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Study on Design and Preparation of the Electric-field Responsive High-strength Pressure Sensitive Adhesive
- ACTA POLYMERICA SINICA Vol. 54, Issue 8, Pages: 1166-1175(2023)
- 作者机构：
1.宁波大学信息科学与工程学院 宁波 315211
2.中国科学院海洋新材料与应用技术重点实验室 中国科学院宁波材料技术与工程研究所 宁波 315201
- 作者简介：
Hai-ming Chen, E-mail: chenhaiming@nimte.ac.cn
He Li, E-mail: lihe@nimte.ac.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2023.23005
CLC：Published：20 August 2023，
Published Online：23 April 2023，
Received：02 January 2023，
Accepted：21 February 2023
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林浩浩,陈海明,茅东升等.电场响应型高强度压敏胶的设计、制备与性能研究[J].高分子学报,2023,54(08):1166-1175.
Lin Hao-hao,Chen Hai-ming,Mao Dong-sheng,et al.Study on Design and Preparation of the Electric-field Responsive High-strength Pressure Sensitive Adhesive[J].ACTA POLYMERICA SINICA,2023,54(08):1166-1175.
林浩浩,陈海明,茅东升等.电场响应型高强度压敏胶的设计、制备与性能研究[J].高分子学报,2023,54(08):1166-1175. DOI： 10.11777/j.issn1000-3304.2023.23005.
Lin Hao-hao,Chen Hai-ming,Mao Dong-sheng,et al.Study on Design and Preparation of the Electric-field Responsive High-strength Pressure Sensitive Adhesive[J].ACTA POLYMERICA SINICA,2023,54(08):1166-1175. DOI： 10.11777/j.issn1000-3304.2023.23005.
摘要
界面结合和本体强度是影响压敏胶黏结强度的两大因素，往往需要同时满足较低模量促进表面润湿和较高本体强度来阻碍裂纹扩展. 然而，材料的模量和本体强度往往正相关，这为设计高性能压敏胶带来了挑战. 本文工作通过在聚电解质中引入固相离子盐(LiTFSI)，不仅有效降低了压敏胶的模量(7.56 MPa)，增强界面结合，而且保持了较高的强度(884 kPa)，使得该压敏胶对金属铝的黏结强度可达1.09 MPa，对高分子有机聚合物(如聚对苯二甲酸乙二醇酯)的黏结强度高达1.17 MPa. 更进一步，基于离子性基团和游离离子的迁移或取向，赋予该压敏胶显著的电场增强效应，对金属铝的黏结增强效率可达89%. 当施加反向电压后，离子性基团的解取向和游离离子的反向运动，使黏结强度得以回落，体现了电场对黏结强度良好的调控作用. 最后，作为导电黏合剂，该压敏胶在摩擦纳米发电机等领域的应用得到了证明.
Abstract
Interfacial bonding and cohesive strength are the two main factors affecting the bonding strength of pressure-sensitive adhesives (PSA)
so that meet both low moduli to promote surface wetting and high cohesive strength to impede crack growth is necessary. However
a positive correlation between the moduli and cohesion strength often poses a challenge in designing high-performance PSA. In this study
introducing solid-phase ionic salt (LiTFSI) into the polyelectrolyte not only effectively reduces the modulus of the PSA (7.56 MPa) and enhances the interfacial bonding
but also maintains a high strength (884 kPa)
which endows a remarkable lap-shear strength of 1.09 and 1.17 MPa when bonded to metallic aluminum and polyethylene terephthalate (PET)
respectively. Furthermore
the migration and/or orientation of ionic groups and free ions enhance the lap-shear strength with an efficiency of 89%. Moreover
a reversed voltage will promote ionic groups and free ions disorient and migrate in a reversed direction
resulting in lower lap-shear strength. Finally
the effect of facilitating charge collection of such PSA in triboelectric nanogenerators was demonstrated.
关键词
离子凝胶压敏胶电场增强黏结强度
Keywords
IonogelPressure-sensitive adhesiveElectric field reinforcementAdhesive strength
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