Frost-resistant and Antifogging Polymeric Composite Films Capable of Healing Fractured Nanofibers

Si-heng Li; Yi-xuan Li; Yu-ting Wang; Jun-qi Sun

doi:10.11777/j.issn1000-3304.2022.22424

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Frost-resistant and Antifogging Polymeric Composite Films Capable of Healing Fractured Nanofibers

Research Article | 更新时间：2024-01-18

- Frost-resistant and Antifogging Polymeric Composite Films Capable of Healing Fractured Nanofibers
  增强出版
- ACTA POLYMERICA SINICA Vol. 54, Issue 5, Pages: 697-707(2023)
- 作者机构：
  
  超分子结构与材料国家重点实验室吉林大学化学学院长春 130012
- 作者简介：
  
  Jun-qi Sun, E-mail: sun_junqi@jlu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22424
  CLC：
- Published：20 May 2023，
  
  Published Online：13 February 2023，
  
  Received：06 December 2022，
  
  Accepted：05 January 2023
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李思衡,李懿轩,王钰婷等.可修复纤维损伤的防霜和防雾聚合物复合膜[J].高分子学报,2023,54(05):697-707.

Li Si-heng,Li Yi-xuan,Wang Yu-ting,et al.Frost-resistant and Antifogging Polymeric Composite Films Capable of Healing Fractured Nanofibers[J].ACTA POLYMERICA SINICA,2023,54(05):697-707.
李思衡,李懿轩,王钰婷等.可修复纤维损伤的防霜和防雾聚合物复合膜[J].高分子学报,2023,54(05):697-707. DOI： 10.11777/j.issn1000-3304.2022.22424.

Li Si-heng,Li Yi-xuan,Wang Yu-ting,et al.Frost-resistant and Antifogging Polymeric Composite Films Capable of Healing Fractured Nanofibers[J].ACTA POLYMERICA SINICA,2023,54(05):697-707. DOI： 10.11777/j.issn1000-3304.2022.22424.

摘要

聚合物材料内部具有的微/纳米尺度的结构赋予了它们独特的功能. 然而，聚合物材料在使用时不可避免地会遭受机械损伤，这会使得聚合物材料的微/纳米结构受到破坏，导致聚合物材料自身功能的丧失. 为了解决上述问题，我们利用聚丙烯酸(PAA)与聚丙烯酰胺(PAAm)的嵌段共聚物(PAA-

-PAAm)和聚二烯丙基二甲基氯化铵(PDDA)形成的复合物溶液，通过提拉成膜，然后在25 ℃、相对湿度为~100%的环境中退火处理，制备了可修复纳米纤维损伤的防霜和防雾聚合物复合膜(PAA-

-PAAm/PDDA). 亲水的PAA-

-PAAm/PDDA膜的纳米纤维结构可以增加水滴和膜表面的接触面积并促进膜对水分子的快速吸收，从而赋予了该膜优异的防雾防霜性能. 得益于聚合物链间静电与氢键作用的动态性，PAA-

-PAAm/PDDA膜具有优异的自修复性能，不仅能修复宽度为几十微米的划痕，还能使断裂的纤维重新连接并恢复其原有的纳米纤维结构.

Abstract

Micro- and/or nanoscaled structures have endowed artificial polymeric materials with various unique functions. However

these materials are vulnerable to mechanical damage

which can destroy their inherent micro- and/or nanoscaled structures and result in the loss of their original functions. Therefore

to extend the service life of artificial polymeric materials whose functions depend on micro/nanostructures

it is highly important to fabricate polymeric materials that can heal damaged micro/nanoscaled structures. In this work

we report the fabrication of self-healing antifogging and frost-resisting films capable of healing the fractured nanofibrils. The films are fabricated by dip-coating of clean substrate from aqueous solution of poly(acrylic acid)-block-poly(acrylamide) (PAA-

-PAAm) and poly(diallyldimethylammonium chloride) (PDDA) complexes

followed by annealing under a humid environment of ~25 ℃ and relative humidity of ~100% (denoted as PAA-

-PAAm/PDDA). The complexation of PAA-

-PAAm and PDDA in aqueous solutions can assemble into nanorods

which are comprised of electrostatically cross-linked PAA blocks and PDDA chains as the hydrophobic cores and hydrogen-bonded PAAm chains as the hydrophilic coronas. These nanorods in the complex solutions can fuse into oriented nanofibers in the dip-coated PAA-

-PAAm/PDDA films during the dip-coating and the annealing processes. Nanofibrillar structures of the hydrophilic PAA-

-PAAm/PDDA film can increase the contact area between water droplets and film surfaces to facilitate water dispersion and adsorption

thereby endowing the film with excellent antifogging and frost-resisting properties. Because of the dynamic nature of electrostatic and hydrogen-bonding interactions

the PAA-

-PAAm/PDDA films can not only heal physical cuts with several tens of micrometer width

but also reconnect the fractured nanofibers to restore their original ordered nanostructures. The ability to heal macroscopic damages and restore inherent nanostructures can largely extend the service life and enhance the reliability of the antifogging and frost-resisting PAA-

-PAAm/PDDA films. The present work paves a way for the fabrication of polymeric materials that can heal micro/nanostructures and thus restore their original functions.

关键词

自修复材料防雾膜嵌段共聚物超分子材料

Keywords

Self-healing materialsAntifogging filmsBlock copolymersSupramolecular materials

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State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University

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