.compositesa.2021.106293

刘璇, 杨睿. 橡胶密封材料老化研究进展. 机械工程材料, 2020, 44(9), 1-10. doi:10.11973/jxgccl202009001http://dx.doi.org/10.11973/jxgccl202009001

Donskoi A. A.; Baritko N. V.; Zaitseva E. I.; Eliseev O. A. New fuel-resistant sealants. Polym. Sci. Ser. D, 2010, 3, 54-57. doi:10.1134/s1995421210010090http://dx.doi.org/10.1134/s1995421210010090

宋英红, 吴松华, 章谏正. 耐高温液体改性聚硫橡胶的制备及性能. 中国胶粘剂, 2019, 28, 40-43.

Song B.; Li J. X.; Wu F.; Patel S.; Hah J.; Wang X.; Moon K.; Wong C. P. Processing and characterization of silver-filled conductive polysulfide sealants for aerospace applications. Soft Matter, 2018, 14, 9036-9043. doi:10.1039/c8sm02004chttp://dx.doi.org/10.1039/c8sm02004c

Minkin V. S.; Khakimullin Y. N.; Deberdeev T. R.; Berlin A. A. Influence of the nature of a curing agent on the peculiarities of formation of vulcanization networks in polysulfide sealants. Polym. Sci. Ser. D, 2009, 2, 195-198. doi:10.1134/s1995421209040017http://dx.doi.org/10.1134/s1995421209040017

孙超, 章谏正, 刘若愚, 吴松华. 聚硫密封剂用二氧化锰的研究. 粘接, 2018, 39(9), 42-44. doi:10.3969/j.issn.1001-5922.2018.09.007http://dx.doi.org/10.3969/j.issn.1001-5922.2018.09.007

全燕南, 章谏正, 鲍传磊, 吴松华. 二氧化锰结构对液体聚硫橡胶硫化特性及性能的影响研究. 中国胶粘剂, 2021, 30(8), 17-21.

刘丽萍, 冯志力, 刘嘉. 航空橡胶密封材料发展及应用. 军民两用技术与产品, 2013, 6, 13-16. doi:10.3969/j.issn.1009-8119.2013.06.003http://dx.doi.org/10.3969/j.issn.1009-8119.2013.06.003

Matsui T.; Nakajima M.; Nonaka T.; Dokoshi N. New liquid polysulfide polymer terminated with silyl group. J. Appl. Polym. Sci., 2004, 93, 2642-2649. doi:10.1002/app.20848http://dx.doi.org/10.1002/app.20848

Wang X.; Mu X. L.; Wang H. W.; Liao S. Z.; Yang H. Y. Preparation and mechanical properties of poly-(urea-formaldehyde) microcapsules containing liquid polysulfide. J. Adhesion, 2021, 97(11), 985-1003. doi:10.1080/00218464.2020.1723553http://dx.doi.org/10.1080/00218464.2020.1723553

Lee J.; Park S. J.; Park, C-S.; Kwon O. S.; Chung S. Y.; Shim J.; Lee C. S.; Bae J. Effect of a surfactant in microcapsule synthesis on self-healing behavior of capsule embedded polymeric films. Polymers, 2018, 10(6), 675. doi:10.3390/polym10060675http://dx.doi.org/10.3390/polym10060675

Zotiadis C.; Patrikalos I.; Loukaidou V.; Korres D. M.; Karantonis A.; Vouyiouka S. Self-healing coatings based on poly(urea-formaldehyde) microcapsules: in situ polymerization, capsule properties and application. Prog. Org. Coat., 2021, 161, 106475. doi:10.1016/j.porgcoat.2021.106475http://dx.doi.org/10.1016/j.porgcoat.2021.106475

Gite V. V.; Tatiya P. D.; Marathe R. J.; Mahulikar P. P.; Hundiwale D. G. Microencapsulation of quinoline as a corrosion inhibitor in polyurea microcapsules for application in anticorrosive PU coatings. Prog. Org. Coat., 2015, 83, 11-18. doi:10.1016/j.porgcoat.2015.01.021http://dx.doi.org/10.1016/j.porgcoat.2015.01.021

Xing S. L.; Yang J. S.; Huang Y. L.; Zheng Q.; Zeng J. C. Preparation and characterization of a novel microcapsule-type latent curing agent for epoxy resin. Mater. Design, 2015, 85, 661-670. doi:10.1016/j.matdes.2015.07.098http://dx.doi.org/10.1016/j.matdes.2015.07.098

Schwantes T. A. In situ microencapsulated adhesive. US patent, C08F265/04, 09942648. 2001-08-30.

焦鑫, 赵迪, 张姚, 吴倩, 石小迪, 鲁希华, 邱高. 聚二甲基丙烯酸乙二醇酯壁材微胶囊的制备及其表征. 高分子学报, 2016, (3), 345-351. doi:10.11777/j.issn1000-3304.2016.15215http://dx.doi.org/10.11777/j.issn1000-3304.2016.15215

陈耀, 胡孝勇, 张银钟. 可预涂微胶囊厌氧胶的研究进展. 中国胶粘剂, 2010, 19(6), 54-57. doi:10.3969/j.issn.1004-2849.2010.06.014http://dx.doi.org/10.3969/j.issn.1004-2849.2010.06.014

杨颖泰, 刘伟塘. 可预涂微胶囊型厌氧胶的性能. 化学与粘合, 2001, 3, 117-119. doi:10.3969/j.issn.1001-0017.2001.03.009http://dx.doi.org/10.3969/j.issn.1001-0017.2001.03.009

Ebrahiminiya A.; Khorram M.; Hassanajili S.; Javidi M. Modeling and optimization of the parameters affecting the in situ microencapsulation process for producing epoxy-based self-healing anti-corrosion coatings. Particuology, 2018, 36, 59-69. doi:10.1016/j.partic.2017.01.010http://dx.doi.org/10.1016/j.partic.2017.01.010

Fang Z.; Cao X. R.; Yu Y. L.; Li M. Fabrication and characterization of microcapsule encapsulating EOR surfactants by microfluidic technique. Colloids Surf. A, 2019, 570, 282-292. doi:10.1016/j.colsurfa.2019.02.045http://dx.doi.org/10.1016/j.colsurfa.2019.02.045

Kröber H.; Teipel U. Microencapsulation of particles using supercritical carbon dioxide. Chem. Eng. Process., 2005, 44, 215-219. doi:10.1016/j.cep.2004.02.014http://dx.doi.org/10.1016/j.cep.2004.02.014

Naveen V.; Deshpande A. P.; Raja S. Self-healing microcapsules encapsulated with carbon nanotubes for improved thermal and electrical properties. RSC Adv., 2020, 10, 33178-33188. doi:10.1039/d0ra06631ahttp://dx.doi.org/10.1039/d0ra06631a

Behzadnasab M.; Mirabedini S. M.; Esfandeh M.; Farnood R. R. Evaluation of corrosion performance of a self-healing epoxy-based coating containing linseed oil-filled microcapsules via electrochemical impedance spectroscopy. Prog. Org. Coat., 2017, 105, 212-224. doi:10.1016/j.porgcoat.2017.01.006http://dx.doi.org/10.1016/j.porgcoat.2017.01.006

Malofsky M. B. Anaerobic adhesive composition having improved strength at elevated temperature consisting of unsaturated diacrylate monomer and maleimide additive. US patent, C08F20/10, 39988299. 1976-10-26.

Rich D. R. Accelerator for curable compositions. US patent, C08F265/04, 05580267. 1981-09-01.

Asako T.; Chiba T.; Takahashi N.; Kitada T. Anaerobic adhesive and sealing agent composition for precoated bolt containing microencapsulated catalyst. JP patent, C09J11/06, JP1983171220. 1983-09-19.

杨颖泰, 匡志祥, 杨锦新. GY-540可预涂微胶囊厌氧胶的技术性能. 粘接, 1991, 5, 22-24.

王璇, 金涛, 王浩伟, 廖圣智, 杨怀玉. 脲醛树脂包覆聚硫密封剂微胶囊的制备和性能. 材料研究学报, 2018, 32(10), 730-736. doi:10.11901/1005.3093.2017.579http://dx.doi.org/10.11901/1005.3093.2017.579

朱雯, 黄芳婷, 董观秀, 张明. 无皂乳液聚合法制备单分散聚苯乙烯微球. 功能材料, 2012, 43(6), 775-778. doi:10.3969/j.issn.1001-9731.2012.06.026http://dx.doi.org/10.3969/j.issn.1001-9731.2012.06.026

华琼瑶, 于贵营, 洪魏悠然, 李春海, 郭少云. 基于液态金属/聚硫橡胶构筑兼具导热与自修复功能可拉伸热界面材料. 高分子材料科学与工程, 2021, 37(7), 153-161. doi:10.16865/j.cnki.1000-7555.2021.0198http://dx.doi.org/10.16865/j.cnki.1000-7555.2021.0198

Freitas S.; Merkle H. P.; Gander B. Microencapsulation by solvent extraction/evaporation: reviewing the state of the art of microsphere preparation process technology. J. Control. Release, 2005, 102, 313-332. doi:10.1016/j.jconrel.2004.10.015http://dx.doi.org/10.1016/j.jconrel.2004.10.015

GB/T 601-2016. 化学试剂标准滴定溶液的制备[S]. 北京: 中国国家标准化管理委员会, 2016. doi:10.12173/j.issn.1004-5511.202111004http://dx.doi.org/10.12173/j.issn.1004-5511.202111004

赵海川. 聚硫橡胶的结构与性能及其改性苯并噁嗪树脂的研究. 北京化工大学博士学位论文, 2008.

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Regulation of Polystyrene Blocks on Stereocomplex Crystallization Behavior of Poly(L-lactic acid)/Polystyrene-b-Poly(D-lactic acid) Blends

Photo-and Chemo-Degradable Polystyrene Containing o-Nitrobenzyl Ester and Trithiocarbonate Moieties

Preparation of Polybenzoxazine-ammonium Polyphosphate Microcapsules and Their Effects on the Flame Properties of Epoxy Resin

Diffusion and Polymerization Behavior of Styrene in High Density Polyethylene Pellets

Related Author

No data

Related Institution

State Key Laboratory of Organic-Inorganic Composite Materials, Beijing Laboratory of Biomedical Materials, College of Life Science and Technology, Beijing University of Chemical Technology

Department of Chemistry, University of Tennessee

Key Laboratory of Soft Matter Chemistry, Chinese Academy of Sciences; Department of Polymer Science and Engineering, University of Science and Technology of China

Department of Material Science and Engineering, Southwest Petroleum University

Key Laboratory of Advanced Materials, Ministry of Education, Department of Chemical Engineering, Tsinghua University

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰