Poly(L-lactide) has derived extensive attention as a most promising biodegradable plastics with the excellent physical and mechanical properties.But it's so stiff and brittle for room temperature applications that restrict its wide applications.This work focused on NBR as toughening agent
adding MAH or DCP or the combination of MAH/DCP as the compatibilizer to increase the compatibility.We found that
by adding DCP only
the toughening system has the optimal mechnical properties
the elongation at break and the impact strength were improved by more than 60 times and 5 times respectively
compared with pure PLLA.This method is simple and operable.For understanding the toughening mechanism in depth
we use polarizing optical microscope and transmission electron microscope toinvestigate the morphology of the blends.It was found that the system of PLLA/NBR/DCP has the smallest dispersed size and the uniform state.Also the interface is fuzzy which symbolizes the good compatibility.Besides
the PLLA spherulite is small and uniform.All the factors above lead to the good toughness.The fast crystallization rate is beneficial to the stability of the products.Based on the mechanical properties and the morphology of the blends
we discussed the toughening mechanism of PLLA/NBR.
Preparation of Low-shrinkage Polypropylene by Tailoring Crystallization
Preparation of High Performance Dielectric Elastomers by Tailoring the Aggregation Structure of Polyurethane
The Effect of Lamellar Thickness of iPP on the Formation of Trigonal Modification of PB-1 under Confinement Environment
Regulating the Crystallization Behaviors of High-molecular-weight Poly(lactic acid) Stereocomplex System Based on the Structure of Poly(ethylene glycol)
Functionalized Imidazolium-based Ionomers as Effective Toughening Agents for Poly(lactic acid)
Related Author
No data
Related Institution
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University
SINOPEC Beijing Research Institute of Chemical Industry
Bohai Rim Collaborative Innovation Center on Green Chemical Application Technology, Department of Chemical Engineering, Weifang Vocational College
Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics, School of Polymer Science and Engineering, Qingdao University of Science & Technology
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology