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Construction and Function of CO2-Switchable Polymers and Composites
- ACTA POLYMERICA SINICA Vol. 54, Issue 10, Pages: 1409-1425(2023)
- 作者机构：
1.清华大学，化学系 有机光电子与分子工程教育部重点实验室，北京 100084
2.清华大学，致理书院，北京 100084
- 作者简介：
- 基金信息：
DOI：10.11777/j.issn1000-3304.2023.23113
CLC：Published：20 October 2023，
Published Online：30 August 2023，
Received：25 April 2023，
Accepted：11 July 2023
扫 描 看 全 文
周硕,杨松铭,袁金颖.基于二氧化碳响应的聚合物及复合材料的构建与功能[J].高分子学报,2023,54(10):1409-1425.
Zhou Shuo,Yang Song-ming,Yuan Jin-ying.Construction and Function of CO2-Switchable Polymers and Composites[J].ACTA POLYMERICA SINICA,2023,54(10):1409-1425.
周硕,杨松铭,袁金颖.基于二氧化碳响应的聚合物及复合材料的构建与功能[J].高分子学报,2023,54(10):1409-1425. DOI： 10.11777/j.issn1000-3304.2023.23113.
Zhou Shuo,Yang Song-ming,Yuan Jin-ying.Construction and Function of CO2-Switchable Polymers and Composites[J].ACTA POLYMERICA SINICA,2023,54(10):1409-1425. DOI： 10.11777/j.issn1000-3304.2023.23113.
摘要
CO
2
响应聚合物是一类可以对CO
2
气体和溶液做出响应的聚合物. 与CO
2
反应后聚合物的亲疏水和电荷等性质发生改变，通过氩气、氮气或空气的通入，或略微加热，可以实现CO
2
的去除，使聚合物及复合材料性质完全或部分恢复. 本文回顾了基于CO
2
响应的聚合物及复合材料的近年发展，从化学结构与响应基团出发介绍了不同类型的响应聚合物，包括脒基类、叔胺基类、胍基类和咪唑类，并对常见CO
2
响应聚合物的单体进行了总结. 介绍了CO
2
响应聚合物的不同功能，从组装体的角度出发讨论了囊泡、球形胶束和复合组装体及其他形貌的不同性质，同时逐级深入，总结了乳胶、气凝胶与水凝胶、功能表面与纳米纤维膜、有机无机杂化材料与复合材料和荧光传感与监测体系的构建及效果. 最后对于该领域还需继续探索优化的问题进行了讨论与总结，对未来的发展方向进行了展望.
Abstract
CO
2
-responsive polymers are a class of polymers that can respond to CO
2
gases and solutions. The reaction with CO
2
changes the properties of the polymer such as hydrophobicity and charge. By introducing argon
nitrogen and air
or by slightly heating
CO
2
can be removed and the properties of the polymer and composite material can be fully or partially restored. This review summarizes the recent development of CO
2
-responsive polymers and composites
introduces different types of responsive polymers from chemical structures and responsive groups
including amidines
tertiary amines
guanidines and imidazoles
and summarizes the monomers of common CO
2
-responsive polymers. The different functions of CO
2
-responsive polymers are introduced. Different properties of vesicles
spherical micelles and composite assemblies and other morphologies are discussed from the viewpoint of assemblies
while the construction and effects of emulsions
aerogels and hydrogels
functional surfaces and nanofiber membranes
organic-inorganic hybrid materials and composites
and fluorescence sensing and monitoring systems are summarized progressively. Finally
the problems that need to be explored and optimized in this field are discussed
and the future development direction is foreseen.
关键词
CO2响应环境响应聚合物组装体亲疏水性传感
Keywords
CO2-switchableEnvironmental responsePolymer assembliesHydrophobic and hydrophilic performanceSensor
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