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The Luminescence of Controllable Lanthanide-based Coordination Polymers and the Properties as Thermometer
增强出版- ACTA POLYMERICA SINICA Vol. 54, Issue 7, Pages: 1095-1102(2023)
- 作者机构：
山西师范大学化学与材料科学学院 磁性分子与磁信息材料教育部重点实验室 太原 030031
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2022.22375
CLC：Published：20 July 2023，
Published Online：12 January 2023，
Received：07 November 2022，
Accepted：01 December 2022
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王金增,梁瑞梅,裴雅儒等.可调控镧系配位聚合物荧光及温度传感性能研究[J].高分子学报,2023,54(07):1095-1102.
Wang Jin-zeng,Liang Rui-mei,Pei Ya-ru,et al.The Luminescence of Controllable Lanthanide-based Coordination Polymers and the Properties as Thermometer[J].ACTA POLYMERICA SINICA,2023,54(07):1095-1102.
王金增,梁瑞梅,裴雅儒等.可调控镧系配位聚合物荧光及温度传感性能研究[J].高分子学报,2023,54(07):1095-1102. DOI： 10.11777/j.issn1000-3304.2022.22375.
Wang Jin-zeng,Liang Rui-mei,Pei Ya-ru,et al.The Luminescence of Controllable Lanthanide-based Coordination Polymers and the Properties as Thermometer[J].ACTA POLYMERICA SINICA,2023,54(07):1095-1102. DOI： 10.11777/j.issn1000-3304.2022.22375.
摘要
通过2-羟基对苯二甲酸(H
2
hbdc)配体合成了2种不同结构的镧系配位聚合物(Ln
2
(hbdc)
3
(H
2
O)
8
·6H
2
O)
∞
(Ln-1)和(Ln
2
(hbdc)
3
(H
2
O)
8
·2H
2
O)
∞
(Ln-2)，合成混掺杂TbEu-1，TbEu-2和GdTbEu-2 (90% Gd
3+
). 对其进行了荧光强度分析及变温荧光光谱的测定，荧光强度排序为GdTbEu-2
>
TbEu-2
>
TbEu-1，经过Gd
3+
稀释后的金属间能量转移效率为57%，明显低于未稀释的TbEu-2 67%. 廉价Gd
3+
的引入及结构变换，使GdTbEu-2在100~250 K之间实现温度传感，同未调控的TbEu-1相比，温控区间扩大了1倍，绝对灵敏度(
S
ab
)和相对灵敏度(
S
re
)分别提升了22倍和3倍，这主要是由于Gd
3+
稀释后金属间距大于1 nm，弱化了金属间能量传递作用及Ln-2较少的游离水分子热运动. 进一步合成了一系列Sm
2
x
Eu
2-2
x
-2 (0.1≤
x
≤0.9)，呈现出可见和近红外发光，尤其是Sm
3+
在近红外区域呈现优异的光谱渐变. 这项工作为调控掺杂的荧光温度传感器及近红外温度传感器提供了一种思路和基础.
Abstract
Two different structures lanthanide-based coordination polymers (Ln
2
(hbdc)
3
(H
2
O)
8
·6H
2
O)
∞
(Ln-1) and (Ln
2
(hbdc)
3
(H
2
O)
8
·2H
2
O)
∞
(Ln-2) have been synthesized by changing the adding order of reactants
and TbEu-1
TbEu-2 and GdTbEu-2 (90% Gd
3+
) were further synthesized. The luminance was analyzed and the temperature-dependent luminescence spectrum was measured. All the luminescent spectra were recorded at solid state. The luminance was ranked as GdTbEu-2
>
TbEu-2
>
TbEu-1. For TbEu-2
the value of intermetallic energy transfer efficiency is 67%
after the dilution of 90% Gd
3+
this value significantly decreased to 57%. The introduction of cheap Gd
3+
and the transformation of the structure enable GdTbEu-2 to achieve temperature sensing between 100 K and 250 K. Compared with unregulated TbEu-1
the range of temperature sensing was doubled
the absolute sensitivity (
S
ab
) and relative sensitivity (
S
re
) increased by 22 and 3 times
respectively. This phenomenon could be caused by the fact that
the intermetallic distance is larger than 1 nm after Gd
3+
dilution
which weakens the intermetallic energy transfer effect
and the less free water molecule thermal motion of structure 2. A series of Sm
2
x
Eu
2-2
x
-2 (0.1≤
x
≤0.9) were further synthesized
showing both visible and near-infrared luminescence
especially Sm
3+
displaying excellent spectral gradation in the near-infrared region. This work provides an idea and basis for regulating doping luminescence thermometer and near-infrared temperature sensors.
关键词
镧系配位聚合物荧光温度传感器近红外发光
Keywords
Lanthanide-based coordination polymersLuminescenceThermometerNear infra-red emission
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