Effect of the Microstructures of Silane-modified Liquid Polybutadiene on the Properties of Styrene-Butadiene Rubber

Qian Wang; Meng-han Xing; Jing-yi Zhang; Yu-fei Shang; Ming-xiang Yu; Ying Tan; Chun-yu Zhang; Xue-quan Zhang; Yu Sun

doi:10.11777/j.issn1000-3304.2026.26151

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Effect of the Microstructures of Silane-modified Liquid Polybutadiene on the Properties of Styrene-Butadiene Rubber

更新时间：2026-07-23

- Effect of the Microstructures of Silane-modified Liquid Polybutadiene on the Properties of Styrene-Butadiene Rubber
- Acta Polymerica Sinica Pages: 1-13(2026)
- 作者机构：
  
  1.青岛科技大学高分子科学与工程学院青岛 266000
  2.山东德博新材料科技有限公司德州 253300
- 作者简介：
  
  Xue-quan Zhang, E-mail: xqzhang@qust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26151
  CLC：
- CSTR：32057.14.GFZXB.2026.7673
- Received：30 April 2026，
  
  Accepted：23 June 2026，
  
  Online First：23 July 2026，
- 稿件说明：
移动端阅览
王茜, 邢梦菡, 张敬一, 商育菲, 于明祥, 谭莹, 张春雨, 张学全, 孙宇. 硅烷改性液体聚丁二烯微观结构对丁苯橡胶性能的影响. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26151.

Wang, Q.; Xing, M. H.; Zhang, J. Y.; Shang, Y. F.; Yu, M. X.; Tan, Y.; Zhang, C. Y.; Zhang, X. Q.; Sun, Y. Effect of the microstructures of silane-modified liquid polybutadiene on the properties of styrene-butadiene rubber. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26151.
王茜, 邢梦菡, 张敬一, 商育菲, 于明祥, 谭莹, 张春雨, 张学全, 孙宇. 硅烷改性液体聚丁二烯微观结构对丁苯橡胶性能的影响. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26151. DOI： CSTR： 32057.14.GFZXB.2026.7673.

Wang, Q.; Xing, M. H.; Zhang, J. Y.; Shang, Y. F.; Yu, M. X.; Tan, Y.; Zhang, C. Y.; Zhang, X. Q.; Sun, Y. Effect of the microstructures of silane-modified liquid polybutadiene on the properties of styrene-butadiene rubber. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26151. DOI： CSTR： 32057.14.GFZXB.2026.7673.

摘要

为明确硅烷改性液体聚丁二烯(SiLPB)中1

2-乙烯基含量对橡胶性能的影响，本研究制备了5种不同1

2-乙烯基含量的SiLPB. 核磁共振氢谱(

H-NMR)、傅里叶变换红外光谱(FTIR)与凝胶渗透色谱(GPC)证实各SiLPB硅烷接枝率及分子量基本一致. DSC显示随SiLPB中1

2-乙烯基含量从5%增加到80%，其玻璃化转变温度由-87 ℃升高到-26 ℃. 采用SiLPB替代10 phr传统芳烃油(TDAE)，可有效降低混炼胶门尼黏度，延长焦烧时间及改善白炭黑分散，同时保持与仅含TDAE油参照样(C-Ref)相近的正硫化时间和物理力学性能. 含高乙烯基含量(60%与80%) SiLPB的硫化胶具备更好的耐热氧老化性能，但耐磨性能较C-Ref下降约5%. 中低1

2-乙烯基含量(

45%) SiLPB对橡胶耐磨性能无影响. 动态力学性能和回弹测试表明，所有SiLPB均可显著降低60 ℃下tan

值并提高70 ℃回弹，具有降低滚动阻力的潜力；同时，随SiLPB中1

2-乙烯基含量增加，硫化胶0 ℃下tan

值逐步提高，表明其具有改善抗湿滑性能潜力. 通过调控SiLPB中1

2-乙烯基含量可为胎面材料性能平衡提供新思路.

Abstract

Silane-modified liquid polybutadiene (SiLPB) with different 1

2-vinyl contents were prepared to study the effect of 1

2-vinyl content on rubber properties.

H-NMR

FTIR and GPC results confirmed that the samples SiLPB had similar silane contents and molecular weights. DSC results showed that

as the 1

2-vinyl content in SiLPB was increased from 5% to 80%

its g

lass transition temperature was increased from -87 ℃ to -26 ℃. Replacing 10 phr conventional aromatic oil (TDAE) with SiLPB effectively reduced the Mooney viscosity of the compounds

prolonged the scorch time and improved silica dispersion

while maintaining the similar curing time (

) and physical-mechanical properties to that containing TDAE oil (C-Ref). Vulcanizates containing SiLPB with high 1

2-vinyl content (C-SiLPB60 and C-SiLPB80) exhibited better thermal-oxidative aging resistance

although their abrasion resistance was decreased by approximately 5% compared with C-Ref. In contrast

SiLPB with 1

2-vinyl contents below 45% showed no obvious effect on abrasion resistance. Dynamic mechanical analysis and rebound tests demonstrated that all SiLPB samples significantly reduced the tan

value at 60 ℃ and increased the rebound resilience at 70 ℃

indicating their potential to reduce rolling resistance. Meanwhile

the tan

value at 0 ℃ was gradually increased with increasing 1

2-vinyl content in SiLPB

suggesting the potential to improve wet-skid resistance. These results indicate that regulating the 1

2-vinyl content in SiLPB provides a new strategy for balancing the performance of tire tread materials.

关键词

Keywords

references

Zhang M. Strategic research on the development of china's new energy automobile industry . IOP Conf. Ser.: Mater. Sci. Eng. , 2019 , 677 ( 3 ), 032104 . doi: 10.1088/1757-899x/677/3/032104 http://dx.doi.org/10.1088/1757-899x/677/3/032104

Liu Z. C. Rational design of high-performance nanomaterials for electric vehicle tires . Highlights Sci. Eng. Technol. , 2023 , 62 , 110 - 118 . doi: 10.54097/hset.v62i.10432 http://dx.doi.org/10.54097/hset.v62i.10432

Li H. W. ; Zhao B. ; Yu W. B. ; Xu N. ; Guo K. H. Design and application of a tire slip energy control scheme based on optimal guaranteed cost theory for four-in-wheel drive electric vehicles . Asian J. Control , 2022 , 24 ( 3 ), 1333 - 1350 . doi: 10.1002/asjc.2523 http://dx.doi.org/10.1002/asjc.2523

Huang H. B. ; Wang Y. W. ; Wu J. H. ; Ding W. P. ; Pang J. Prediction and optimization of pure electric vehicle tire/road structure-borne noise based on knowledge graph and multi-task ResNet . Expert Syst. Appl. , 2024 , 255 , 124536 . doi: 10.1016/j.eswa.2024.124536 http://dx.doi.org/10.1016/j.eswa.2024.124536

Foroutan H. ; Aryal A. ; Craine M. ; Rakha H. Projecting airborne tire wear particle emissions in the United States in the era of electric vehicles . Sci. Total Environ. , 2025 , 967 , 178848 . doi: 10.1016/j.scitotenv.2025.178848 http://dx.doi.org/10.1016/j.scitotenv.2025.178848

Polukarova M. ; Hjort M. ; Gustafsson M. Comprehensive approach to national tire wear emissions: challenges and implications . Sci. Total Environ. , 2024 , 924 , 171391 . doi: 10.1016/j.scitotenv.2024.171391 http://dx.doi.org/10.1016/j.scitotenv.2024.171391

Bernal-Ortega P. ; Gaillard E. ; van Elburg F. ; Blume A. Use of hydrocarbon resins as an alternative to TDAE oil in tire tread compounds . Polym. Test. , 2023 , 126 , 108168 . doi: 10.1016/j.polymertesting.2023.108168 http://dx.doi.org/10.1016/j.polymertesting.2023.108168

Dhanorkar R. J. ; Mohanty S. ; Gupta V. K. Synthesis of functionalized styrene butadiene rubber and its applications in SBR-silica composites for high performance tire applications . Ind. Eng. Chem. Res. , 2021 , 60 ( 12 ), 4517 - 4535 . doi: 10.1021/acs.iecr.1c00013 http://dx.doi.org/10.1021/acs.iecr.1c00013

Nakazono T. ; Matsumoto A. Mechanical properties and thermal aging behavior of styrene-butadiene rubbers vulcanized using liquid diene polymers as the plasticizer . J. Appl. Polym. Sci. , 2010 , 118 ( 4 ), 2314 - 2320 . doi: 10.1002/app.31483 http://dx.doi.org/10.1002/app.31483

Hayichelaeh C. ; Mingsamoh A. ; Boonkerd K. Influence of silane-modified palm oil as a green processing oil in silica-reinforced SBR/BR compounds for tire tread applications . J. Ind. Eng. Chem. , 2024 , 139 , 347 - 357 . doi: 10.1016/j.jiec.2024.05.013 http://dx.doi.org/10.1016/j.jiec.2024.05.013

Um G. Y. ; Kwon T. ; Lee S. H. ; Kim W. ; Kim J. ; Yu S. ; Kim K. ; Lee J. H. Effect of functionality and loading procedure of liquid butadiene rubber on properties of silica-filled tire tread compounds . Polym. Test. , 2023 , 129 , 108283 . doi: 10.1016/j.polymertesting.2023.108283 http://dx.doi.org/10.1016/j.polymertesting.2023.108283

Diekmann A. ; Giese U. ; Schaumann I. Polycyclic aromatic hydrocarbons in consumer goods made from recycled rubber material: a review . Chemosphere , 2019 , 220 , 1163 - 1178 . doi: 10.1016/j.chemosphere.2018.12.111 http://dx.doi.org/10.1016/j.chemosphere.2018.12.111

Chen P. ; Liang J. Polycyclic aromatic hydrocarbons in green space soils in Shanghai: source, distribution, and risk assessment . J. Soils Sediments , 2021 , 21 ( 2 ), 967 - 977 . doi: 10.1007/s11368-020-02838-2 http://dx.doi.org/10.1007/s11368-020-02838-2

Armada D. ; Martinez-Fernandez A. ; Celeiro M. ; Dagnac T. ; Llompart M. Assessment of the bioaccessibility of PAHs and other hazardous compounds present in recycled tire rubber employed in synthetic football fields . Sci. Total Environ. , 2023 , 857 (Pt 2 ), 159485 . doi: 10.1016/j.scitotenv.2022.159485 http://dx.doi.org/10.1016/j.scitotenv.2022.159485

Wang Q. ; Sun T. ; Wei C. Y. ; Sun N. ; Zhao W. P. ; Liu L. J. ; Wei L. P. ; Liu H. ; Zhang C. Y. ; Zhang X. Q. ; Sun Y. Liquid 3,4-polyisoprene: a novel processing aid to achieve tire tread SBR composites with high wet grip and low energy consumption . Polym. Test. , 2022 , 115 , 107713 . doi: 10.1016/j.polymertesting.2022.107713 http://dx.doi.org/10.1016/j.polymertesting.2022.107713

Li M. ; Liu X. L. ; Cui D. M. Influence of high cis-1,4-liquid polydienes on properties of carbon-black filled composites . Polymer , 2024 , 313 , 127710 . doi: 10.1016/j.polymer.2024.127710 http://dx.doi.org/10.1016/j.polymer.2024.127710

Dong W. ; He J. Y. ; Xia Z. ; Fan W. F. ; Sun W. ; Bai C. X. Synthesis and performance study of hydrogenated and isocyanated polybutadiene liquid rubber for energy efficient tires . Polymer , 2025 , 334 , 128554 . doi: 10.1016/j.polymer.2025.128554 http://dx.doi.org/10.1016/j.polymer.2025.128554

Ren Y. Q. ; Zhao S. H. ; Li Q. Q. ; Zhang X. Y. ; Zhang L. Q. Influence of liquid isoprene on rheological behavior and mechanical properties of polyisoprene rubber . J. Appl. Polym. Sci. , 2015 , 132 ( 8 ), app . 41485 . doi: 10.1002/app.41485 http://dx.doi.org/10.1002/app.41485

Ryu G. ; Kim D. ; Song S. ; Hwang K. ; Kim W. Effect of the epoxide contents of liquid isoprene rubber as a processing aid on the properties of silica-filled natural rubber compounds . Polymers , 2021 , 13 ( 18 ), 3026 . doi: 10.3390/polym13183026 http://dx.doi.org/10.3390/polym13183026

Colucci G. ; Di Gianni A. ; Bongiovanni R. ; Priola A. ; Torello F. ; Bracco S. ; Sozzani P. Modification of silica by liquid polybutadienes containing alkoxysilane groups . Macromol. Symp. , 2010 , 296 ( 1 ), 550 - 556 . doi: 10.1002/masy.201051072 http://dx.doi.org/10.1002/masy.201051072

Kim D. ; Ahn B. ; Kim K. ; Lee J. ; Kim I. J. ; Kim W. Effects of molecular weight of functionalized liquid butadiene rubber as a processing aid on the properties of SSBR/silica compounds . Polymers , 2021 , 13 ( 6 ), 850 . doi: 10.3390/polym13060850 http://dx.doi.org/10.3390/polym13060850

Kim D. ; Yeom G. ; Joo H. ; Ahn B. ; Paik H. J. ; Jeon H. ; Kim W. Effect of the functional group position in functionalized liquid butadiene rubbers used as processing aids on the properties of silica-filled rubber compounds . Polymers , 2021 , 13 ( 16 ), 2698 . doi: 10.3390/polym13162698 http://dx.doi.org/10.3390/polym13162698

Choi H. ; Song S. ; Yeom G. ; Kim D. ; Kim S. ; Jeong J. ; Hwang K. ; Joo S. W. ; Chung S. ; Kim W. ; Paik H. J. Triethoxysilyl-terminated telechelic liquid butadiene rubber with disulfide linkages for tire tread of electric vehicles . ACS Appl. Polym. Mater. , 2024 , 6 ( 4 ), 2076 - 2084 . doi: 10.1021/acsapm.3c02037 http://dx.doi.org/10.1021/acsapm.3c02037

李敏 , 刘新立 , 崔冬梅 . 硅烷封端液体聚丁二烯对二氧化硅填充丁苯橡胶/顺丁橡胶复合材料性能的影响 . 高分子学报 , 2026 , 57 ( 1 ), 119 - 128 .

Liu J. H. ; Li D. ; Fu Z. ; Geng J. T. ; Hua J. Preparation and properties of 1,2-polybutadiene grafting with poly(1,3-butadiene)-block-(dimethylsiloxane) . Polym. Adv. Technol. , 2019 , 30 ( 7 ), 1663 - 1672 . doi: 10.1002/pat.4597 http://dx.doi.org/10.1002/pat.4597

Yu Y. ; Xu S. L. ; Pang L. R. ; Jiang B. T. ; Liu H. ; Zhang C. Y. ; Zhang X. Q. Enhancing dynamic properties of natural rubber nanocomposites: a novel syndiotactic 1,2-polybutadiene via iron-catalyzed butadiene-ethylene copolymerization . Chem. Eng. J. , 2025 , 525 , 170255 . doi: 10.1016/j.cej.2025.170255 http://dx.doi.org/10.1016/j.cej.2025.170255

Zhu H. ; Tang M. ; Hao Y. Q. ; Zhou Z. F. ; Sun D. ; Yu P. F. ; Wu Y. X. Novel polybutadiene rubber with long cis -1,4 and syndiotactic vinyl segments (CVBR) for high performance sidewall of all-steel giant off-the-road tire . Compos. Part B Eng. , 2024 , 275 , 111349 . doi: 10.1016/j.compositesb.2024.111349 http://dx.doi.org/10.1016/j.compositesb.2024.111349

Yu Y. ; Xu S. L. ; Zhao Y. N. ; Sun Y. F. ; Liu H. ; Zhang C. Y. ; Zhang X. Q. Syndiotactic 1,2-polybutadiene with regulable viscoelasticity and crystallinity via a steric hindrance strategy for promoting the dynamic mechanical properties of nanocomposites . Compos. Part A Appl. Sci. Manuf. , 2025 , 191 , 108723 . doi: 10.1016/j.compositesa.2025.108723 http://dx.doi.org/10.1016/j.compositesa.2025.108723

Pang S. ; Yu Y. ; Zhang L. Q. ; Wu Y. P. Adjusting silica/rubber interfacial interactions and properties via the click reactions between liquid polybutadiene and silane . Compos. Sci. Technol. , 2021 , 213 , 108903 . doi: 10.1016/j.compscitech.2021.108903 http://dx.doi.org/10.1016/j.compscitech.2021.108903

Lim K. ; Hong S. J. ; Lee H. ; Jung J. ; Kim K. ; Park J. H. ; Bang J. Open-structured silica network based on silane-terminated telechelic polybutadiene for electric vehicle tires . Sustain. Mater. Technol. , 2024 , 42 , e01156 . doi: 10.1016/j.susmat.2024.e01156 http://dx.doi.org/10.1016/j.susmat.2024.e01156

Song S. ; Choi H. ; Jeong J. ; Kim S. ; Kwon M. ; Kim M. ; Kim D. ; Jeon H. ; Paik H. J. ; Chung S. ; Kim W. Optimized end functionality of silane-terminated liquid butadiene rubber for silica-filled rubber compounds . Polymers , 2023 , 15 ( 12 ), 2583 . doi: 10.3390/polym15122583 http://dx.doi.org/10.3390/polym15122583

Sengloyluan K. ; Sahakaro K. ; Dierkes W. K. ; Noordermeer J. W. M. Silane grafted natural rubber and its compatibilization effect on silica-reinforced rubber tire compounds . Express Polym. Lett. , 2017 , 11 ( 12 ), 1003 - 1022 . doi: 10.3144/expresspolymlett.2017.95 http://dx.doi.org/10.3144/expresspolymlett.2017.95

Yan X. S. ; Hamed G. R. ; Jia L. Urushiol-derived non-silane coupling agent . Polymer , 2017 , 125 , 172 - 181 . doi: 10.1016/j.polymer.2017.07.087 http://dx.doi.org/10.1016/j.polymer.2017.07.087

孙庆刚 , 马德龙 , 李云峰 , 王茜 , 王洪奎 , 杨振林 , 张保宁 , 孙宇 . 液体聚丁二烯微观结构对丁苯橡胶性能的影响 . 高分子通报 , 2026 , 39 ( 2 ), 280 - 286 .

王茜 , 张俊驰 , 吕贵杰 , 徐新圆 , 孙涛 , 刘恒 , 张春雨 , 孙宇 , 张学全 . 液体1,4-聚丁二烯在丁苯橡胶胶料中的应用 . 橡胶工业 , 2024 , 71 ( 4 ), 266 - 270 .

Liu Z. Y. ; Han L. ; Wang R. J. ; Feng Q. ; Liu G. Y. ; Yong Z. F. Influence of liquid polybutadiene on crosslinking network and mechanical properties of SSBR/BR . Polym. Eng. Sci. , 2022 , 62 ( 5 ), 1416 - 1426 . doi: 10.1002/pen.25931 http://dx.doi.org/10.1002/pen.25931

Choi S. S. ; Park B. H. ; Nah C. Effect of low molecular weight polybutadiene as processing aid on properties of silica-filled styrene-butadiene rubber compounds . J. Appl. Polym. Sci. , 2003 , 90 ( 11 ), 3135 - 3140 . doi: 10.1002/app.13056 http://dx.doi.org/10.1002/app.13056

Wang X. L. ; Yang K. ; Zhang P. Evaluation of the aging coefficient and the aging lifetime of carbon black-filled styrene-isoprene-butadiene rubber after thermal-oxidative aging . Compos. Sci. Technol. , 2022 , 220 , 109258 . doi: 10.1016/j.compscitech.2021.109258 http://dx.doi.org/10.1016/j.compscitech.2021.109258

Sanglar C. ; Nguyen Quoc H. ; Grenier-Loustalot M. F. Studies on thermal degradation of 1-4 and 1-2 polybutadienes in inert atmosphere . Polym. Degrad. Stab. , 2010 , 95 ( 9 ), 1870 - 1876 . doi: 10.1016/j.polymdegradstab.2010.04.021 http://dx.doi.org/10.1016/j.polymdegradstab.2010.04.021

Bakar M. ; Sola-Wdowska M. ; Przybyłek M. ; Białkowska A. ; Zarzyka I. ; Hanulikova B. ; Masař M. Investigation of combined aging and mullins stress softening of rubber nanocomposites . Polymers , 2024 , 16 ( 22 ), 3141 . doi: 10.3390/polym16223141 http://dx.doi.org/10.3390/polym16223141

朱寒 , 程竹杰 , 刘天保 , 刘胜利 , 王国田 , 吴一弦 . 微观结构含量对稀土高顺式聚丁二烯性能的影响 . 高分子学报 , 2023 , 54 ( 8 ), 1176 - 1185 .

Hashim A. S. ; Azahari B. ; Ikeda Y. ; Kohjiya S. The effect of bis(3-triethoxysilylpropyl) tetrasulfide on silica reinforcement of styrene-butadiene rubber . Rubber Chem. Technol. , 1998 , 71 ( 2 ), 289 - 299 . doi: 10.5254/1.3538485 http://dx.doi.org/10.5254/1.3538485

Yoshioka A. ; Komuro K. ; Ueda A. ; Watanabe H. ; Akita S. ; Masuda T. ; Nakajima A. Structure and physical properties of high-vinyl polybutadiene rubbers and their blends . Pure Appl. Chem. , 1986 , 58 ( 12 ), 1697 - 1706 . doi: 10.1351/pac198658121697 http://dx.doi.org/10.1351/pac198658121697

葛建宁 , 李柏林 , 董为民 , 张新惠 , 于琦周 , 任慧娟 , 姜连升 , 张学全 . 铁系3,4-聚异戊二烯橡胶的性能 . 弹性体 , 2007 , 17 ( 1 ), 45 - 47 .

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