Preparation and Properties of Carboxylated Styrene-Butadiene/ Carboxylated Cellulose Nanocrystal Composites with Self-healing Properties

Xiao-yu Hou; Jie Hu; Ya-bing Liu; Yong-xin Duan

doi:10.11777/j.issn1000-3304.2023.22388

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Preparation and Properties of Carboxylated Styrene-Butadiene/ Carboxylated Cellulose Nanocrystal Composites with Self-healing Properties

Research Article | 更新时间：2023-06-21

- Preparation and Properties of Carboxylated Styrene-Butadiene/ Carboxylated Cellulose Nanocrystal Composites with Self-healing Properties
- ACTA POLYMERICA SINICA Vol. 54, Issue 7, Pages: 1074-1083(2023)
- 作者机构：
  
  青岛科技大学高分子科学与工程学院青岛 266042
- 作者简介：
  
  Yong-xin Duan, E-mail: dyx@qust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.22388
  CLC：
- Published：20 July 2023，
  
  Published Online：11 April 2023，
  
  Received：15 November 2022，
  
  Accepted：14 February 2023
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侯晓宇,胡洁,刘亚兵等.羧基丁苯橡胶/羧基化纤维素纳米晶自愈合复合材料的制备及性能研究[J].高分子学报,2023,54(07):1074-1083.

Hou Xiao-yu,Hu Jie,Liu Ya-bing,et al.Preparation and Properties of Carboxylated Styrene-Butadiene/ Carboxylated Cellulose Nanocrystal Composites with Self-healing Properties[J].ACTA POLYMERICA SINICA,2023,54(07):1074-1083.
侯晓宇,胡洁,刘亚兵等.羧基丁苯橡胶/羧基化纤维素纳米晶自愈合复合材料的制备及性能研究[J].高分子学报,2023,54(07):1074-1083. DOI： 10.11777/j.issn1000-3304.2023.22388.

Hou Xiao-yu,Hu Jie,Liu Ya-bing,et al.Preparation and Properties of Carboxylated Styrene-Butadiene/ Carboxylated Cellulose Nanocrystal Composites with Self-healing Properties[J].ACTA POLYMERICA SINICA,2023,54(07):1074-1083. DOI： 10.11777/j.issn1000-3304.2023.22388.

摘要

动态交联键的引入可赋予橡胶制品自愈合性能. 本文利用氧化锌(ZnO)的Zn

与羧基丁苯橡胶(XSBR)和羧基化纤维素纳米晶(CCA)的羧基间可形成离子键，CCA的羧基与XSBR的羧基间可形成氢键，制备了具有氢键和离子键双动态交联网络的羧基丁苯橡胶(X/C/Z)复合材料. 傅里叶变换红外光谱(Fourier transform infrared spectroscopy，FTIR)结果证实在X/C/Z复合材料中构筑了双动态交联网络. 与XSBR/CCA和XSBR/ZnO复合材料相比，离子键和氢键共存的双动态交联网络以及CCA和ZnO的协同补强赋予了X/C/Z复合材料更优异的物理机械性能及自愈合能力. 当CCA添加量为5 wt%时，随ZnO用量增加，X/C/Z复合材料的交联密度逐渐提高，复合材料的拉伸强度呈递增趋势，而断裂伸长率逐渐下降. 同时，ZnO用量的增加提供了更多可与XSBR和CCA上羧基络合形成离子键的Zn

，进而使复合材料的自愈合能力随ZnO含量的增加而提高. 利用ZnO和CCA作为补强/交联填料，采用简单便捷的方法制备了性能优异的羧基丁苯橡胶自愈合复合材料，为自愈合复合材料的开发提供了一种思路.

Abstract

The self-healing properties of rubber products can be given by the introduction of dynamic crosslinking bonds. In this work

carboxylated cellulose nanocrystals (CCA) and zinc oxide (ZnO) were selected as fillers. Carboxylated styrene-butadiene rubber (XSBR) composites (X/C/Z) with dual dynamic crosslinking networks were constructed by constructing ionic bonds between Zn

of ZnO and the carboxyl groups of XSBR and CCA

as well as hydrogen bonds between the carboxyl groups of CCA and XSBR. The Fourier transform infrared spectroscopy (FTIR) results confirmed the existence of dual dynamic crosslinking networks in X/C/Z composites. Compared with XSBR/CCA and XSBR/ZnO composites

the dual dynamic crosslinking networks and the synergistic reinforcement of CCA and ZnO endow X/C/Z composites with more excellent physical and mechanical properties. Fixed the CCA content at 5 wt%

the crosslinking density of X/C/Z composites increased with the increase of ZnO content. The tensile strength of the composites also showed an increasing trend

while the elongation at break gradually decreased. Meanwhile

the increase of ZnO content provided more Zn

that can complex with the carboxyl groups of XSBR and CCA to form ionic bonds. As a result

the self-healing ability of the composites were enhanced greatly. In this study

using ZnO and CCA as reinforcing/cross-linking fillers

carboxylated styrene-butadiene rubber self-healing composites with excellent properties were prepared by a simple and convenient method

which provided a way for the development of self-healing composites.

关键词

羧基化纤维素纳米晶氧化锌羧基丁苯橡胶动态交联自愈合

Keywords

Carboxylated cellulose nanocrystalsZinc oxideCarboxylated styrene-butadiene rubberDynamic crosslinkingSelf-healing

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青岛科技大学橡塑材料与工程教育部重点实验室

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